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Safety Data Sheet EN

PETOL 410-4N

EC 701-426-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
PETOL 410-4N
Product Code
FDS 050/1
Chemical Name
Propoxylated reaction products of phenol, 4-nonyl-, branched and formaldehyde and 2,2'-iminodiethanol

Regulatory Identifiers

CAS Number
N/A
EC Number
701-426-6 Check regulations →
REACH No.
01-2119928014-47-0001

Identified Uses

Petol PM 410-4N is a Mannich polyol used in polyol blends for rigid foams blow with water for pipes insulation and for spray rigid foams. Main applications: rigid polyurethane foams, semi rigid polyurethane foams, cross linker agent. Formulation [SU 10] (ERC 6a, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]; Industrial use as intermediate (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]-Rigid foam (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 10, PROC 13, PROC 15, PROC 21). Industrial use[SU3]-Foundry industrial use (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 14, PROC 15). Professional use[SU 22]; Rigid foam professional use (ERC 8e, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 10, PROC 11, PROC 13)

Uses advised against

There are no uses advised against.

Manufacturers & Suppliers

S

S.C. Chimcomplex SA Borzesti –Ramnicu Valcea Branch

manufacturer

1 Uzinei Street, 240050 Ramnicu Valcea, Romania

+40 250 701 785, +40 250 701 200 ext.2785, 3001, 3115

Emergency Contacts

European Emergency N°

112

Emergency telephone at the company

+40/250/738141

24h/day/365days

For Romania

+40 21 599 2300

RO, EN

Emergency phone number

021 112

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container to according to in force regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type uvcb
Chemical Name CAS Number Concentration Hazardous
Petol 410-4N EC: 701-426-6 --- 100% No

Notes

Impurities: No impurities relevant for classification and labeling. Notes on nanoforms: Petol PM 410-4N does not contain nanoforms or substances that include nanoforms.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove affected person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Symptoms: Inhalation of vapors from heated materials may cause respiratory irritation and symptoms may include cough and sometimes slight dizziness.

Skin contact

Wash skin with soap and plenty of water immediately at least 15 minutes, until no evidence of chemical remains.

Symptoms: Causes skin irritation. May cause an allergic skin reaction on prolonged or repeated contact.

Eye contact

Wash eyes immediately with large amounts of lukewarm water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains at least 15 minutes. Get medical attention immediately if pain, blinking, tears or redness persist.

Symptoms: Contact with eyes cause irritation.

Ingestion

Not expected to be an important route of entry into the body. The product has low to very low oral toxicity. If accidentally ingested, seek medical attention

Symptoms: No known significant effects or critical hazards.

Immediate Medical Attention

Get medical attention immediately if pain, blinking, tears or redness persist (eyes); Get medical attention immediately (inhalation); If accidentally ingested, seek medical attention.

Medical Treatment

Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry chemical, carbon dioxide, dry chemical, foam and water spray.

Unsuitable media

Do not use direct water stream as it may spread the fire.

Specific hazards

Polyether polyols are low in volatility are not considered serious fire hazard. However, in the presence of an existing fire, or under the proper conditions of heat and oxygen, will burn. Heat or fire may produce decomposition products, which may be hazardous. This material is toxic to aquatic life with long lasting effects.

Instructions

Keep unnecessary and unprotected personnel away from entering. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.

Firefighter Protection

Firefighters should be equipment with protective equipment and self-contained breathing apparatus to protect against potentially toxic and irritating fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Spills may cause very slippery surfaces. Spread granular cover.

Small spill

Minor spills on concrete or other hard surfaces can be wiped or mopped up. Also small spills can be absorbed with dry sand, earth, vermiculite then collect into drums, small containers for later disposal. Dispose according to all applicable federal, state or local environment regulations.

Large spill

Industrial spill or release are accidental and are generally contained. For large spills, dike and pump into suitable containers for disposal. The residual spilled material may be absorbed with dry absorbent material (sand, earth, vermiculite). Flush area with plenty of water. Waste water will be treated in biological treatment plant.

Environmental

Prevent contamination of ground and surface water by isolating the hazard area. Contain and recover liquid when possible. Water polluting material! May be harmful to the environment if released in large quantities. Collect spillage. Keep closed containers and dispose according to all applicable federal, state or local environment regulations.

Cleanup methods

Absorb spills with dry sand, earth or similar absorbent material then collect into drums for later disposal. Incinerate or bury in a licensed facility according to national environmental regulations.

Materials: dry sand, earth, vermiculite

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

No special measures required. It is not considered a hazardous material in most industrial operations. Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

Storage

Store in tightly closed containers, in dry and well ventilated areas, away from UV light, between 20-30°C. Product will absorb water if the product container is not secured properly. This may affect reactivity, appearance and performance. Therefore, keep drums tightly closed to prevent contamination. Use dry nitrogen or low dew point air for tank padding. Drums should be stacked to a maximum of 3 high.

Hygiene

Avoid inhalation or ingestion and contact with skin and eyes. General occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking, eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated clothing at home.

Fire prevention

Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special ventilation is recommended under anticipated conditions of normal use beyond that needed for normal comfort control. Good general ventilation should be sufficient for most conditions.

Hands

Handle with gloves which were inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. The selected protective gloves have to satisfy the specifications of the standard EN 374 derived from it. Examples of preferred glove barrier materials: Butyl rubber, Nitrile/butadiene rubber, Polyvinyl alcohol ("PVA"), Neoprene, Polyvinyl chloride (PVC or "vynil"), Natural rubber ("later"). For prolonged or frequently repeated contact a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended.

Eyes

Chemical splash goggles and/or face shield must be worn when possibility exist for eye contact due to splashing or spraying liquid, airborne particles or vapor. Contact lenses must not be worn. Equipment for eye protection should be tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

No special respirator protection is recommended under anticipated conditions of normal use with adequate ventilation. However, if material is heated or sprayed, without sufficient ventilation use an approved air-purifying respirator. Organic vapor respirator with a particulate pre-filter may be worn if vapors are detected or irritating. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.

Skin/Body

Wear impervious protective clothing including boots, apron, if needed.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

State Under Standard Conditions
---
Density
1.01-1.10, g/cm³
Appearance
yellow-brown clear viscous
Dynamic Viscosity
8000-15000 cP
Auto Ignition Temperature
338 °C at 1013 hPa
Melting Point
3 °C at 101.3 kPa
Lower Explosive Limit
---
Solubility In Water
14.24 g/L at 20 °C
Flammability
not flammable
Softening Point
---
Physical State
yellow-brown clear viscous liquid
Colour
yellow-brown
Solubility
---
Freezing Point
---
Voc Content
---
Metal Corrosion
---
Partition Coefficient
Log Kow (Pow): 2.2 at 25 °C
Upper Explosive Limit
---
Evaporation Rate
---
Relative Evaporation Rate
---
Flash Point
184 °C at 1013 hPa (open cup)
Odor Threshold
---
Cloud Point
---
Solubility In Fat
---
Colour Intensity
---
Kinematic Viscosity
---
Relative Density
---
Physical State Data
liquid
Decomposition Temperature
230°C
Crystallisation Point
---
Vapor Pressure
61.5 Pa
Odor
Odourless
Solidification Point
---
Explosive Limits
---
Boiling Point
---
Ph
---
Vapor Density
---
Properties Status
---
Bulk Density
---
Form
---
Molecular Weight
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal temperature and pressure, but hygroscopic.

Reactivity

Not considered to be reactive.

Avoid

Moisture, ignition sources and incompatibles.

Incompatible

Avoid contact with strong acids, alkalis and oxidizers such as peroxides and hypochlorite salts, water. Avoid unintended contact with isocyanates.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Waste Codes

16 03 05* organic wastes containing dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
Environmentally hazardous Substance Liquid,N.O.S. (Polypropoxylated p-nonylphenolformaldehyde-Diethanolamine Mannich Base)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

A chemical safety assessment has been carried out for this substance and CSR was issued.

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for PETOL 410-4N?

The signal word is warning.

What is the physical form of PETOL 410-4N?

PETOL 410-4N is a yellow-brown clear viscous liquid appearing as yellow-brown clear viscous with yellow-brown color. It has odourless odor.

What is PETOL 410-4N used for?

Petol PM 410-4N is a Mannich polyol used in polyol blends for rigid foams blow with water for pipes insulation and for spray rigid foams. Main applications: rigid polyurethane foams, semi rigid polyurethane foams, cross linker agent. Formulation [SU 10] (ERC 6a, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]; Industrial use as intermediate (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 8b, PROC 9, PROC 15). Industrial use [SU3]-Rigid foam (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 10, PROC 13, PROC 15, PROC 21). Industrial use[SU3]-Foundry industrial use (ERC 6c, PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 14, PROC 15). Professional use[SU 22]; Rigid foam professional use (ERC 8e, PROC 3, PROC 4, PROC 5, PROC 8a, PROC 8b, PROC 10, PROC 11, PROC 13)

What are the hazard statements for PETOL 410-4N?

This substance has 4 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of PETOL 410-4N?

The melting point is 3 °C at 101.3 kPa .