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Safety Data Sheet EN

NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%
Product Code
MSDS 1005 (99-0013, 99-0020, 99-0027, 99-0109, 99-0135, 99-0160, 99-0193)

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Calibration of Monitoring and Research Equipment

Manufacturers & Suppliers

P

PortaGAS, Inc.

manufacturer

1202 E. Sam Houston Pkwy S., Pasadena, TX 77503

(713) 928-6477

Emergency Contacts

TOLL-FREE in USA/Canada

(800)255-3924

International calls

+1 813 248 0585

Australian Poison Control

13 11 26

Australian Fire Brigade

000

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Asp. Tox. Cat. 1 H304
Press. Gas (Comp.) H280
Acute Tox. Cat. 3 H331

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS04 - Compressed gas

GHS04

GHS07 - Health hazard

GHS07

Hazard Statements

H270 May cause or intensify fire, oxidizer.
H280 Contains gas under pressure, may explode if heated.
H304 May be fatal if swallowed and enters airways.
H331 Toxic if inhaled.

Precautionary Statements

Keep container in a well-ventilated area.
Do not breathe gas.
Wear suitable protective clothing and gloves.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Carbon Monoxide EC: 211-128-3 630-08-0 0.0005 - 1% Yes
Hydrogen EC: 215-605-7 1333-74-0 2% Yes
Methane EC: 200-812-7 74-82-8 2.5% Yes
Oxygen EC: 231-956-9 7782-44-7 23.5% Yes
Nitrogen EC: 231-783-9 7727-37-9 --- Yes

Note: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: 2000 .

Notes

None of the trace impurities in this product contribute significantly to the hazards associated with the product. All hazard information pertinent to the product has been provided in this Material Safety Data sheet., per the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and State equivalent standards

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If any adverse symptom develops after over-exposure to this gas mixture, remove victim(s) to fresh air as quickly as possible. Only trained personnel should administer supplemental oxygen and/or cardio-pulmonary resuscitation if necessary.

Immediate Medical Attention

Victim(s) who experience any adverse effect after over-exposure to this gas mixture must be taken for medical attention.

Medical Treatment

Treat symptoms and reduce over-exposure. Provide oxygen.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing media appropriate for surrounding fire.

Specific hazards

This gas mixture is not flammable; however, containers, when involved in fire, may rupture or burst in the heat of the fire.

Instructions

Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment.

Firefighter Protection

Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Clear the affected area, protect people, and respond with trained personnel. In the event of a release in which the atmosphere is unknown, and in which other chemicals are potentially involved, evacuate immediate area.

Cleanup methods

Secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated area or outdoors. Allow the gas mixture to dissipate.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Be aware of any signs of dizziness or fatigue; exposures to fatal concentrations of this product could occur without any significant warning symptoms, due to oxygen deficiency. Do not attempt to repair, adjust, or in any other way modify the cylinders containing Carbon Monoxide. If there is a malfunction or another type of operational problem, contact nearest distributor immediately. Use equipment designed for these specific cylinders. Ensure all lines and equipment are rated for proper service pressure.

Storage

Cylinders should be firmly secured to prevent falling or being knocked-over. Cylinders must be protected from the environment, and preferably kept at room temperature (approximately 21°C, 70°F). Cylinders should be stored in dry, well-ventilated areas, away from sources of heat, ignition, and direct sunlight. Protect cylinders against physical damage. Full and empty cylinders should be segregated. Use a first-in, first-out inventory system to prevent full containers from being stored for long periods of time.

Hygiene

Be aware of any signs of dizziness or fatigue.

Fire prevention

Stored away from sources of heat, ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special ventilation systems or engineering controls are needed under normal circumstances of use. As with all chemicals, use this gas mixture in well-ventilated areas. If this gas mixture is used in a poorly-ventilated area, install automatic monitoring equipment to detect the levels of oxygen.

Hands

No special protection is needed under normal circumstances of use. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada.

Eyes

Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards.

Respiratory

No special respiratory protection is required under normal circumstances of use. Use supplied air respiratory protection if the levels of components exceed exposure limits presented in Section 2 (Composition and Information of Ingredients) and Oxygen levels are below 19.5%, or unknown, during emergency response to a release of this gas mixture. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA Standard Z94.4-93 and applicable standards of Canadian Provinces. Oxygen levels below 19.16.33% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full face piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).

Skin/Body

No special protection is needed under normal circumstances of use. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Fat
---
Cloud Point
---
Colour
colorless
Explosive Limits
---
Vapor Density
---
State Under Standard Conditions
---
Evaporation Rate
Not applicable.
Colour Intensity
---
Properties Status
---
Partition Coefficient
Not applicable.
Flammability
---
Solubility In Water
0.023
Odor Threshold
Not applicable. Odorless.
Softening Point
---
Odor
odorless
Melting Point
-210°C (-345.8°F)
Lower Explosive Limit
---
Decomposition Temperature
---
Voc Content
---
Form
gas
Molecular Weight
28.01
Auto Ignition Temperature
---
Appearance
colorless, odorless gas
Ph
Not applicable.
Crystallisation Point
---
Dynamic Viscosity
---
Solidification Point
---
Kinematic Viscosity
---
Boiling Point
-320.4°F (-195.8°C)
Upper Explosive Limit
---
Relative Evaporation Rate
---
Bulk Density
---
Solubility
---
Physical State Data
gas
Vapor Pressure
Not applicable.
Metal Corrosion
---
Flash Point
---
Relative Density
0.906
Density
.072 lbs/ ft [3] (1.153 kg/m [3])
Physical State
gas
Freezing Point
-210°C (-345.8°F)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Normally stable in gaseous state.

Hazardous reactions

Will not occur.

Avoid

Contact with incompatible materials. Cylinders exposed to high temperatures or direct flame can rupture or burst.

Incompatible

Titanium will burn in Nitrogen (the main component of this product). Lithium reacts slowly with Nitrogen at ambient temperatures. Components of this product (Hydrogen, Carbon Monoxide, Methane) are also incompatible with strong oxidizers (i.e. chlorine, bromine pentafluoride, oxygen, oxygen difluoride, and nitrogen trifluoride). Carbon Monoxide is mildly corrosive to nickel and iron (especially at high temperatures and pressures).

Decomposition

The thermal decomposition products of Methane include carbon oxides. The other components of this gas mixture do not decompose, per se, but can react with other compounds in the heat of a fire.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Cylinders with undesired residual product may be safely vented outdoors with the proper regulator.

Disposal

Waste disposal must be in accordance with appropriate Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1956
Shipping Name
Compressed gases, n.o.s. (Oxygen, Nitrogen)
Transport Class
2.2 (Non-Flammable Gas)
Packing Group
Not applicable.
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%?

The signal word is danger.

What is the physical form of NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%?

NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5% is a gas appearing as colorless, odorless gas with colorless color. It has odorless odor.

What is NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5% used for?

Calibration of Monitoring and Research Equipment

What are the hazard statements for NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%?

This substance has 4 hazard statements:

  • H270: May cause or intensify fire, oxidizer.
  • H280: Contains gas under pressure, may explode if heated.
  • H304: May be fatal if swallowed and enters airways.
  • H331: Toxic if inhaled.

What is the melting point of NON-FLAMMABLE GAS MIXTURE Containing One or More of the Following Components in a Nitrogen Balance Gas: Carbon Monoxide, 0.0005 – 1.0%; Hydrogen, 0 – 2.0%; Methane, 0 – 2.5%; Oxygen, 0 – 23.5%?

The melting point is -210°C (-345.8°F) and the boiling point is -320.4°F (-195.8°C).