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Safety Data Sheet EN

Ammonium persulfate

CAS 7727-54-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ammonium persulfate
Product Code
215589
Chemical Name
Ammonium persulfate

Regulatory Identifiers

CAS Number
7727-54-0 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient's responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

manufacturer

3050 SPRUCE ST, ST. LOUIS MO 63103, UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Sol. Cat. 3 H272
Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Acute Cat. 3 H402

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H402 Harmful to aquatic life.

Precautionary Statements

P210 Keep away from heat.
P220 Keep/Store away from clothing/ combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P285 In case of inadequate ventilation wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ammonium peroxodisulphate EC: 231-786-5 7727-54-0 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Nitrogen oxides (NOx), Sulfur oxides, Container explosion may occur under fire conditions., Not combustible., Has a fire-promoting effect due to release of oxygen., Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Keep locked up or in an area accessible only to qualified or authorized persons. Do not store near combustible materials.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Partition Coefficient
No data available
Metal Corrosion
---
Vapor Pressure
No data available
Molecular Weight
---
State Under Standard Conditions
---
Solubility In Fat
---
Physical State Data
solid
Dynamic Viscosity
---
Lower Explosive Limit
No data available
Auto Ignition Temperature
No data available
Explosive Limits
---
Appearance
powder, white
Bulk Density
---
Decomposition Temperature
No data available
Kinematic Viscosity
---
Ph
1.0 - 2 at 228 g/l at 25 °C (77 °F)
Odor
No data available
Vapor Density
7.88 - (Air = 1.0)
Colour Intensity
---
Relative Evaporation Rate
---
Freezing Point
---
Solidification Point
---
Physical State
powder
Evaporation Rate
No data available
Upper Explosive Limit
No data available
Softening Point
---
Form
powder
Solubility In Water
228 g/l at 20 °C (68 °F) - completely soluble
Boiling Point
Decomposes below the boiling point.
Voc Content
---
Odor Threshold
No data available
Properties Status
---
Cloud Point
---
Colour
white
Crystallisation Point
---
Relative Density
No data available
Flash Point
No data available
Solubility
---
Density
1.980 g/cm3
Melting Point
Decomposes before melting.
Flammability
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). May decompose on exposure to moist air or water.

Reactivity

No data available

Hazardous reactions

No data available

Avoid

no information available

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1444
Shipping Name
Ammonium persulfate
Transport Class
5.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Ammonium persulfate?

The signal word is danger.

What is the physical form of Ammonium persulfate?

Ammonium persulfate is a powder appearing as powder, white with white color. It has no data available odor.

What is Ammonium persulfate used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Ammonium persulfate?

This substance has 8 hazard statements:

  • H272: May intensify fire; oxidizer.
  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H402: Harmful to aquatic life.

What is the melting point of Ammonium persulfate?

The melting point is Decomposes before melting. and the boiling point is Decomposes below the boiling point..