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Safety Data Sheet EN

Gasoline Blend

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Gasoline Blend
Product Code
817752

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Fuel

Uses advised against

Uses other than those covered by the exposure scenarios appended to this Safety Data Sheet are not supported.

Manufacturers & Suppliers

Phillips 66 Commercial Storage Ltd logo

Phillips 66 Commercial Storage Ltd

manufacturer

Portman House, 2 Portman Street, London, W1H 6DU, UK

+1 800 762 0942

http://www.Phillips66.com

Emergency Contacts

Emergency Contact

+44 (0)1469 555348

24 Hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1 H224
Asp. Tox. Cat. 1 H304
Skin Irrit. Cat. 2 H315
STOT SE Cat. 3 H336
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Repr. Cat. 2
Repr. Cat. 2
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H224 Extremely flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 Wear protective gloves / protective clothing / eye protection / face protection
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container to approved disposal facility.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Gasoline Blend. All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

Chemical Name CAS Number Concentration Hazardous
Naphtha (petroleum), full-range straight-run EC: 265-042-6 64741-42-0 100% Yes
Naphtha (petroleum), heavy catalytic cracked EC: 265-055-7 64741-54-4 100% Yes
Naphtha (petroleum), light catalytic cracked EC: 265-056-2 64741-55-5 100% Yes
Naphtha (petroleum), isomerization EC: 265-073-5 64741-70-4 100% Yes
Naphtha (petroleum), full-range alkylate, butane-contg. EC: 271-267-0 68527-27-5 100% Yes
Naphtha (petroleum), catalytic reformed EC: 273-271-8 68955-35-1 100% Yes
Gasoline (Benzine) EC: 289-220-8 86290-81-5 100% Yes
Naphtha (petroleum), hydrodesulfurized full-range EC: 295-433-7 92045-52-8 100% Yes
Toluene EC: 203-625-9 108-88-3 1 - 48% Yes
Benzene EC: 200-753-7 71-43-2 36% Yes
n-Hexane EC: 203-777-6 110-54-3 1 - 17% Yes

Total Sulfur: < 0.1

Notes

Regulation EC 1272/2008. Superseded Directives 67/548/EEC and 1999/45/EC.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If respiratory symptoms develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention.

Symptoms: respiratory symptoms

Skin contact

Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse.

Symptoms: irritation or redness

Eye contact

If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention.

Symptoms: irritation or redness

Ingestion

Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek medical attention.

Immediate Medical Attention

Seek medical attention.

Medical Treatment

Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents (e.g., in enclosed spaces or with deliberate abuse). The use of other drugs with less arrhythmogenic potential should be considered. If sympathomimetic drugs are administered, observe for the development of cardiac arrhythmias.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry chemical, carbon dioxide, or foam is recommended. Water spray is recommended to cool or protect exposed materials or structures.

Unsuitable media

Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Water may be ineffective for extinguishment, unless used under favorable conditions by experienced fire fighters.

Specific hazards

Extremely flammable. This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe). Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire.

Instructions

Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Avoid spreading burning liquid with water used for cooling purposes. Cool equipment exposed to fire with water, if it can be done safely.

Firefighter Protection

For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stay upwind and away from spill/release. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely.

Large spill

Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out.

Environmental

Use water sparingly to minimize environmental contamination and reduce disposal requirements.

Cleanup methods

Immediate cleanup of any spill is recommended. Absorb spill with inert material. If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal.

Materials: sand or vermiculite

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from ignition sources such as heat/sparks/open flame – No smoking. Take precautionary measures against static discharge. Nonsparking tools should be used. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment. Open container slowly to relieve any pressure. Do not enter confined spaces such as tanks or pits without following proper entry procedures. Do not wear contaminated clothing or shoes.

Storage

Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post area 'No Smoking or Open Flame.' Protect container(s) against physical damage. Outdoor or detached storage is preferred.

Hygiene

Wash thoroughly after handling. Use good personal hygiene practices. Do not wear contaminated clothing or shoes.

Fire prevention

Keep away from ignition sources such as heat/sparks/open flame – No smoking. Take precautionary measures against static discharge. Nonsparking tools should be used. Grounding and bonding containers and equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required.

Hands

The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Suggested protective materials: Viton (fluoroelastomers)

Eyes

The use of eye protection that meets or exceeds EN 166 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, close fitting eye protection and a face shield may be necessary.

Respiratory

Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type A, organic gases and vapour filters (as specified by the manufacturer) may be used. A respiratory protection program that follows recommendations for the selection, use, care and maintenance of respiratory protective devices in EN 529:2005 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health.

Skin/Body

Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits.

Environmental

Refer to Sections 6, 7, 12 and 13.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear to yellow-green
Colour
Clear to yellow-green
Colour Intensity
---
Form
Liquid
Odor
Petroleum
Odor Threshold
N/D
Ph
---
Melting Point
N/D
Boiling Point
20 - 220 °C
Flash Point
< -40 °C; (estimate)
Freezing Point
N/D
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
N/D
Vapor Pressure
1-100 kPa @38°C
Vapor Density
---
Relative Density
0.68-0.88 @ 15°C
Bulk Density
---
Density
---
Flammability
Extremely Flammable
Upper Explosive Limit
N/D
Lower Explosive Limit
N/D
Explosive Limits
---
Auto Ignition Temperature
N/D
Decomposition Temperature
N/D
Solubility
Solubility in water: Negligible
Partition Coefficient
N/D
Solubility In Water
Negligible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
N/D
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal ambient and anticipated conditions of use.

Reactivity

Not chemically reactive.

Hazardous reactions

Hazardous reactions not anticipated.

Avoid

Avoid high temperatures and all sources of ignition. Prevent vapor accumulation.

Decomposition

Not anticipated under normal conditions of use.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal must be in accordance with Directive 2006/12/EC and other applicable national or regional provisions. For incineration of waste, follow Directive 2000/76/EC. For landfill of waste, follow Directive 1999/31/EC.

Disposal

Waste generators/producers are responsible for assessing the actual process used when generating the waste and it's contaminants in order to assign the proper waste disposal code.

Waste Codes

13 08 99* (oil) wastes not otherwise specified EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1268
Shipping Name
PETROLEUM DISTILLATES, N.O.S. (Contains Naphtha)
Transport Class
3 (N2, CMR, F)
Packing Group
I
IMDG

If transported in bulk by marine vessel in international waters, product is being carried under the scope of MARPOL Annex I.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

EN166:2002 Eye Protection, EN 529:2005 Respiratory Protective devices, BS EN 374-1:2003 Protective gloves against chemicals and micro-organisms. Export Rating: NLR (No License Required).

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Gasoline Blend?

The signal word is danger.

What is the physical form of Gasoline Blend?

Gasoline Blend is a liquid appearing as clear to yellow-green with clear to yellow-green color. It has petroleum odor.

What is the solubility of Gasoline Blend?

Solubility in water: Negligible

What is Gasoline Blend used for?

Fuel

What are the hazard statements for Gasoline Blend?

This substance has 8 hazard statements:

  • H224: Extremely flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways
  • H315: Causes skin irritation
  • H336: May cause drowsiness or dizziness
  • H340: May cause genetic defects
  • H350: May cause cancer
  • H361: Suspected of damaging fertility or the unborn child.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Gasoline Blend?

The melting point is N/D and the boiling point is 20 - 220 °C.

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