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FORMIC ACID

DANGER liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
FORMIC ACID
Product Code
0128

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Overview

FORMIC ACID is a colorless substance .

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GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 3
Met. Corr. Category 1
Acute Tox. Category 4
Skin Corr. Category 1A
Eye Dam. Category 1
STOT SE Category 3

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS05 GHS Hazard Pictogram: Corrosive hazard - Materials that can cause severe skin burns and eye damage

GHS05

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H226: Flammable liquid and vapor.
  • H290: May be corrosive to metals.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.

Precautionary Statements

  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Keep only in original container.
  • Ground and bond container and receiving equipment.
  • Use explosion-proof electrical/ventilating/lighting/equipment.
  • Use only non-sparking tools.
  • Take precautionary measures against static discharge.
  • Wear protective gloves/protective clothing/eye protection/face protection.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Do not breathe dust/mist/vapors/spray.
  • Use only outdoors or in a well-ventilated area.
  • In case of fire: Use water spray, foam, dry powder or carbon dioxide for extinction.
  • Immediately call a POISON CENTER or doctor/physician.
  • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
  • Wash contaminated clothing before reuse.
  • IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • Absorb spillage to prevent material damage.
  • Store locked up.
  • Store in a well-ventilated place. Keep cool.
  • Keep container tightly closed.
  • Store in corrosive resistant container with a resistant inner liner.
  • Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Avantor Performance Materials, Inc.

manufacturer

πŸ“

3477 Corporate Parkway, Suite 200 Center Valley, PA 18034

🌍

US

πŸ“ž

855-282-6867

πŸ“ 

610-573-2610

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

CHEMTREC

πŸ“ž

1-800-424-9300

🌍

US

πŸ’‘

within US and Canada

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

substance

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
FORMIC ACID 64-18-6 88-100% βœ“ Non-hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

🫁 Inhalation Exposure

Move to fresh air. Get medical attention if symptoms persist. Apply artificial respiration if victim is not breathing if breathing is difficult, give oxygen.

Symptoms:

Mist or vapor extremely irritating to eyes and respiratory tract.

πŸ–οΈ Skin Contact

Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes.

Symptoms:

Causes severe skin and eye burns.

πŸ‘οΈ Eye Contact

Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. In case of irritation from airborne exposure, move to fresh air. Get medical attention immediately.

Symptoms:

Causes severe skin and eye burns. Mist or vapor extremely irritating to eyes and respiratory tract.

🍽️ Ingestion/Swallowing

Call a physician or poison control center immediately. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Symptoms:

Causes digestive tract burns.

🚨 Immediate Medical Attention Required

Call a physician or poison control center immediately. Get medical attention if symptoms persist. Get medical attention immediately.

Medical Treatment

Symptoms may be delayed. Treat symptomatically.

Fire Fighting Measures & Emergency Response

Fire suppression methods, extinguishing media, and firefighting safety procedures

βœ… Suitable Extinguishing Media

Water spray, foam, dry powder or carbon dioxide.

❌ Unsuitable Extinguishing Media

Avoid water in straight hose stream; will scatter and spread fire.

⚠️ Specific Fire Hazards

Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance to a source of ignition and flash back. Prevent buildup of vapors or gases to explosive concentrations. Heat may cause the containers to explode.

πŸ”₯ Fire Fighting Instructions

Move containers from fire area if you can do so without risk. Use water spray to keep fire-exposed containers cool. Cool containers exposed to flames with water until well after the fire is out. Fight fire from a protected location.

πŸ›‘οΈ Firefighter Protection Equipment

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Accidental Release Measures & Spill Response

Emergency spill cleanup procedures, containment methods, and environmental protection

🚨 Emergency Procedures

Keep unauthorized personnel away. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep upwind. Ventilate closed spaces before entering them. See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

🌊 Large Spill Procedures

Dike far ahead of larger spill for later recovery and disposal. Inform authorities if large amounts are involved.

🌍 Environmental Precautions

Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

🧹 Cleanup Methods

Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination.

Cleanup Materials:

vermiculite or other inert material

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

πŸ“Š Molecular Weight
46.02 g/mol (CHβ‚‚Oβ‚‚)
🧊 Melting Point
8.4 Β°C
Critical Property
βš–οΈ Density
Not available
πŸ“Š Voc Content
Not available
πŸ’§ Solubility
No data available.
πŸ“Š Decomposition Temperature
No data available.
πŸ“Š Relative Evaporation Rate
2.1 (butyl acetate=1)
πŸ“Š Properties Status
Not available
πŸ“Š Vapor Density
1.59 AIR=1
πŸ“Š Cloud Point
Not available
πŸ“Š Crystallisation Point
Not available
πŸ“Š Odor Threshold
No data available.
πŸ§ͺ Physical State
liquid
Critical Property
πŸ’¨ Vapor Pressure
5.680 kPa (25 Β°C)
πŸ“Š Partition Coefficient
-0.54
πŸ§ͺ Ph
No data available.
πŸ“Š State Under Standard Conditions
Not available
πŸ‘οΈ Appearance
Colorless
πŸ“Š Bulk Density
217.44 kg/mΒ³ (20 Β°C)
πŸ“Š Solidification Point
Not available
πŸ“Š Colour Intensity
Not available
πŸ“Š Freezing Point
8.4 Β°C
πŸ“Š Softening Point
Not available
πŸ’¨ Boiling Point
100.8 Β°C
Critical Property
πŸ’¨ Evaporation Rate
2.1 (butyl acetate=1)
πŸ“Š Physical State Data
liquid
πŸ”₯ Flash Point
50 Β°C (Closed Cup)
Critical Property
πŸ“Š Dynamic Viscosity
Not available
πŸ“Š Kinematic Viscosity
Not available
πŸ“Š Lower Explosive Limit
No data available.
πŸ‘ƒ Odor
Characteristic, Pungent
πŸ“Š Upper Explosive Limit
No data available.
πŸ“Š Explosive Limits
Not available
πŸ“Š Form
liquid
πŸ“Š Solubility In Water
Miscible with water.
πŸ“Š Auto Ignition Temperature
505 Β°C
πŸ“Š Metal Corrosion
Not available
πŸ”₯ Flammability
Class II Combustible Liquid
πŸ“Š Relative Density
1.22 (20 Β°C)
🎨 Colour
Colorless
πŸ“Š Solubility In Fat
Not available

Safe Handling & Storage Procedures

Industrial handling precautions, storage conditions, and workplace safety requirements

⚠️ Handling Precautions

β€’ DO NOT handle, store or open near an open flame, sources of heat or sources of ignition.

β€’ Protect material from direct sunlight.

β€’ Take precautionary measures against static discharges.

β€’ Use personal protective equipment as required.

β€’ Do not breathe mist or vapor.

β€’ Do not get in eyes, on skin, on clothing.

β€’ Do not taste or swallow.

β€’ Use only with adequate ventilation.

β€’ Wash hands thoroughly after handling.

β€’ Use caution when adding this material to water.

β€’ Always add acid to water while stirring to prevent release of heat, steam and fumes.

β€’ See Section 8 of the SDS for Personal Protective Equipment.

πŸͺ Storage Conditions

β€’ Keep container tightly closed in a cool, well-ventilated place.

β€’ Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids.

🧼 General Hygiene Measures

Wash hands thoroughly after handling. Do not get in eyes, on skin, on clothing. Do not taste or swallow.

πŸ”₯ Fire Prevention Measures

DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Take precautionary measures against static discharges.

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

🏭 Engineering Controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Use explosion-proof ventilation equipment.

🧀 Hand Protection

Chemical resistant gloves

πŸ‘οΈ Eye Protection

Wear safety glasses with side shields (or goggles) and a face shield.

😷 Respiratory Protection

If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn.

🦺 Skin/Body Protection

Wear suitable protective clothing.

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

βœ… Chemical Stability

Material is stable under normal conditions.

βš—οΈ Reactivity

No dangerous reaction known under conditions of normal use.

⚠️ Hazardous Reactions

Hazardous polymerization does not occur.

🚫 Conditions to Avoid

Heat, sparks, flames. Contact with incompatible materials.

πŸ§ͺ Incompatible Materials

Strong oxidizing agents. Sulfuric acid. Caustics. Hydrogen peroxide (H_{2}O_{2}) Strong bases. Metals.

πŸ’¨ Hazardous Decomposition Products

Thermal decomposition may release oxides of carbon.

Ecological Information & Environmental Impact

Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data

🌱 Ecotoxicity

Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): FORMIC ACID LC 50 (Bluegill (Lepomis macrochirus), 24 h): 175 mg/l Mortality Aquatic Invertebrates Product: No data available. Specified substance(s): FORMIC ACID LC 50 (Brine shrimp (Artemia salina), 24 h): 410 mg/l Mortality EC 50 (Water flea (Daphnia magna), 48 h): 138 - 165.6 mg/l Intoxication LC 50 (Green or European shore crab (Carcinus maenas), 48 h): 80 - 90 mg/l Mortality Chronic hazards to the aquatic environment: Fish Product: No data available. Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available.

🌱 Persistence and Degradability

Biodegradation Product: Expected to be readily biodegradable. BOD/COD Ratio Product: No data available.
Expected to be readily biodegradable.

🌱 Bioaccumulative potential

Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available on bioaccumulation. Partition Coefficient n-octanol / water (log Kow) Product: Log Kow: -0.54
No data available on bioaccumulation. Log Kow: -0.54

🌱 Mobility in soil:

Mobility in soil: The product is water soluble and may spread in water systems.
The product is water soluble and may spread in water systems.

🌱 Other adverse effects:

Other adverse effects: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Waste Disposal & Treatment Methods

Waste disposal procedures, treatment methods, and regulatory compliance requirements

πŸ—‚οΈ Product Disposal Recommendations

Discharge, treatment, or disposal may be subject to national, state, or local laws.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

🏷️ UN Number

UN 1779

πŸ“¦ Proper Shipping Name

Formic acid

⚠️ Transport Hazard Class

8

πŸ“‹ Packing Group

II

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for FORMIC ACID?

The signal word for this substance is "danger".

What is the physical form of FORMIC ACID?

FORMIC ACID is a liquid appearing as colorless with colorless color. It has characteristic, pungent odor.

What is the solubility of FORMIC ACID?

No data available.

What are the hazard statements for FORMIC ACID?

This substance has 5 hazard statements: H226: Flammable liquid and vapor. H290: May be corrosive to metals. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H335: May cause respiratory irritation.

What is the melting point of FORMIC ACID?

The melting point is 8.4 Β°C and the boiling point is 100.8 Β°C.