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Safety Data Sheet EN

GARDOBOND R 2600 E27 (BULK)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GARDOBOND R 2600 E27 (BULK)
Product Code
140597000

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Phosphating solution for metal surfaces.

Uses advised against

Uses other than recommended

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

+49 621 60-0

Emergency Contacts

International emergency number

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Corr. Cat. 1B
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Resp. Sens. Cat. 1
Muta. Cat. 2
Carc. Cat. 1A
Repr. Cat. 1B
Aquatic Acute Cat. 2
Aquatic Chronic Cat. 2
Met. Corr. Cat. 1
STOT RE Cat. 2

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer by inhalation.
H360 May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original packaging.
P260 Do not breathe dust or mist.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash contaminated body parts thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye protection or face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P310 Immediately call a POISON CENTER or physician.
P314 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents and container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Water, inorganic salts, inorganic acids

Chemical Name CAS Number Concentration Hazardous
Zinc phosphate monobasic EC: 237-067-2 13598-37-3 15 - 20% Yes
Manganese bis(dihydrogen phosphate) EC: 242-520-2 18718-07-5 7 - 10% Yes
Orthophosphoric acid EC: 231-633-2 7664-38-2 3 - 5% Yes
Nickel bis(dihydrogen phosphate) EC: 242-522-3 18718-11-1 3 - 5% Yes
Zinc hexafluorosilicate EC: 240-894-1 16871-71-9 1 - 2% Yes

For the classifications not written out in full in this section the full text can be found in section 16.

Notes

Hazardous ingredients (GHS) According to UN GHS criteria

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Immediate medical attention required. Remove the affected individual into fresh air and keep the person calm. If breathing is irregular or stopped, administer artificial respiration.

Skin contact

Flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing immediately and clean before re-use or dispose it if necessary. Immediate medical attention required. Apply calcium gluconate gel.

Symptoms: allergic symptoms, skin corrosion

Eye contact

Remove contact lenses, if present. Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. Immediate medical attention required.

Ingestion

Summon medical aid without delay. Keep at rest. Immediately rinse mouth and then drink milk or a magnesium hydroxide/calcium carbonate suspension, do not induce vomiting, seek medical attention.

Symptoms: May cause severe burns of the mouth and throat if orally ingested, as well as a danger of perforation of the oesophagus and the stomach.

Immediate Medical Attention

Immediate medical attention required.

Medical Treatment

Symptomatic treatment (decontamination, vital functions).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

carbon dioxide, alcohol-resistant foam, dry powder, water spray

Unsuitable media

water jet

Specific hazards

fluorinated compounds, phosphorus oxides

Instructions

Cool closed containers in the vicinity of the source of fire.

Firefighter Protection

Appropriate breathing apparatus may be required.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid breathing vapours. For non-emergency personnel: Use personal protective clothing. Ensure adequate ventilation. Keep away from sources of ignition. For emergency responders: Advice on product handling can be found in sections 7 and 8 of this safety data sheet. Information regarding personal protective measures, see section 8.

Environmental

Do not allow to enter drains or waterways. Do not discharge into the subsoil/soil.

Cleanup methods

Contain and collect spillage with non-combustible absorbent materials. Clean preferably with a detergent; avoid the use of solvents.

Materials: non-combustible absorbent materials (sand, earth, vermiculite, diatomaceous earth), detergent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provide good ventilation of working area (local exhaust ventilation if necessary). Do not return residues to the storage containers. Smoking, eating and drinking are forbidden in application area. Avoid inhalation of vapour and spray mist. The workplace should be equipped with an emergency shower and eye-rinsing facility. Avoid contact with the skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice.

Storage

Keep container dry. Keep in a cool, well-ventilated place. Avoid direct sunlight. Store only in corrosion proof containers. Close containers carefully once opened and store them upright in order to prevent any leakage. No smoking. No admission for unauthorised personnel. Always keep in containers of same material as the original one. Observe label precautions. avoid contact with metals Store protected against freezing.

Hygiene

Smoking, eating and drinking are forbidden in application area. The workplace should be equipped with an emergency shower and eye-rinsing facility. Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

The relevant fire protection measures should be noted.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction.

Hands

Chemical resistant protective gloves (EN ISO 374-1); chloroprene rubber (CR) - 0.5 mm coating thickness; butyl rubber (butyl) - 0.7 mm coating thickness; nitrile rubber (NBR) - 0.4 mm coating thickness; Performance level 6, corresponding to a breakthrough time of >480 min according to EN ISO 374-1. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream).

Eyes

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Respiratory

Respiratory protection required if exposure limit (if available) may be exceeded (Gas filter EN 14387 B). If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.

Skin/Body

Chemical resistant protective clothing according to DIN EN 13034 (Type 6)

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Pressure
(20 °C) not determined, (50 °C) not determined
Boiling Point
not determined
Density
1,340 g/cm3 (20 °C)
Flammability
not applicable
Colour
clear
Solubility
---
Partition Coefficient
not applicable for mixtures
Form
liquid
Relative Density
---
Softening Point
---
Cloud Point
---
Solubility In Water
completely miscible
Auto Ignition Temperature
---
Odor
odourless
Molecular Weight
---
Flash Point
not applicable, The product has not been tested. The statement has been derived from the properties of the individual components.
Lower Explosive Limit
not determined
Colour Intensity
---
Physical State
liquid
Ph
1,0 - 2,0
Decomposition Temperature
No decomposition if stored and handled as prescribed/indicated.
Physical State Data
liquid
Metal Corrosion
---
Vapor Density
---
Bulk Density
---
Kinematic Viscosity
(40 °C) not determined
Properties Status
---
Crystallisation Point
---
Freezing Point
---
Odor Threshold
---
Appearance
---
Explosive Limits
---
Solidification Point
---
Relative Evaporation Rate
---
Melting Point
0 °C
Voc Content
---
Solubility In Fat
---
Evaporation Rate
---
Dynamic Viscosity
---
State Under Standard Conditions
---
Upper Explosive Limit
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable if stored and handled as prescribed/indicated.

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effect on metals.

Hazardous reactions

Reacts with metals, with evolution of hydrogen.

Avoid

Avoid direct sunlight. Avoid freezing. avoid contact with metals

Incompatible

metal, glass, Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions.

Decomposition

When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced., No hazardous decomposition products if stored and handled as prescribed/indicated.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not discharge into drains/surface waters/groundwater. Observe national and local legal requirements.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3264
Shipping Name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Orthophosphoric acid, NICKEL BIS(DIHYDROGEN PHOSPHATE))
Transport Class
8, EHSM
Packing Group
III
IATA

None known

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Not applicable

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for GARDOBOND R 2600 E27 (BULK)?

The signal word is danger.

What is the physical form of GARDOBOND R 2600 E27 (BULK)?

GARDOBOND R 2600 E27 (BULK) is a liquid with clear color. It has odourless odor.

What is GARDOBOND R 2600 E27 (BULK) used for?

Phosphating solution for metal surfaces.

What are the hazard statements for GARDOBOND R 2600 E27 (BULK)?

This substance has 10 hazard statements:

  • H290: May be corrosive to metals.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer by inhalation.
  • H360: May damage the unborn child.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of GARDOBOND R 2600 E27 (BULK)?

The melting point is 0 °C and the boiling point is not determined.