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Safety Data Sheet EN

VERSENE™ 100 Chelating Agent

CAS 64-02-8
EC 200-573-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
VERSENE™ 100 Chelating Agent
Chemical Name
tetrasodium ethylene diamine tetraacetate

Regulatory Identifiers

CAS Number
64-02-8 Check regulations →
EC Number
200-573-9 Check regulations →
REACH No.
01-2119486762-27-0002

Identified Uses

Manufacture: Industrial Manufacturing of substance (powder, conc. up to 100 %) and its use as an intermediate. Industrial Manufacturing of substance (liquid, conc. up to 55 %) and its use as an intermediate. Formulation or re-packing: Industrial Formulation of substance (powder) of medium dustiness (conc. up to 100 %, full day shift). Industrial Formulation of substance (powder) of medium dustiness (conc. up to 100 %, short-term). Industrial Production of formulations of high dustiness (conc. up to 2.5 %, full day shift). Industrial Formulation of liquid substance (conc. up to 55 %, full day shift). Widespread use by professional workers: Professional Formulation with powdery substance of medium dustiness (conc. = 100%, full day shift). Professional Formulation with powdery substance of medium dustiness (conc. = 100%, short-term). Professional Production of formulations of high dustiness (conc. up to 2.5 %, full day shift). Professional Formulation of liquid substance (conc. up to 55 %, full day shift). Use at industrial sites: Industrial End-Use of powdery products (conc. up to 100 %). Industrial End-Use of powdery formulations of medium dustiness (conc. up to 5 %). Industrial End-Use of granular formulations (conc. up to 20 %). Industrial End-Use of liquid formulations (conc. up to 55 %, not air-dispersive). Industrial End-Use of liquid formulations (conc. up to 10 %), air-dispersive. Widespread use by professional workers: Professional End-Use of powdery products (conc. up to 100 %). Professional End-Use of powdery formulations of medium dustiness (conc. up to 5 %). Professional End-Use of granular formulations (conc. up to 20 %). Professional End-Use of liquid formulations (conc. up to 55 %), not air-dispersive. Professional End-use of liquid formulations (conc. up to 10 %), air-dispersive. Consumer use: Consumer End-Use of substance in Adhesives and Sealants (conc. up to 5%). Consumer End-Use of substances in Air care products (conc. up to 5 %). Consumer End-Use of substances in Coatings, paints, thinners, paint removers and Fillers, putties, plasters, modelling clay (conc. conc. up to 5 %). Consumer End-Use of substances in Metal surface treatment products (conc. conc. up to 5 %). Consumer End-Use of substances in Non-metal surface treatment products (conc. conc. up to 5 %). Consumer End-Use of substances in Photo-chemicals (conc. up to 5 %). Consumer End-Use of substances in Polishes and wax blends (conc. up to 5%). Consumer End-Use of substances in Textile dyes, finishing and impregnating products (conc. = 5 %). Consumer End-Use of substances in Washing and cleaning products (conc. up to 5 %). For details on use descriptors and exposure scenarios, please refer to the extended part of the Safety Data Sheet.

Manufacturers & Suppliers

D

DOW EUROPE GMBH

global supplier

BACHTOBELSTRASSE 4 8810 HORGEN SWITZERLAND

31 115 67 2626

D

DOW BENELUX B.V.

national supplier

HERBERT H.DOWWEG 5 HOEK 4542 NM TERNEUZEN NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

00 41 447 28 2820

24-Hour

Emergency Contact

00 32 3575 0330

Belgium Poison Center

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H290 May be corrosive to metals.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H373 May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

Precautionary Statements

P260 Do not breathe mist or vapours.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves, eye protection and/or face protection.
P314 Get medical advice or attention if you feel unwell.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER and/or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Water EC: 231-791-2 7732-18-5 56% No
tetrasodium ethylene diamine tetraacetate EC: 200-573-9 64-02-8 37 - 39% Yes
sodium hydroxide EC: 215-185-5 1310-73-2 1.6% Yes
formaldehyde EC: 200-001-8 50-00-0 0.1% Yes

Notes

If present in this product, any not classified components disclosed above for which no country specific OEL value(s) is(are) indicated under Section 8, are being disclosed as voluntarily disclosed components. For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility.

Symptoms: Harmful if inhaled. Aspiration of vomitus may cause lung injury.

Skin contact

Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation or rash occurs. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands.

Symptoms: Causes skin irritation.

Eye contact

Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.

Symptoms: Causes serious eye damage.

Ingestion

Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Do not give anything by mouth unless the person is fully conscious.

Symptoms: Due to irritant properties, swallowing may result in burns and/or ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury.

Immediate Medical Attention

Call a physician or transport to a medical facility. Seek medical attention if irritation or rash occurs. Obtain prompt medical consultation, preferably from an ophthalmologist. Chemical eye burns may require extended irrigation. If burn is present, treat as any thermal burn, after decontamination.

Medical Treatment

Maintain adequate ventilation and oxygenation of the patient. Chemical eye burns may require extended irrigation. Obtain prompt consultation, preferably from an ophthalmologist. If burn is present, treat as any thermal burn, after decontamination. Due to irritant properties, swallowing may result in burns and/or ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest endotracheal or esophageal control if lavage is done. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

Unsuitable media

No data available

Specific hazards

This material will not burn until the water has evaporated. Residue can burn.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, see Section 8 of the safety data sheet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate area. Keep upwind of spill. Ventilate area of leak or spill. Only trained and properly protected personnel must be involved in clean-up operations. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to section 7, Handling, for additional precautionary measures.

Small spill

Contain spilled material if possible. Absorb with materials such as: Non-combustible material. Collect in suitable and properly labeled containers.

Large spill

Dike area to contain spill. Wash the spill site with water.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Cleanup methods

Absorb with materials such as: Non-combustible material. Collect in suitable and properly labeled containers. Wash the spill site with water.

Materials: Non-combustible material.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not get in eyes. Do not swallow. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.

Storage

Store in accordance with good manufacturing practices. Store in original unopened container.

Hygiene

Wash thoroughly after handling.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Hands

Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Neoprene. When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. Use the following CE approved air-purifying respirator: Particulate filter, type P2 (meeting standard EN 143).

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
---
Metal Corrosion
6,35 mm/a
Vapor Pressure
Same as water
State Under Standard Conditions
---
Kinematic Viscosity
20 cSt at 20 °C Literature
Molecular Weight
380,2 g/mol Literature
Partition Coefficient
not determined
Solubility In Fat
---
Properties Status
---
Voc Content
---
Ph
11,0 - 11,8 Literature 1% aqueous solution.
Upper Explosive Limit
Not applicable
Solubility In Water
completely miscible with water
Crystallisation Point
---
Physical State
Liquid.
Lower Explosive Limit
Not applicable
Melting Point
Not applicable to liquids
Relative Evaporation Rate
---
Solidification Point
---
Auto Ignition Temperature
Not applicable
Solubility
---
Density
---
Explosive Limits
---
Cloud Point
---
Odor Threshold
No test data available
Odor
Mild
Dynamic Viscosity
---
Flash Point
No measurable flash point, Pensky-Martens Closed Cup ASTM D 93
Colour
Colorless to yellow
Freezing Point
-25 °C
Appearance
Colorless to yellow
Flammability
Not expected to be a static-accumulating flammable liquid.
Decomposition Temperature
No test data available
Vapor Density
---
Form
---
Evaporation Rate
< 0,8 Estimated.
Softening Point
---
Physical State Data
liquid
Relative Density
1,31 at 25 °C / 25 °C Literature
Boiling Point
106 °C
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. See Storage, Section 7.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Some components of this product can decompose at elevated temperatures.

Incompatible

Avoid contact with metals such as: Aluminum alloys. Copper. Copper alloys. Nickel. Flammable hydrogen may be generated from contact with metals such as: Zinc. Aluminum.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 3267
Shipping Name
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Transport Class
8
Packing Group
III
IATA

No data available.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for VERSENE™ 100 Chelating Agent?

The signal word is danger.

What is the physical form of VERSENE™ 100 Chelating Agent?

VERSENE™ 100 Chelating Agent is a liquid. appearing as colorless to yellow with colorless to yellow color. It has mild odor.

What is VERSENE™ 100 Chelating Agent used for?

Manufacture: Industrial Manufacturing of substance (powder, conc. up to 100 %) and its use as an intermediate. Industrial Manufacturing of substance (liquid, conc. up to 55 %) and its use as an intermediate. Formulation or re-packing: Industrial Formulation of substance (powder) of medium dustiness (conc. up to 100 %, full day shift). Industrial Formulation of substance (powder) of medium dustiness (conc. up to 100 %, short-term). Industrial Production of formulations of high dustiness (conc. up to 2.5 %, full day shift). Industrial Formulation of liquid substance (conc. up to 55 %, full day shift). Widespread use by professional workers: Professional Formulation with powdery substance of medium dustiness (conc. = 100%, full day shift). Professional Formulation with powdery substance of medium dustiness (conc. = 100%, short-term). Professional Production of formulations of high dustiness (conc. up to 2.5 %, full day shift). Professional Formulation of liquid substance (conc. up to 55 %, full day shift). Use at industrial sites: Industrial End-Use of powdery products (conc. up to 100 %). Industrial End-Use of powdery formulations of medium dustiness (conc. up to 5 %). Industrial End-Use of granular formulations (conc. up to 20 %). Industrial End-Use of liquid formulations (conc. up to 55 %, not air-dispersive). Industrial End-Use of liquid formulations (conc. up to 10 %), air-dispersive. Widespread use by professional workers: Professional End-Use of powdery products (conc. up to 100 %). Professional End-Use of powdery formulations of medium dustiness (conc. up to 5 %). Professional End-Use of granular formulations (conc. up to 20 %). Professional End-Use of liquid formulations (conc. up to 55 %), not air-dispersive. Professional End-use of liquid formulations (conc. up to 10 %), air-dispersive. Consumer use: Consumer End-Use of substance in Adhesives and Sealants (conc. up to 5%). Consumer End-Use of substances in Air care products (conc. up to 5 %). Consumer End-Use of substances in Coatings, paints, thinners, paint removers and Fillers, putties, plasters, modelling clay (conc. conc. up to 5 %). Consumer End-Use of substances in Metal surface treatment products (conc. conc. up to 5 %). Consumer End-Use of substances in Non-metal surface treatment products (conc. conc. up to 5 %). Consumer End-Use of substances in Photo-chemicals (conc. up to 5 %). Consumer End-Use of substances in Polishes and wax blends (conc. up to 5%). Consumer End-Use of substances in Textile dyes, finishing and impregnating products (conc. = 5 %). Consumer End-Use of substances in Washing and cleaning products (conc. up to 5 %). For details on use descriptors and exposure scenarios, please refer to the extended part of the Safety Data Sheet.

What are the hazard statements for VERSENE™ 100 Chelating Agent?

This substance has 5 hazard statements:

  • H290: May be corrosive to metals.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H332: Harmful if inhaled.
  • H373: May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

What is the melting point of VERSENE™ 100 Chelating Agent?

The melting point is Not applicable to liquids and the boiling point is 106 °C.

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