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Safety Data Sheet EN

(+)-Longifolene

CAS 475-20-7
EC 207-491-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
(+)-Longifolene
Product Code
PHL82581
Chemical Name
[1S-(1α,3aβ,4α,8aβ)]-Decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene

Regulatory Identifiers

CAS Number
475-20-7 Check regulations →
EC Number
207-491-2 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich BVBA/SPRL

distributor

Pegasuslaan 5 B-1831 DIEGEM

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Sens. Cat. 1 H317
Asp. Tox. Cat. 1 H304
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves.
P301 + P310 + P331 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of water.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
[1S-(1α,3aβ,4α,8aβ)]-Decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene EC: 207-491-2 475-20-7 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Immediate Medical Attention

No data available

Medical Treatment

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Upper Explosive Limit
No data available
Auto Ignition Temperature
No data available
Kinematic Viscosity
---
Solubility In Water
No data available
State Under Standard Conditions
---
Relative Evaporation Rate
---
Explosive Limits
---
Relative Density
0,9284 g/cm3
Flash Point
101,00 °C - closed cup
Form
liquid
Solidification Point
---
Crystallisation Point
---
Boiling Point
258 - 260 °C at 1.013 hPa
Physical State Data
liquid
Colour Intensity
---
Density
---
Flammability
No data available
Odor Threshold
No data available
Partition Coefficient
No data available
Dynamic Viscosity
---
Solubility In Fat
---
Properties Status
---
Melting Point
No data available
Ph
No data available
Colour
colourless
Appearance
liquid, clear
Physical State
liquid
Odor
No data available
Freezing Point
No data available
Cloud Point
---
Softening Point
---
Vapor Pressure
No data available
Solubility
---
Vapor Density
No data available
Metal Corrosion
---
Evaporation Rate
No data available
Molecular Weight
---
Bulk Density
---
Voc Content
---
Decomposition Temperature
No data available
Lower Explosive Limit
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Incompatible

Strong oxidizing agents

Decomposition

Hazardous decomposition products formed under fire conditions. - Carbon oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
III
ADR

EHS-Mark required (ADR 2.2.9.1.10) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

IMDG

EHS-Mark required (IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

IATA

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for (+)-Longifolene?

The signal word is danger.

What is the physical form of (+)-Longifolene?

(+)-Longifolene is a liquid appearing as liquid, clear with colourless color. It has no data available odor.

What is (+)-Longifolene used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for (+)-Longifolene?

This substance has 3 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H317: May cause an allergic skin reaction.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of (+)-Longifolene?

The melting point is No data available and the boiling point is 258 - 260 °C at 1.013 hPa.

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