NextSDS Logo
Safety Data Sheet EN

Chlorobenzene

Scan your chemical compliance

Free 10-second scan. Upload a document and check compliance instantly.

Scan Now
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chlorobenzene
Product Code
B254-4; B254-4LC; B254-20; B254RS-200; B255-1; B255-500

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness

Precautionary Statements

Use only outdoors or in a well-ventilated area
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Get medical attention/advice if you feel unwell
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant

Manage your Safety Data Sheets

Organize and access chemical safety data with ease

Manage SDS
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Chlorobenzene 108-90-7 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Immediate Medical Attention

Obtain medical attention. Get medical attention if symptoms occur. If skin irritation persists, call a physician.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable media

Water may be ineffective

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition.

Fire prevention

Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

No protective equipment is needed under normal use conditions.

Skin/Body

Long sleeved clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
---
Colour Intensity
---
Form
---
Odor
bitter almond
Odor Threshold
No information available
Ph
Not applicable
Melting Point
-45 °C / -49 °F
Boiling Point
131 °C / 267.8 °F
Flash Point
23 °C / 73.4 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
1 (Butyl Acetate = 1.0)
Vapor Pressure
12 mbar @ 20°C
Vapor Density
3.9
Relative Density
1.108
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
9.6 vol %
Lower Explosive Limit
1.8 vol %
Explosive Limits
---
Auto Ignition Temperature
590 °C / 1094 °F
Decomposition Temperature
> 132°C
Solubility
Insoluble in water
Partition Coefficient
No data available
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
112.56
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.8 mPa.s @ 20°C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Bases, Strong reducing agents, Metals

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas, Phosgene

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12. Ecological information

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. | Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Chlorobenzene | EC50: = 12.5 mg/L, 96h static (Pseudokirchneriella subcapitata) EC50: 2.55 - 420 mg/L, 96h (Pseudokirchneriella subcapitata) | LC50: 36.35 - 58.19 mg/L, 96h static (Poecilia reticulata) LC50: = 91 mg/L, 96h static (Brachydanio rerio) LC50: 4.1 - 5.3 mg/L, 96h flow-through (Oncorhynchus mykiss) LC50: 4.1 - 4.9 mg/L, 96h static (Lepomis macrochirus) LC50: 6.9 - 7.9 mg/L, 96h flow-through (Lepomis macrochirus) LC50: = 4.5 mg/L, 96h static (Pimephales promelas) LC50: 7 - 8.5 mg/L, 96h flow-through (Pimephales promelas) | Not listed | EC50: = 0.59 mg/L, 48h (Daphnia magna) |

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Persistence and Degradability

Persistence and Degradability Persistence is unlikely based on information available. Soluble in water

Persistence is unlikely based on information available. Soluble in water

Bioaccumulation/ Accumulation

Bioaccumulation/ Accumulation No information available.

No information available.

Mobility

. Will likely be mobile in the environment due to its water solubility. | Component | log Pow | | --- | --- | | Chlorobenzene | 2.8 |

Will likely be mobile in the environment due to its water solubility.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Waste Codes

U037 U Series Waste for Chlorobenzene (108-90-7) RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1134
Shipping Name
CHLOROBENZENE
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is classified and labeled according to EC directives or corresponding national laws. The product is classified and labeled in accordance with Directive 1999/45/EC Europe.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chlorobenzene?

The signal word is warning.

What is the physical form of Chlorobenzene?

Chlorobenzene is a liquid appearing as clear . It has bitter almond odor.

What is the solubility of Chlorobenzene?

Insoluble in water

What is Chlorobenzene used for?

Laboratory chemicals.

What are the hazard statements for Chlorobenzene?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H332: Harmful if inhaled
  • H336: May cause drowsiness or dizziness

What is the melting point of Chlorobenzene?

The melting point is -45 °C / -49 °F and the boiling point is 131 °C / 267.8 °F.

Compliance Scanner

Scan your compliance