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Safety Data Sheet EN

Lithium ion batteries, rechargeable

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Lithium ion batteries, rechargeable
Synonyms
Milwaukee Lithium Ion Batteries

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Product category AC3 – Electrical batteries and accumulators

Manufacturers & Suppliers

Techtronic Industries GmbH logo

Techtronic Industries GmbH

manufacturer

Max-Eyth-Straße 10, 71364 Winnenden, Germany

+49 7195 120

http://www.ttigroup.com

Emergency Contacts

Chemtrec International

+1 703-741-5970

24-hour service

Chemtrec United States only

1-800-424-9300

24-hour service

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Rechargeable lithium ion battery pack. Cathode: Li, Ni, Co & Mn oxides (active substances); phosphates. Polyvinyl difluoride/SBR (binder). Carbon (conductive material), additives, aluminium foil. Anode: Carbon (active substance). Silicone, polyvinyl difluoride/SBR (binder), additives, copper foil. Electrolyte: Organic solvent (non-aqueous liquid), lithium salt, additives.

Chemical Name CAS Number Concentration Hazardous
Aluminium EC: 231-072-3 7429-90-5 0.1 - 10% No
Biphenyl EC: 202-163-5 92-52-4 0.1 - 0.3% No
Copper EC: 231-159-6 7440-50-8 0.1 - 10% No
Linear and cyclic carbonate solutions --- 17% No
Carbon EC: 231-153-3 7440-44-0 10 - 30% No
Metal oxide or other electrolyte (proprietary) --- 10 - 50% No
Lithium hexafluorophosphate (1-) EC: 244-334-7 21324-40-3 5% No
Polyvinyl difluoride EC: 607-458-6 24937-79-9 0.1 - 5% No
Styrene-butadiene rubber (SBR) --- 5% No
Aluminium, steel, nickel, and other inert materials --- --- No

Cathode: Li, Ni, Co & Mn oxides (active substances); phosphates, Polyvinyl difluoride/SBR (binder), Carbon (conductive material), additives, aluminium foil. Anode: Carbon (active substance), Silicone, polyvinyl difluoride/SBR (binder), additives, copper foil. Electrolyte: Organic solvent (non-aqueous liquid), lithium salt, additives.

Notes

Contact with the ingredients is not possible under normal operating conditions.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of intense smoke formation or release of gas, leave the room immediately. In case of relatively large amounts and irritation of the respiratory tract, seek medical attention. Provide adequate ventilation as much as possible.

Skin contact

In case of skin or eye contact, rinse the affected areas thoroughly with water for at least 15 minutes.

Eye contact

In case of skin or eye contact, rinse the affected areas thoroughly with water for at least 15 minutes. In case of eye contact, always contact a doctor in addition to thorough rinsing.

Ingestion

Rinse mouth and surrounding areas with water. Seek medical attention immediately.

Immediate Medical Attention

In case of eye contact, always contact a doctor in addition to thorough rinsing. In case of relatively large amounts and irritation of the respiratory tract, seek medical attention. Seek medical attention immediately (for swallowing). It is strongly recommended to contact a doctor in the event of burns.

Medical Treatment

Suitable treatment is necessary in the event of burns. It is strongly recommended to contact a doctor.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Always use water spray to fight fires with lithium ion batteries. No special extinguishing media are required. Conventional extinguishing media should be used to fight fires in the vicinity of the batteries.

Specific hazards

In the event of a fire, gases can be formed which are harmful to health when inhaled.

Instructions

Reduce the fire burden by singling out large quantities and removing them from the hazard area.

Firefighter Protection

Ensure adequate respiratory protection. Use self-contained respiratory equipment. Observe local regulations and ensure adequate ventilation.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Rinse with copious amounts of water.

Environmental

Avoid seepage into the sewer system and/or soil.

Cleanup methods

Electrolyte traces can be soaked up with dry paper towels.

Materials: dry paper towels

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle discharged batteries carefully. Avoid exposure to physical effects and/or blows. Keep batteries away from other metallic objects (paper clips, coins, keys, screws). Avoid contact with leaky batteries. Do not expose batteries to fire or high temperatures (>85°C). Do not dismantle batteries. Do not immerse batteries in liquids. Recharge batteries only in battery chargers recommended by the manufacturer. Use batteries only in the electrical tools and garden implements for which they are intended. Do not use batteries which are damaged or in abnormal condition.

Storage

Store in a dry place at room temperature (max. 50°C). Avoid large temperature variations (do not store close to heaters, avoid long-term exposure to direct sunlight, etc.).

Hygiene

In case of accidental contact with liquid from a battery, rinse with water. If the liquid comes in contact with the eyes, seek medical attention.

Fire prevention

Do not expose batteries to fire or high temperatures. Do not incinerate batteries except in a waste incinerator approved for that purpose.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Protective gloves with CE mark conforming to category III of EN 374.

Eyes

Closed safety glasses or goggles

Skin/Body

Protective clothing

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Freezing Point
Not applicable
Molecular Weight
---
Form
Compact batteries with (plastic) enclosure and electrical terminals
Kinematic Viscosity
Not applicable
Evaporation Rate
---
Odor Threshold
Not applicable
Partition Coefficient
Not applicable
Metal Corrosion
---
Vapor Pressure
Not applicable
Decomposition Temperature
Not determined
Boiling Point
Not applicable
Relative Density
---
Properties Status
---
Crystallisation Point
---
Appearance
---
Density
Not determined
Physical State Data
solid
Upper Explosive Limit
Not determined
Solubility
Insoluble
Explosive Limits
---
Colour Intensity
---
Dynamic Viscosity
Not applicable
Physical State
Compact batteries with (plastic) enclosure and electrical terminals
Ph
Not applicable
Lower Explosive Limit
Not determined
Cloud Point
---
Odor
Odourless
Solidification Point
---
Flash Point
Not applicable
Solubility In Fat
---
Colour
Black
Relative Evaporation Rate
---
Bulk Density
---
Vapor Density
---
Flammability
Not determined
Voc Content
---
State Under Standard Conditions
---
Auto Ignition Temperature
Not determined
Melting Point
Not applicable
Solubility In Water
Insoluble
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition when used as intended

Hazardous reactions

No hazardous reactions known

Avoid

If the upper temperature limit (e.g. 130°C) is exceeded, there is a risk that the batteries may burst or that the pressure relief vent may open. Storage temperatures above 60°C can lead to accelerated ageing and premature loss of functionality.

Incompatible

Strong oxidants, strong acids, electrically conductive materials

Decomposition

Vapours harmful to health are released in the event of fire.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of the battery pack in accordance with national regulations. Used batteries must be taken back (at no charge) by the sales point or handed in to a disposal facility (industrial or commercial).

Disposal

In the EU, used batteries may not be disposed of as household waste and may not be mixed with batteries of different types, in order to avoid difficulties with recycling and hazards to people and the environment.

Waste Codes

16 06 05 Other batteries and accumulators EWC
20 01 34 Batteries and accumulators other than those falling under 20 01 33 EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3480 / 3481
Shipping Name
LITHIUM ION BATTERIES / LITHIUM ION BATTERIES IN EQUIPMENT / LITHIUM ION BATTERIES PACKAGED WITH EQUIPMENT
Transport Class
9
IMDG

188, 230b, 376, 377

IATA

None A general transport prohibition applies to air transport (IATA Special Provision A154). Air transport of waste batteries and batteries shipped to recycling or disposal facilities is prohibited (IATA Special Provision A183).

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Transport regulations according to IATA, ADR, IMDG, RID. See also Section 14.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Lithium ion batteries, rechargeable known by?

Lithium ion batteries, rechargeable is also known as: Milwaukee Lithium Ion Batteries

What is the hazard signal word for Lithium ion batteries, rechargeable?

The signal word is no signal word.

What is the physical form of Lithium ion batteries, rechargeable?

Lithium ion batteries, rechargeable is a compact batteries with (plastic) enclosure and electrical terminals with black color. It has odourless odor.

What is the solubility of Lithium ion batteries, rechargeable?

Insoluble

What is Lithium ion batteries, rechargeable used for?

Product category AC3 – Electrical batteries and accumulators

What is the melting point of Lithium ion batteries, rechargeable?

The melting point is Not applicable and the boiling point is Not applicable.