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Safety Data Sheet EN

Phenol, synthetic

CAS 108-95-2
EC 203-632-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phenol, synthetic

Regulatory Identifiers

CAS Number
108-95-2 Check regulations →
EC Number
203-632-7 Check regulations →
REACH No.
01-2119471329-32-XXXX

Identified Uses

General use: Phenol is an important raw material of the chemical industry. It is used for manufacturing of Bisphenol A, Phenol-Formaldehyde-Resins and Caprolactam. Furthermore it is used for manufacturing of Alkyl Phenols, Salicylic Acid and Nitrophenols. Identified uses: Industrial use: 0 Generic exposure scenario (GES): Industrial Processes relevant for Page 14 phenol and phenol containing products (ES 1 - 8) 1 Manufacture, processing and distribution of substances and mixtures * Page 47 2 Use in laboratories Page 51 3 Uses in coatings Page 54 4 Use in binders and release agents Page 57 5 Rubber production and processing Page 60 6 Polymer manufacturing Page 63 7 Polymer processing Page 66 8 Phenolic resin processing Page 69 Use of phenolic resins uses of downstream users (DU) Professional use: 10 Generic exposure scenario (GES): Professional Processes relevant Page 73 for phenol and phenol containing products (ES 11 - 16) 11 Use in laboratories Page 102 12 Uses in coatings Page 105 13 Use in binders and release agents Page 108 14 Polymer manufacturing Page 111 15 Polymer processing Page 114 16 Phenolic resin processing Page 117 Use of phenolic resins uses of downstream users (DU) - Examples for processing: use as an intermediate, use as a monomer etc., use as a solvent, use for the manufacturing of resins

Manufacturers & Suppliers

INEOS Phenol GmbH logo

INEOS Phenol GmbH

manufacturer

Dechenstrae 3 45966 Gladbeck Germany

+49 (0)2043 / 9 58-0

www.ineosphenol.com

I

INEOS Phenol Belgium NV

national supplier

Haven 1930 Geslecht 1, B-9130 Beveren

+32 3 730 13 50

I

INEOS Europe AG, INEOS Phenol Division

global supplier

3, Avenue des Uttins, 1180 Rolle, Switzerland

Emergency Contacts

Emergency Contact

+49 (0)2043 / 9 58-233

Emergency Contact

+32 3 730 14 44

GIZ-Nord

+49 (0)551-19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Muta. Cat. 2 H341
STOT RE Cat. 2 H373
Aquatic Chronic Cat. 2 H411
Aquatic Chronic Cat. 2 H411
Skin Corr. Cat. 1B H314
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P262 Do not get in eyes, on skin, or on clothing.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water/soap.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterisation: C6 H6 O = C6 H5 OH Phenol, Hydroxybenzene

Chemical Name CAS Number Concentration Hazardous
N/A --- --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide for adequate fresh air. If breathing becomes irregular or ceases, apply mouth-to-mouth resuscitation or artificial respiration immediately, where required supply oxygen. Immediately get medical attention.

Symptoms: Mucous membrane irritation, cough, shortage of breath, damage of respiratory tract.

Skin contact

Take off immediately all contaminated clothing. Immediately get medical attention. In case of contact with the skin, immediately wash with polyethylene glycol. Then wash with water.

Symptoms: Strong skin absorption as main danger of phenol poisoning at the workplace with paralysis of the central nervous system (with lethal consequences in severe cases) as well as liver and kidney damage

Eye contact

Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently seek the immediate attention of an ophthalmologist.

Symptoms: burns

Ingestion

Rinse mouth immediately and drink plenty of water. Do not induce vomiting. Immediately get medical attention.

Immediate Medical Attention

Immediately get medical attention (for inhalation, skin, ingestion). Subsequently seek the immediate attention of an ophthalmologist (for eye contact).

Medical Treatment

Thoroughly clean the wetted skin areas, if possible with polyethylene glycol (e.g. polyethylene glycol 300). In case of eye contact, rinse copiously with water, in case of burns rinse continuously with water as far as possible and take to an eye specialist or eye clinic. In case of inhalation, to prevent pulmonal oedemia, initiate inhalative cortisone therapy as early as possible (e.g. every 10 minutes 5 strokes of a cortisone containing aerosol dosing spray); administer codeine against dry coughing. In case of commencing or manifested pulmonary oedemia, systemic administration of cortisone. If swallowed, gastric lavage after intubation, activated charcoal, saline laxative.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Execute works under fume hood. Do not inhale substance. The substance should only be handled in closed apparatus or systems. Process exhaust through separator/filter as needed.

Hands

Protective gloves according to EN 374. Glove material: Neoprene, PVC. Breakthrough time: 140 min. (Neoprene), 75 min. (PVC). Observe glove manufacturer's instructions concerning penetrability and breakthrough time.

Eyes

Goggles (DIN EN 58211) or face protection shield.

Respiratory

Respiratory protection must be worn whenever the WEL levels have been exceeded. Use filter type ABEK according to EN 14387.

Skin/Body

Wear suitable protective clothing. Material: PVC. Safety shoes according to EN 345-347.

Environmental

All information for relevant exposure scenarios including operational conditions and risk management measures are listed in 'Annex II: Environmental Exposure and Risk Assessment' and 'Annex III: Environmental Exposure Calculation Tool'.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Crystallisation Point
---
Boiling Point
181.9 C (1013 hPa, DIN 510751)
Colour
colourless (liquid) white (solid)
Vapor Pressure
at 20 C: 0.2 hPa at 50 C: 3 hPa
Colour Intensity
---
Decomposition Temperature
---
Ph
at 20 C, 10 g/L: 4 - 5
Flash Point
81 C (DIN EN ISO 2719)
Explosive Limits
---
Lower Explosive Limit
1.30 Vol-%
Evaporation Rate
no data available
Form
liquid (> 40.9 C) solid (< 40.9 C)
Flammability
595 C (VDE G1; EN T1)
Relative Density
---
Relative Evaporation Rate
---
Kinematic Viscosity
---
Voc Content
---
Vapor Density
no data available
Freezing Point
40.9 C
Softening Point
---
Upper Explosive Limit
9.00 Vol-%
Auto Ignition Temperature
no data available
Solubility In Water
at 20 C: 84 g/L at 25 C: 87 g/L at 68 C: completely miscible
Molecular Weight
94.11 g/mol
Solubility
---
Density
at 25 C: 1.13 g/cm (DIN 51 757)
Physical State
Form: liquid (> 40.9 C) solid (< 40.9 C)
Cloud Point
---
Solidification Point
---
Appearance
---
Melting Point
40.9 C
Dynamic Viscosity
at 50 C: 3.437 mPa*s
Physical State Data
---
Partition Coefficient
1.47 log P(o/w) (CPC)
Bulk Density
---
Properties Status
---
Metal Corrosion
---
Solubility In Fat
---
Odor
stinging
Odor Threshold
0.022 - 22 mg/m
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2312
Shipping Name
PHENOL, MOLTEN
Transport Class
Class 6.1
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Phenol, synthetic?

The signal word is danger.

What is the physical form of Phenol, synthetic?

Phenol, synthetic is a form: liquid (> 40.9 c) solid (< 40.9 c) with colourless (liquid) white (solid) color. It has stinging odor.

What is Phenol, synthetic used for?

General use: Phenol is an important raw material of the chemical industry. It is used for manufacturing of Bisphenol A, Phenol-Formaldehyde-Resins and Caprolactam. Furthermore it is used for manufacturing of Alkyl Phenols, Salicylic Acid and Nitrophenols. Identified uses: Industrial use: 0 Generic exposure scenario (GES): Industrial Processes relevant for Page 14 phenol and phenol containing products (ES 1 - 8) 1 Manufacture, processing and distribution of substances and mixtures * Page 47 2 Use in laboratories Page 51 3 Uses in coatings Page 54 4 Use in binders and release agents Page 57 5 Rubber production and processing Page 60 6 Polymer manufacturing Page 63 7 Polymer processing Page 66 8 Phenolic resin processing Page 69 Use of phenolic resins uses of downstream users (DU) Professional use: 10 Generic exposure scenario (GES): Professional Processes relevant Page 73 for phenol and phenol containing products (ES 11 - 16) 11 Use in laboratories Page 102 12 Uses in coatings Page 105 13 Use in binders and release agents Page 108 14 Polymer manufacturing Page 111 15 Polymer processing Page 114 16 Phenolic resin processing Page 117 Use of phenolic resins uses of downstream users (DU) - Examples for processing: use as an intermediate, use as a monomer etc., use as a solvent, use for the manufacturing of resins

What are the hazard statements for Phenol, synthetic?

This substance has 7 hazard statements:

  • H301: Toxic if swallowed.
  • H311: Toxic in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.
  • H341: Suspected of causing genetic defects.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Phenol, synthetic?

The melting point is 40.9 C and the boiling point is 181.9 C (1013 hPa, DIN 510751).

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