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Safety Data Sheet EN

Zinc chloride, anhydrous

CAS 7646-85-7
EC 231-592-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Zinc chloride, anhydrous
Product Code
A16281
Chemical Name
Zinc chloride
Synonyms
Zinc (II) Chloride; Zinc dichloride; Zinc butter;

Regulatory Identifiers

CAS Number
7646-85-7 Check regulations →
EC Number
231-592-0 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher (Kandel) GmbH

manufacturer

Erlenbachweg 2, 76870 Kandel, Germany

+49 (0) 721 84007 280

Fisher Scientific AG logo

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

https://www.fishersci.ch/ch/en/customer-help-support/forms/email-us.html

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H335 May cause respiratory irritation
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Zinc chloride EC: 231-592-0 7646-85-7 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician or poison control center immediately. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Ingestion

Do NOT induce vomiting. Immediate medical attention is required. Drink plenty of water. Never give anything by mouth to an unconscious person.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Possible perforation of stomach or esophagus should be investigated

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

The product causes burns of eyes, skin and mucous membranes.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing.

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Butyl rubber (> 480 minutes, 0.5 mm, EN 374), Nitrile rubber (> 480 minutes, 0.35 mm), Natural rubber (> 480 minutes, 0.5 mm), Neoprene (> 480 minutes, 0.5 mm), PVC (> 480 minutes, 0.5 mm), Viton (R) (> 480 minutes, 0.4 mm). Inspect gloves before use. Observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced: full face mask (DIN EN 136). Recommended Filter type: Particulates filter conforming to EN 143; Type P; White. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001; or; Half mask: EN140 plus filter, EN 143; White. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
White
Colour
White
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
No data available
Ph
5 (100 g/L aq.sol)
Melting Point
293 °C / 559.4 °F
Boiling Point
732 °C / 1349.6 °F
Flash Point
No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable - Solid
Vapor Pressure
1.3 mbar @ 428 °C
Vapor Density
Not applicable
Relative Density
---
Bulk Density
1,400 - 1,800 kg/m³ (20 °C)
Density
---
Flammability
No information available
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
No information available
Partition Coefficient
---
Solubility In Water
432 g/100ml (25°C)
Solubility In Fat
---
Molecular Weight
136.29
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions. Hygroscopic.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Excess heat.

Incompatible

Strong bases. Strong acids. Cyanides. Sulfides.

Decomposition

Zinc. Hydrogen chloride gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecotoxicity effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. | Component | Freshwater Fish | Water Flea | Freshwater Algae | | --- | --- | --- | --- |

12.1. Toxicity

Zinc chloride | LC50: 0.4-2.2 mg/L/96h (Cyprinus carpio) | EC50: 0.2 mg/L/48h | EC50: 0.027-0.105 mg/L/72h

12.1. Toxicity

| Component | Microtox | M-Factor | | --- | --- | --- | | Zinc chloride | | Acute = 10 Chronic = 1 |

12.2. Persistence and degradability

Persistence Soluble in water, Persistence is unlikely, based on information available. Degradability Not relevant for inorganic substances. Degradation in sewage treatment plant Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

Persistence is unlikely due to water solubility. Degradability is not relevant for inorganic substances. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- |

Bioaccumulation is unlikely.

12.3. Bioaccumulative potential

| Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- | | Zinc chloride | | 16000 dimensionless |

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

The product is water soluble and highly mobile in soils, with the potential to spread in water systems.

12.5. Results of PBT and vPvB assessment

In accordance with Annex XIII of the REACH Regulation, inorganic substances do not require assessment.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Disposal

Should not be released into the environment.

Waste Codes

Waste codes are not product specific, but application specific. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2331
Shipping Name
ZINC CHLORIDE, ANHYDROUS
Transport Class
8
Packing Group
III
ADR

No special precautions required.

IMDG

No special precautions required.

IATA

No special precautions required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Zinc chloride, anhydrous known by?

Zinc chloride, anhydrous is also known as: Zinc (II) Chloride; Zinc dichloride; Zinc butter;

What is the hazard signal word for Zinc chloride, anhydrous?

The signal word is danger.

What is the physical form of Zinc chloride, anhydrous?

Zinc chloride, anhydrous is a solid appearing as white with white color. It has odorless odor.

What is the solubility of Zinc chloride, anhydrous?

No information available

What is Zinc chloride, anhydrous used for?

Laboratory chemicals.

What are the hazard statements for Zinc chloride, anhydrous?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed
  • H314: Causes severe skin burns and eye damage
  • H335: May cause respiratory irritation
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of Zinc chloride, anhydrous?

The melting point is 293 °C / 559.4 °F and the boiling point is 732 °C / 1349.6 °F.