PETOL 360-4G

Remove affected person to fresh air. If any ill effects appear get medical attention immediately.

Wash skin with soap and plenty of water immediately at least 15 minutes, until no evidence of chemical remains.

Symptoms: Skin contact with the product is not like to result in a significant irritation.

Wash eyes immediately with large amounts of lukewarm water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains at least 15 minutes.

Symptoms: Contact with eyes not cause irritation. (Note: pain, blinking, tears or redness mentioned as conditions for medical attention).

If a polyol is swallowed obtain emergency medical attention.

Dry chemical, carbon dioxide, dry chemical, foam and water spray.

Do not use direct water stream as it may spread the fire.

Polyether polyols are low in volatility are not considered serious fire hazard. However, in the presence of an existing fire, or under the proper conditions of heat and oxygen, PETOL polyols will burn.

Keep unnecessary and unprotected personnel away from entering. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.

Ventilate area of leak or spill. Wear appropriate personal protective equipment (see section 8). Spills may cause very slippery surfaces. Spread granular cover.

Prevent contamination of ground and surface water by isolating the hazard area. Contain and recover liquid when possible. Keep closed containers and dispose according to all applicable federal, state or local environment regulations.

Absorb spills with dry sand, earth or similar non-combustible absorbent material then collect into drums for later disposal. Incinerate or bury in a licensed facility if permitted.

Materials: dry sand, earth or similar non-combustible absorbent material

No special measures required. It is not considered a hazardous material in most industrial operations. Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

Store in tightly closed containers, in dry and well ventilated areas away from UV radiations, between 20-30°C. Product will absorb water if the product container is not secured properly. This may affect reactivity, appearance and performance. Therefore, keep drums tightly closed to prevent contamination. Use dry nitrogen or low dew point air for tank padding.

Avoid inhalation or ingestion and contact with skin and eyes. General occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking, eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated clothing at home.

Sources of ignition such as smoking and open flames are prohibited where this compound is handled.

No special ventilation is recommended under anticipated conditions of normal use beyond that needed for normal comfort control. Good general ventilation should be sufficient for most conditions.

Handle with gloves which were inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. The selected protective gloves have to satisfy the specifications of the standard EN 374. Preferred materials: Butyl rubber, Nitrile/butadiene rubber, Polyvinyl alcohol ("PVA"), Neoprene, Polyvinyl chloride (PVC or "vynil"), Natural rubber ("latex"). For prolonged or frequently repeated contact a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended.

Use chemical safety goggles and/or a full face shield where splashing is possible. Equipment for eye protection should be tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Maintain eye wash fountain and quick-drench facilities in work area.

No special respirator protection is recommended under anticipated conditions of normal use with adequate ventilation. However, if material is heated or sprayed, without sufficient ventilation use an approved air-purifying respirator. Organic vapor respirator with a particulate pre-filter may be worn if vapors are detected or irritating. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.

Not normally considered a skin hazard. Wear impervious protective clothing including boots, apron.

Stable under normal temperature and pressure, but hygroscopic.

No dangerous reaction known under conditions of normal use.

Moisture, ignition sources and incompatibles.

Avoid contact with strong acids, alkalis and oxidizers such as peroxides and hypochlorite salts, water. Avoid unintended contact with isocyanates.

Unknown toxic products may be formed under recommended storage conditions.

The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.