Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- (+)-Longifolene
- Product Code
- PHL82581
Regulatory Identifiers
- CAS Number
- 475-20-7 Check regulations →
- REACH No.
- A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.
Identified Uses
Laboratory chemicals, Manufacture of substances
Manufacturers & Suppliers
Sigma-Aldrich BVBA/SPRL
distributor
Pegasuslaan 5, B-1831 DIEGEM
+32 (0)3 899-1301
Emergency Contacts
CHEMTREC
+(32) 28 083237
Anti-poison centre
070 245245
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS07
GHS08
GHS09
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| [1S-(1α,3aβ,4α,8aβ)]-Decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene EC: 207-491-2 | 475-20-7 | 100% | Yes |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Notes
For the full text of the H-Statements mentioned in this Section, see Section 16.
First Aid Measures
Emergency procedures for chemical exposure incidents
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Wash off with soap and plenty of water. Consult a physician.
Flush eyes with water as a precaution.
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Carbon oxides
Firefighter Protection
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
Materials: inert absorbent material
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2.
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Handle in accordance with good industrial hygiene and safety practice.
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Stable under recommended storage conditions.
No data available
No data available
No data available
Strong oxidizing agents
Hazardous decomposition products formed under fire conditions. - Carbon oxides. Other decomposition products - No data available. In the event of fire: see section 5
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Offer surplus and non-recyclable solutions to a licensed disposal company.
Leave chemicals in original containers. No mixing with other waste.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 3082
- Shipping Name
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ([1S-(1α,3aβ,4α,8aβ)]-Decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene)
- Transport Class
- 9
- Packing Group
- III
EHS-Mark required (ADR 2.2.9.1.10)
EHS-Mark required (IMDG code 2.10.3)
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for (+)-Longifolene?
The signal word is danger.
What is the physical form of (+)-Longifolene?
(+)-Longifolene is a liquid appearing as liquid, clear with colourless color. It has no data available odor.
What is (+)-Longifolene used for?
Laboratory chemicals, Manufacture of substances
What are the hazard statements for (+)-Longifolene?
This substance has 3 hazard statements:
- H304: May be fatal if swallowed and enters airways.
- H317: May cause an allergic skin reaction.
- H410: Very toxic to aquatic life with long lasting effects.
What is the melting point of (+)-Longifolene?
The melting point is No data available and the boiling point is 258 - 260 °C.