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Safety Data Sheet EN

Oxygen

CAS 7782-44-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Oxygen
Product Form
Gaseous
Chemical Name
Oxygen
Synonyms
Oxygen, Oxygen gas, Gaseous Oxygen, GOX

Regulatory Identifiers

CAS Number
7782-44-7 Check regulations →
REACH No.
Listed in Annex IV / V REACH, exempted from registration.

Identified Uses

Industrial and professional use. Perform risk assessment prior to use.

Uses advised against

None.

Manufacturers & Suppliers

A

Air Products N.V.

national supplier

Leonardo Da Vincilaan 19C - Bus 4, 1831 Diegem, Belgium

+32 (0)78 15 52 02

Emergency Contacts

Cylinder, Bulk, Medical

32-28083237

Poison Center

07 0245245

Poison Center

+32 70245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Gas Cat. 1 H270
Press. Gas (Comp.) H280

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS04 - Compressed gas

GHS04

Hazard Statements

H270 May cause or intensify fire; oxidiser.
H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P220 Keep away from clothing and other combustible materials.
P244 Keep valves and fittings free from oil and grease.
P370 + P376 In case of fire: Stop leak if safe to do so.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Concentration is nominal. For the exact product composition, please refer to technical specifications.

Chemical Name CAS Number Concentration Hazardous
Oxygen EC: 231-956-9 7782-44-7 100% Yes

Notes

Concentration is nominal. For the exact product composition, please refer to technical specifications. Specific concentration limits, M-factors and ATEs are not applicable for components of this product.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Consult a physician after significant exposure. Move to fresh air. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately.

Skin contact

Adverse effects not expected from this product. IF exposed or concerned: Get medical advice/attention.

Eye contact

IF exposed or concerned: Get medical advice/attention.

Ingestion

Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

If exposed or concerned: Get medical attention/advice.

Medical Treatment

If exposed or concerned: Get medical attention/advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

The product itself does not burn. Use extinguishing media appropriate for surrounding fire.

Unsuitable media

Do not use water jet to extinguish.

Specific hazards

Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture violently. Oxidant. Strongly supports combustion. May react violently with combustible materials. Some materials which are noncombustible in air may burn in the presence of an oxidizer.

Instructions

Move away from container and cool with water from a protected position. Keep adjacent cylinders cool by spraying with large amounts of water until the fire burns itself out. If possible, stop flow of product.

Firefighter Protection

Wear self contained breathing apparatus for fire fighting if necessary. Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fighters. Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. Standard EN 469 - Protective clothing for firefighters. Standard - EN 659: Protective gloves for firefighters.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

If possible, stop flow of product. Increase ventilation to the release area and monitor concentrations. If leak is from cylinder or cylinder valve, call the emergency telephone number. If the leak is in the user's system, close the cylinder valve, safely vent the pressure, and purge with an inert gas before attempting repairs.

Environmental

Do not discharge into any place where its accumulation could be dangerous. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Ventilate the area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

All gauges, valves, regulators, piping and equipment to be used in oxygen service must be cleaned for oxygen service. Oxygen is not to be used as a substitute for compressed air. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood of an engulfing fire. Only experienced and properly instructed persons should handle compressed gases/cryogenic liquids. Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not allow storage area temperature to exceed 50°C (122°F). Before using the product, determine its identity by reading the label. Know and understand the properties and hazards of the product before use. When doubt exists as to the correct handling procedure for a particular gas, contact the supplier. Do not remove or deface labels provided by the supplier for the identification of the cylinder contents. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use. Use an adjustable strap wrench to remove over-tight or rusted caps. Before connecting the container, check the complete gas system for suitability, particularly for pressure rating and materials. Before connecting the container for use, ensure that back feed from the system into the container is prevented. Ensure the complete gas system is compatible for pressure rating and materials of construction. Ensure the complete gas system has been checked for leaks before use. Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with lower pressure rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve, causing a leak to occur. If user experiences any difficulty operating cylinder valve discontinue use and contact supplier. Close container valve after each use and when empty, even if still connected to equipment. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Do not use containers as rollers or supports or for any other purpose than to contain the gas as supplied. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Do not smoke while handling product or cylinders. Never re-compress a gas or a gas mixture without first consulting the supplier. Never attempt to transfer gases from one cylinder/container to another. Always use backflow protective device in piping. When returning cylinder install valve outlet cap or plug leak tight. Never permit oil, grease, or other readily combustible substances to come into contact with valves or containers containing oxygen or other oxidants. Do not use rapidly opening valves (e.g. ball valves). Open valve slowly to avoid pressure shock. Never pressurize the entire system at once. Use only with equipment cleaned for oxygen service and rated for cylinder pressure. Never use direct flame or electrical heating devices to raise the pressure of a container.

Storage

Containers should be stored in a purpose build compound which should be well ventilated, preferably in the open air. Full containers should be stored so that oldest stock is used first. Stored containers should be periodically checked for general condition and leakage. Observe all regulations and local requirements regarding storage of containers. Protect containers stored in the open against rusting and extremes of weather. Containers should not be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and properly secured to prevent toppling. The container valves should be tightly closed and where appropriate valve outlets should be capped or plugged. Container valve guards or caps should be in place. Keep containers tightly closed in a cool, well-ventilated place. Store containers in location free from fire risk and away from sources of heat and ignition. Full and empty cylinders should be segregated. Do not allow storage temperature to exceed 50°C (122°F). Display 'No Smoking or Open Flames' signs in the storage areas. Return empty containers in a timely manner.

Hygiene

Do not smoke while handling product or cylinders.

Fire prevention

Store containers in location free from fire risk and away from sources of heat and ignition. Display 'No Smoking or Open Flames' signs in the storage areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation.

Hands

Wear work gloves when handling gas containers. Gloves must be clean and free of oil and grease. Standard EN 388 - Protective gloves against mechanical risk.

Eyes

Safety glasses recommended when handling cylinders. Standard EN 166 - Personal eye-protection.

Respiratory

Not required under normal use. Self contained breathing apparatus (SCBA) or positive pressure airline with mask are to be used in oxygen-deficient atmosphere. Users of breathing apparatus must be trained.

Skin/Body

Safety shoes are recommended when handling cylinders. Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Environmental

If applicable, refer to the extended section of the SDS for further information on CSA.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
32 g/mol
Explosive Limits
---
Lower Explosive Limit
Not applicable.
Dynamic Viscosity
---
Freezing Point
-219 °C ( -362 °F )
Relative Evaporation Rate
---
State Under Standard Conditions
---
Relative Density
0.0013 g/cm3 at 21 °C
Kinematic Viscosity
Not applicable for gases and gas mixtures.
Partition Coefficient
Not applicable for inorganic gases.
Auto Ignition Temperature
Not applicable.
Crystallisation Point
---
Physical State
Gaseous. Compressed gas.
Odor Threshold
Odour threshold is subjective and inadequate to warn of overexposure.
Solidification Point
---
Odor
No odor warning properties. Odour threshold is subjective and inadequate to warn of overexposure.
Vapor Density
---
Form
---
Flammability
Non flammable.
Melting Point
-219 °C ( -362 °F )
Boiling Point
-183 °C ( -297 °F )
Solubility
---
Softening Point
---
Solubility In Fat
---
Metal Corrosion
---
Vapor Pressure
Not applicable for compressed gases and gas mixtures.
Bulk Density
---
Upper Explosive Limit
Not applicable.
Evaporation Rate
---
Flash Point
Not applicable for gases and gas mixtures.
Colour
Colorless gas.
Solubility In Water
0.039 g/l
Physical State Data
gas
Colour Intensity
---
Properties Status
---
Cloud Point
---
Density
0.0013 g/cm3 at 21 °C
Decomposition Temperature
Not applicable.
Voc Content
---
Appearance
Colorless gas.
Ph
Not applicable for gases and gas mixtures.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

No reactivity hazard other than the effects described in sub-sections below.

Hazardous reactions

Violently oxidises organic material.

Avoid

None under recommended storage and handling conditions (see section 7).

Incompatible

Flammable materials. Organic materials. Avoid oil, grease and all other combustible materials.

Decomposition

No data available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Return unused product in original cylinder to supplier. Contact supplier if guidance is required. Refer to the EIGA code of practice Doc. 30 "Disposal of Gases", downloadable at http://www.eiga.org for more guidance on suitable disposal methods.

Disposal

Return unused product in original cylinder to supplier.

Waste Codes

16 05 04* gases in pressure containers (including halons) containing hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1072
Shipping Name
OXYGEN, COMPRESSED
Transport Class
2.2
Packing Group
Not applicable.
ADR

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Oxygen known by?

Oxygen is also known as: Oxygen, Oxygen gas, Gaseous Oxygen, GOX

What is the hazard signal word for Oxygen?

The signal word is danger.

What is the physical form of Oxygen?

Oxygen is a gaseous. compressed gas. appearing as colorless gas. with colorless gas. color. It has no odor warning properties. odour threshold is subjective and inadequate to warn of overexposure. odor.

What is Oxygen used for?

Industrial and professional use. Perform risk assessment prior to use.

What are the hazard statements for Oxygen?

This substance has 2 hazard statements:

  • H270: May cause or intensify fire; oxidiser.
  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of Oxygen?

The melting point is -219 °C ( -362 °F ) and the boiling point is -183 °C ( -297 °F ).