PETOL 410-4N

Remove affected person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Symptoms: Inhalation of vapors from heated materials may cause respiratory irritation and symptoms may include cough and sometimes slight dizziness.

Wash skin with soap and plenty of water immediately at least 15 minutes, until no evidence of chemical remains.

Symptoms: Causes skin irritation. May cause an allergic skin reaction on prolonged or repeated contact.

Wash eyes immediately with large amounts of lukewarm water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains at least 15 minutes. Get medical attention immediately if pain, blinking, tears or redness persist.

Symptoms: Contact with eyes cause irritation.

If accidentally ingested, seek medical attention

Symptoms: Not expected to be an important route of entry into the body. The product has low to very low oral toxicity. No known significant effects or critical hazards.

Dry chemical, carbon dioxide, dry chemical, foam and water spray.

Do not use direct water stream as it may spread the fire.

Polyether polyols are low in volatility are not considered serious fire hazard. However, in the presence of an existing fire, or under the proper conditions of heat and oxygen, will burn. Heat or fire may produce decomposition products, which may be hazardous. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Keep unnecessary and unprotected personnel away from entering. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage.

Ventilate area of leak or spill. Spread granular cover. Contain and recover liquid when possible. Collect spillage.

Minor spills on concrete or other hard surfaces can be wiped or mopped up. Also small spills can be absorbed with dry sand, earth, vermiculite then collect into drums, small containers for later disposal. Dispose according to all applicable federal, state or local environment regulations.

Industrial spill or release are accidental and are generally contained. For large spills, dike and pump into suitable containers for disposal. The residual spilled material may be absorbed with dry absorbent material (sand, earth, vermiculite). Flush area with plenty of water. Waste water will be treated in biological treatment plant.

Prevent contamination of ground and surface water by isolating the hazard area. Contain and recover liquid when possible. Water polluting material! May be harmful to the environment if released in large quantities. Collect spillage. Keep closed containers and dispose according to all applicable federal, state or local environment regulations.

Absorb spills with dry sand, earth or similar absorbent material then collect into drums for later disposal. Minor spills on concrete or other hard surfaces can be wiped or mopped up. Flush area with plenty of water.

Materials: Dry sand, earth, vermiculite or similar absorbent material. Do not use combustible materials, such as saw dust.

No special measures required. It is not considered a hazardous material in most industrial operations. Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

Store in tightly closed containers, in dry and well ventilated areas, away from UV light, between 20-30°C. Product will absorb water if the product container is not secured properly. This may affect reactivity, appearance and performance. Therefore, keep drums tightly closed to prevent contamination. Use dry nitrogen or low dew point air for tank padding. Drums should be stacked to a maximum of 3 high.

Avoid inhalation or ingestion and contact with skin and eyes. General occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking, eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated clothing at home.

Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

No special ventilation is recommended under anticipated conditions of normal use beyond that needed for normal comfort control. Good general ventilation should be sufficient for most conditions.

Handle with gloves which were inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. The selected protective gloves have to satisfy the specifications of the standard EN 374 derived from it. Examples of preferred glove barrier materials: - Butyl rubber - Nitrile/butadiene rubber - Polyvinyl alcohol ("PVA") - Neoprene: - Polyvinyl chloride (PVC or "vynil") - Natural rubber ("later") For prolonged or frequently repeated contact a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Chemical splash goggles and/or face shield must be worn when possibility exist for eye contact due to splashing or spraying liquid, airborne particles or vapor. Contact lenses must not be worn. Equipment for eye protection should be tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

No special respirator protection is recommended under anticipated conditions of normal use with adequate ventilation. However, if material is heated or sprayed, without sufficient ventilation use an approved air-purifying respirator. Organic vapor respirator with a particulate pre-filter may be worn if vapors are detected or irritating. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.

Wear impervious protective clothing including boots, apron, if needed.

Stable under normal temperature and pressure, but hygroscopic.

Not considered to be reactive.

Moisture, ignition sources and incompatibles.

strong acids, alkalis and oxidizers such as peroxides and hypochlorite salts, water. Avoid unintended contact with isocyanates.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.