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Safety Data Sheet EN

Gasoline (All Grades)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Gasoline (All Grades)
Product Code
MSDS-7
Chemical Name
Petroleum Hydrocarbon
Synonyms
Motor Gasoline, Petrol, Gas, BS 7800, BS EN 228

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119471335-39-0096

Identified Uses

Motor Fuel.

Manufacturers & Suppliers

Murco Petroleum Limited logo

Murco Petroleum Limited

manufacturer

4 Beaconsfield Road, St.Albans, Hertfordshire, AL1 3RH

01727 892400

http://www.murco.co.uk/welcome.htm

Emergency Contacts

National Emergency Centre

0870 190 6777

7/24

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified na: r-phrases

Hazard Classifications

F+; R12
Carc. Cat. 1
Muta. Cat. 2
Xn; R65
Skin Irrit.
Aquatic Chronic

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Gasoline EC: 289-220-8 86290-81-5 89 - 100% Yes
Toluene EC: 203-625-9 108-88-3 20% Yes
Xylene EC: 215-535-7 1330-20-7 15% Yes
Ethyl Alcohol EC: 200-578-6 64-17-5 11% Yes
Ethylbenzene EC: 202-849-4 100-41-4 5% Yes
n-hexane EC: 203-777-6 110-54-3 5% Yes
Naphthalene EC: 202-049-5 91-20-3 5% Yes
1,2,4-Trimethylbenzene EC: 202-436-9 95-63-6 5% Yes
Trimethylbenzene EC: 247-099-9 25551-13-7 5% Yes
Benzene EC: 200-753-7 71-43-2 1% Yes

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK). Occupational exposure limits, if available, are listed in Section 8.

Notes

See Section 16 for the full text of the R-phrases declared above.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move exposed person to fresh air. Get medical attention if symptoms occur.

Skin contact

After contact with skin, wash immediately with plenty of soap and water. Get medical attention.

Eye contact

Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptoms occur.

Ingestion

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Call medical doctor or poison control centre immediately.

Immediate Medical Attention

Call medical doctor or poison control centre immediately. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Instructions

Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Large spill

Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Environmental

Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Prevent leaking substances from running into the aquatic environment or the sewage system.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: inert dry material, sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing mists or vapors. Avoid contact with skin. Use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapors may be evolved from heated or agitated material. Do not siphon by mouth. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put fuel into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapors and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices unless the devices are certified intrinsically safe. Prevent small spills and leakage to avoid slip hazard. Material may accumulate static.

Storage

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. Handle containers with care. Open slowly in order to control possible pressure release. Outside or detached storage preferred.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Use non-sparking tools and explosion-proof equipment. Eliminate all ignition sources. Storage containers should be grounded and bonded. Drums must be grounded and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Use gloves appropriate for work or task being performed. Recommended: If prolonged or repeated contact is likely, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves.

Eyes

Safety eyewear should be used when there is a likelihood of exposure. Recommended: Safety glasses with side shields.

Respiratory

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: No special requirements under ordinary conditions of use and with adequate ventilation.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Decomposition Temperature
---
Odor Threshold
---
Relative Density
0.72
Density
0.72 g/cm³
Molecular Weight
---
State Under Standard Conditions
---
Flash Point
<-40°C
Boiling Point
20°C
Colour
Clear (May Be Dyed).
Vapor Pressure
46.9 to 97.3 kPa [20°C]
Appearance
---
Odor
Petroleum/Solvent.
Ph
Not applicable.
Properties Status
---
Lower Explosive Limit
1.4%
Relative Evaporation Rate
---
Bulk Density
---
Explosive Limits
---
Partition Coefficient
---
Solubility In Water
Negligible.
Vapor Density
3 [Air = 1]
Solubility
Negligible.
Flammability
Not available.
Form
---
Physical State
Liquid.
Physical State Data
liquid
Dynamic Viscosity
---
Freezing Point
Not available.
Voc Content
---
Solidification Point
---
Kinematic Viscosity
<0.01 cm²/s (<1 cSt)
Metal Corrosion
---
Solubility In Fat
---
Colour Intensity
---
Evaporation Rate
>10 (butyl acetate = 1)
Melting Point
Not available.
Crystallisation Point
---
Auto Ignition Temperature
>254°C
Softening Point
---
Cloud Point
---
Upper Explosive Limit
7.5%
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Avoid release to the environment. Refer to special instructions/safety data sheet.

Incompatible

Highly reactive or incompatible with the following materials: oxidizing materials

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. This material and its container must be disposed of in a safe way. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1203
Shipping Name
GASOLINE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product contains substances for which Chemical Safety Assessments are still required.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Gasoline (All Grades) known by?

Gasoline (All Grades) is also known as: Motor Gasoline, Petrol, Gas, BS 7800, BS EN 228

What is the hazard signal word for Gasoline (All Grades)?

The signal word is na: r-phrases.

What is the physical form of Gasoline (All Grades)?

Gasoline (All Grades) is a liquid. with clear (may be dyed). color. It has petroleum/solvent. odor.

What is the solubility of Gasoline (All Grades)?

Negligible.

What is Gasoline (All Grades) used for?

Motor Fuel.

What is the melting point of Gasoline (All Grades)?

The melting point is Not available. and the boiling point is 20°C.

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