Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- PETOL 410-4N
- Product Code
- FDS 050/1
- Chemical Name
- Propoxylated reaction products of phenol, 4-nonyl-, branched and formaldehyde and 2,2'-iminodiethanol
Regulatory Identifiers
- CAS Number
- N/A
- EC Number
- 701-426-6 Check regulations →
- REACH No.
- 01-2119928014-47-0001
Identified Uses
Petol PM 410-4N is a Mannich polyol used in polyol blends for rigid foams blow with water for pipes insulation and for spray rigid foams. Main applications: rigid polyurethane foams, semi rigid polyurethane foams, cross linker agent. Formulation [SU 10] (ERC 6a, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]; Industrial use as intermediate (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]-Rigid foam (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 10, PROC 13, PROC 15, PROC 21). Industrial use[SU3]-Foundry industrial use (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 14, PROC 15). Professional use[SU 22]; Rigid foam professional use (ERC 8e, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 10, PROC 11, PROC 13)
Uses advised against
There are no uses advised against.
Manufacturers & Suppliers
S.C. Chimcomplex SA Borzesti –Ramnicu Valcea Branch
manufacturer
1 Uzinei Street, 240050 Ramnicu Valcea, Romania
+40 250 701 785, +40 250 701 200 ext.2785, 3001, 3115
Emergency Contacts
European Emergency N°
112
Emergency telephone at the company
+40/250/738141
24h/day/365days
For Romania
+40 21 599 2300
RO, EN
Emergency phone number
021 112
24/7
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS07
GHS09
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Petol 410-4N EC: 701-426-6 | --- | 100% | No |
Notes
Impurities: No impurities relevant for classification and labeling. Notes on nanoforms: Petol PM 410-4N does not contain nanoforms or substances that include nanoforms.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove affected person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Symptoms: Inhalation of vapors from heated materials may cause respiratory irritation and symptoms may include cough and sometimes slight dizziness.
Wash skin with soap and plenty of water immediately at least 15 minutes, until no evidence of chemical remains.
Symptoms: Causes skin irritation. May cause an allergic skin reaction on prolonged or repeated contact.
Wash eyes immediately with large amounts of lukewarm water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains at least 15 minutes. Get medical attention immediately if pain, blinking, tears or redness persist.
Symptoms: Contact with eyes cause irritation.
Not expected to be an important route of entry into the body. The product has low to very low oral toxicity. If accidentally ingested, seek medical attention
Symptoms: No known significant effects or critical hazards.
Immediate Medical Attention
Get medical attention immediately if pain, blinking, tears or redness persist (eyes); Get medical attention immediately (inhalation); If accidentally ingested, seek medical attention.
Medical Treatment
Treat symptomatically and supportively.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Dry chemical, carbon dioxide, dry chemical, foam and water spray.
Do not use direct water stream as it may spread the fire.
Polyether polyols are low in volatility are not considered serious fire hazard. However, in the presence of an existing fire, or under the proper conditions of heat and oxygen, will burn. Heat or fire may produce decomposition products, which may be hazardous. This material is toxic to aquatic life with long lasting effects.
Keep unnecessary and unprotected personnel away from entering. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.
Firefighter Protection
Firefighters should be equipment with protective equipment and self-contained breathing apparatus to protect against potentially toxic and irritating fumes.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Spills may cause very slippery surfaces. Spread granular cover.
Minor spills on concrete or other hard surfaces can be wiped or mopped up. Also small spills can be absorbed with dry sand, earth, vermiculite then collect into drums, small containers for later disposal. Dispose according to all applicable federal, state or local environment regulations.
Industrial spill or release are accidental and are generally contained. For large spills, dike and pump into suitable containers for disposal. The residual spilled material may be absorbed with dry absorbent material (sand, earth, vermiculite). Flush area with plenty of water. Waste water will be treated in biological treatment plant.
Prevent contamination of ground and surface water by isolating the hazard area. Contain and recover liquid when possible. Water polluting material! May be harmful to the environment if released in large quantities. Collect spillage. Keep closed containers and dispose according to all applicable federal, state or local environment regulations.
Absorb spills with dry sand, earth or similar absorbent material then collect into drums for later disposal. Incinerate or bury in a licensed facility according to national environmental regulations.
Materials: dry sand, earth, vermiculite
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
No special measures required. It is not considered a hazardous material in most industrial operations. Sources of ignition such as smoking and open flames are prohibited where this compound is handled.
Store in tightly closed containers, in dry and well ventilated areas, away from UV light, between 20-30°C. Product will absorb water if the product container is not secured properly. This may affect reactivity, appearance and performance. Therefore, keep drums tightly closed to prevent contamination. Use dry nitrogen or low dew point air for tank padding. Drums should be stacked to a maximum of 3 high.
Avoid inhalation or ingestion and contact with skin and eyes. General occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking, eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated clothing at home.
Sources of ignition such as smoking and open flames are prohibited where this compound is handled.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
No special ventilation is recommended under anticipated conditions of normal use beyond that needed for normal comfort control. Good general ventilation should be sufficient for most conditions.
Handle with gloves which were inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. The selected protective gloves have to satisfy the specifications of the standard EN 374 derived from it. Examples of preferred glove barrier materials: Butyl rubber, Nitrile/butadiene rubber, Polyvinyl alcohol ("PVA"), Neoprene, Polyvinyl chloride (PVC or "vynil"), Natural rubber ("later"). For prolonged or frequently repeated contact a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended.
Chemical splash goggles and/or face shield must be worn when possibility exist for eye contact due to splashing or spraying liquid, airborne particles or vapor. Contact lenses must not be worn. Equipment for eye protection should be tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
No special respirator protection is recommended under anticipated conditions of normal use with adequate ventilation. However, if material is heated or sprayed, without sufficient ventilation use an approved air-purifying respirator. Organic vapor respirator with a particulate pre-filter may be worn if vapors are detected or irritating. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.
Wear impervious protective clothing including boots, apron, if needed.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Stable under normal temperature and pressure, but hygroscopic.
Not considered to be reactive.
Moisture, ignition sources and incompatibles.
Avoid contact with strong acids, alkalis and oxidizers such as peroxides and hypochlorite salts, water. Avoid unintended contact with isocyanates.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Waste Codes
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 3082
- Shipping Name
- Environmentally hazardous Substance Liquid,N.O.S. (Polypropoxylated p-nonylphenolformaldehyde-Diethanolamine Mannich Base)
- Transport Class
- 9
- Packing Group
- III
Regulatory Information
Chemical regulations, safety assessments, and compliance status
A chemical safety assessment has been carried out for this substance and CSR was issued.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for PETOL 410-4N?
The signal word is warning.
What is the physical form of PETOL 410-4N?
PETOL 410-4N is a yellow-brown clear viscous liquid appearing as yellow-brown clear viscous with yellow-brown color. It has odourless odor.
What is PETOL 410-4N used for?
Petol PM 410-4N is a Mannich polyol used in polyol blends for rigid foams blow with water for pipes insulation and for spray rigid foams. Main applications: rigid polyurethane foams, semi rigid polyurethane foams, cross linker agent. Formulation [SU 10] (ERC 6a, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]; Industrial use as intermediate (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]-Rigid foam (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 10, PROC 13, PROC 15, PROC 21). Industrial use[SU3]-Foundry industrial use (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 14, PROC 15). Professional use[SU 22]; Rigid foam professional use (ERC 8e, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 10, PROC 11, PROC 13)
What are the hazard statements for PETOL 410-4N?
This substance has 4 hazard statements:
- H315: Causes skin irritation.
- H317: May cause an allergic skin reaction.
- H319: Causes serious eye irritation.
- H411: Toxic to aquatic life with long lasting effects.
What is the melting point of PETOL 410-4N?
The melting point is 3 °C at 101.3 kPa .