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Safety Data Sheet EN

GLYCERINE 4813

CAS 56-81-5
EC 200-289-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GLYCERINE 4813
Product Form
Substance
Chemical Name
Glycerol
Synonyms
1,2,3-propanetriol

Regulatory Identifiers

CAS Number
56-81-5 Check regulations →
EC Number
200-289-5 Check regulations →
REACH No.
1907/2006/EC Annex V.9

Identified Uses

Industrial use, Professional use; wide dispersive use

Uses advised against

No additional information available

Manufacturers & Suppliers

OLEON N.V. logo

OLEON N.V.

manufacturer

Assenedestraat 2, 9940 Ertvelde - Belgium

+32 9 341 10 11

http://www.oleon.com

Emergency Contacts

SGS ERS; Oleon contract nr 76858

+32 3 575 55 55

24/7

SGS ERS; Oleon contract nr 76858

+1 888 765 6554

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Substance type : Mono-constituent

Chemical Name CAS Number Concentration Hazardous
Glycerol EC: 200-289-5 56-81-5 99% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: Coughing. ON HEATING: Irritation of the respiratory tract. Irritation of the nasal mucous membranes.

Skin contact

Rinse with water. Soap may be used. Take victim to a doctor if irritation persists.

Eye contact

Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.

Symptoms: Slight irritation.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Call Poison Information Centre (www.who.int/ipcs/poisons/centre/directory/en). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.

Symptoms: Nausea. Vomiting. Diarrhoea. AFTER INGESTION OF HIGH QUANTITIES: Headache. Dehydration. Disturbances of heart rate. Change in the haemogramme/blood composition. Decreased renal function.

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital. Ingestion of large quantities: immediately to hospital.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Specific hazards

DIRECT FIRE HAZARD: Combustible. INDIRECT FIRE HAZARD: Temperature above flashpoint: higher fire/explosion hazard.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. Exposure to heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothes.

Cleanup methods

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite, kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling.

Materials: sand, earth, vermiculite, kieselguhr, powdered limestone

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Storage

Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements.

Fire prevention

KEEP SUBSTANCE AWAY FROM: heat sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Gloves. Materials for protective clothing: GIVE GOOD RESISTANCE: natural rubber, neoprene, PVC, viton. GIVE LESS RESISTANCE: styrene-butadiene rubber. GIVE POOR RESISTANCE: polyurethane.

Eyes

Safety glasses.

Respiratory

Mist formation: aerosol mask with filter type P1. On heating: gas mask with filter type A.

Skin/Body

Protective clothing. Materials for protective clothing: GIVE GOOD RESISTANCE: natural rubber, neoprene, PVC, viton. GIVE LESS RESISTANCE: styrene-butadiene rubber. GIVE POOR RESISTANCE: polyurethane.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Metal Corrosion
---
Crystallisation Point
---
Vapor Density
---
Explosive Limits
---
Physical State
Liquid
Upper Explosive Limit
19 vol %
Form
---
Physical State Data
liquid
Colour Intensity
---
Softening Point
< 20 °C
Evaporation Rate
No data available
Odor
Odourless.
Odor Threshold
No data available
Freezing Point
ca. 18 °C
Relative Density
1,26 (20 °C)
Auto Ignition Temperature
370 °C
Bulk Density
---
Ph
6 - 7,5 (10% in water)
Solidification Point
---
Dynamic Viscosity
ca. 1150 mPa·s (20°C)
Solubility In Water
Soluble in water.
Kinematic Viscosity
ca. 912,698 mm²/s
Properties Status
---
Decomposition Temperature
290 °C
Relative Evaporation Rate
No data available
Solubility
Soluble in water. Soluble in ethanol. Soluble in acetone. Soluble in ethylacetate. Insoluble in oils/fats.
Molecular Weight
---
Cloud Point
---
Melting Point
No supplementary information available
Lower Explosive Limit
2,7 vol %
Flammability
No data available
Boiling Point
290 °C (760 mm Hg)
Solubility In Fat
Insoluble in oils/fats.
Colour
Colourless to light yellow.
Density
ca. 1260 kg/m³ (25°C); ca. 1249 kg/m³ (40°C); ca. 1209 kg/m³ (100°C)
State Under Standard Conditions
---
Voc Content
< 1 % (1999/13/EC; 2004/42/EC; 2010/75/EU; SR 814.018)
Partition Coefficient
-1,75 (Experimental value, Equivalent or similar to OECD 107, 25 °C)
Appearance
Liquid.
Flash Point
177 °C (Open cup, 1013 hPa, ASTM D92: Flash and Fire point (Cleveland Open Cup))
Vapor Pressure
< 0,001 mm Hg (20 °C)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

Decomposes on exposure to temperature rise: release of toxic/corrosive/combustible gases/vapours (acrolein). Upon combustion CO and CO2 are formed. May polymerize on exposure to temperature rise. Reacts violently with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with (some) acids: (increased) risk of fire/explosion. Reacts with nitric acid to form highly explosive nitroglycerine.

Hazardous reactions

No additional information available

Avoid

Refer to Section 10 on Incompatible Materials.

Incompatible

Keep away from oxidizers, strong acids and strong bases. Water, humidity.

Decomposition

On heating/burning: release of toxic/combustible gases/vapours (acrolein).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite, or kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Wash down leftovers with plenty of water. Wash clothing and equipment after handling

Disposal

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. Recycle by distillation. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber. Do not discharge into surface water.

Waste Codes

No supplementary information available. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
Shipping Name
Not applicable
Transport Class
Not applicable
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

No chemical safety assessment needed: the substances is not classified and exempt from Regulation EC No 1907/2006 (REACH) under Annex V, point 9.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is GLYCERINE 4813 known by?

GLYCERINE 4813 is also known as: 1,2,3-propanetriol

What is the hazard signal word for GLYCERINE 4813?

The signal word is no signal word.

What is the physical form of GLYCERINE 4813?

GLYCERINE 4813 is a liquid appearing as liquid. with colourless to light yellow. color. It has odourless. odor.

What is the solubility of GLYCERINE 4813?

Soluble in water. Soluble in ethanol. Soluble in acetone. Soluble in ethylacetate. Insoluble in oils/fats.

What is GLYCERINE 4813 used for?

Industrial use, Professional use; wide dispersive use

What is the melting point of GLYCERINE 4813?

The melting point is No supplementary information available and the boiling point is 290 °C (760 mm Hg).