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Safety Data Sheet EN

KWClean

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
KWClean

Regulatory Identifiers

CAS Number
N/A
UFI Code
FE64-MR0W-AG6S-C9KN

Identified Uses

Cleaner

Uses advised against

Any non-intended use.

Manufacturers & Suppliers

K

Kraul & Wilkening und Stelling GmbH

national supplier

Lohweg 39, D-30559 Hannover

+49-511-51005-57

Dr. Gans-Eichler Chemieberatung GmbH logo

Dr. Gans-Eichler Chemieberatung GmbH

Otto-Hahn-Str. 36, D-48161 Münster

+49(0)2534 6441185

www.tge-consult.de

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

< 5 % anionic surfactants, perfumes (Linalool), preservation agents (Sodium benzoate).

Chemical Name CAS Number Concentration Hazardous
Ethanol, ethyl alcohol EC: 200-578-6 64-17-5 75 - 80% Yes
ethanediol; ethylene glycol EC: 203-473-3 107-21-1 3 - 5% Yes
butanone; ethyl methyl ketone EC: 201-159-0 78-93-3 0.5 - 1% Yes
(2-methoxymethylethoxy)-propanol EC: 252-104-2 34590-94-8 0.2 - 0.3% No

Product does not contain listed SVHC substances > 0.1 % according to Regulation (EC) No. 1907/2006 Article 59 (REACH)

Notes

Full text of H and EUH statements: see section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of accident by inhalation: remove casualty to fresh air and keep at rest. If unconscious place in recovery position and seek medical advice. In case of allergic symptoms, especially in the breathing area, seek medical advice immediately.

Symptoms: allergic symptoms, especially in the breathing area

Skin contact

After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, seek medical treatment.

Symptoms: skin irritation, skin redness

Eye contact

Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Symptoms: eye irritation

Ingestion

Rinse mouth thoroughly with water. Let water be drunken in little sips (dilution effect). Seek medical advice.

Symptoms: nausea after ingestion of large amounts

Immediate Medical Attention

Treat symptomatically. Percutaneously absorbed and inhaled substance causes next to irritation of affected mucous membranes only an indicated impairment of the inhibitory functions of the central nervous system, clinically recognizable as the beginning of a euphoric stage. At the same time face and skin redness is caused by dilation of peripheral blood vessels in the body.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2). Dry extinguishing powder. Alcohol resistant foam. Atomized water.

Unsuitable media

High power water jet.

Specific hazards

In use, may form flammable/explosive vapour-air mixture. Vapours are heavier than air and will spread at floor level.

Instructions

Use water spray jet to protect personnel and to cool endangered containers.

Firefighter Protection

In case of fire: Wear self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

For non-emergency personnel: Remove all sources of ignition. Ventilate affected area. Special danger of slipping by leaking/spilling product. Wear personal protection equipment. (refer to chapter 8). For emergency responders: No special measures are necessary.

Environmental

Do not allow to enter into surface water or drains. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Prevent spread over a wide area (e.g. by containment or oil barriers). In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.

Cleanup methods

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Ventilate affected area. Treat the recovered material as prescribed in the section on waste disposal. Clear contaminated areas thoroughly.

Materials: liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Wear personal protection equipment. (See section 8.)

Storage

Keep/Store only in original container. Keep container tightly closed in a cool, well-ventilated place. Protect against direct sunlight. Ensure adequate ventilation of the storage area. Concentrated vapours are heavier than air. Recommended storage temperature: 5-25°C. Protect against: UV-radiation/sunlight. heat. Cold.

Hygiene

Always close containers tightly after the removal of product. When using do not eat, drink or smoke. Wash hands before breaks and after work. Take off contaminated clothing. Protect skin by using skin protective cream. General protection and hygiene measures: refer to chapter 8

Fire prevention

Keep away from sources of ignition. - No smoking. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and the application of suitable work processes have priority over personal protection equipment. Provide adequate ventilation. If local exhaust ventilation is not possible or not sufficient, the entire working area should be ventilated by technical means.

Hands

In case of prolonged or frequently repeated skin contact: Tested protective gloves are to be worn: Suitable material: Butyl rubber. Thickness of glove material: 0,5 mm Breakthrough time >=480 min, Penetration time (maximum wearing period): 160 min) FKM (fluororubber). Thickness of glove material: 0,5 mm Breakthrough time >=480 min, Penetration time (maximum wearing period): 160 min) CR (polychloroprenes, Chloroprene rubber). Thickness of glove material: 0,4 mm, Breakthrough time >=120 min, Penetration time (maximum wearing period): 40 min) For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The selected protective gloves have to satisfy the specifications of EU Directive EC/2016/425 and the standard EN 374 derived from it. Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them before taking off and air them well.

Eyes

Tightly sealed safety glasses. EN 166

Respiratory

With correct and proper use, and under normal conditions, breathing protection is not required. Respiratory protection necessary at: - Insufficient ventilation - Exceeding exposure limit values - Generation/formation of aerosols Suitable respiratory protective equipment: gas filtering equipment (EN 141). type: A The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190).

Skin/Body

Protective clothing. (fire retardant.)

Environmental

Do not allow to enter into surface water or drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
blue
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
not determined
Ph
not determined
Melting Point
not determined
Boiling Point
~78 °C
Flash Point
16 °C
Freezing Point
not determined
Softening Point
not relevant
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not determined
Vapor Pressure
Ethanol: 58,0 hPa
Vapor Density
---
Relative Density
---
Bulk Density
not relevant
Density
Ethanol: 0,79 g/cm³
Flammability
not determined
Upper Explosive Limit
Ethanol: 27,7 vol. %
Lower Explosive Limit
Ethanol: 3,1 vol. %
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
---
Solubility In Water
complete miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
not determined
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable under storage at normal ambient temperatures.

Reactivity

No information available.

Hazardous reactions

Explosion risk in contact with: Oxidizing agents, strong. nitric acid. Hydrogenium peroxide. Exothermic reactions with: Alkali metals. Alkaline earth metals. Reducing agents, strong.

Avoid

Keep away from heat. Protect against direct sunlight. Protect from moisture. In use may form flammable/explosive vapour-air mixture. Heating causes rise in pressure with risk of bursting.

Incompatible

Strong acid. Oxidizing agents. Alkali metals. Alkaline earth metals. Peroxides. phosphorus oxides. Nitrogen oxides (NOx). Hydrogenium peroxide. Nitric acid. hydrochloric acid. Sulfuric acid. Perchlorates. Chromium oxides. Acid chlorides.

Decomposition

Does not decompose when used for intended uses.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Based on available data, the classification criteria are not met. | CAS No | Chemical name | | --- | --- | | | Aquatic toxicity | Dose | [h] | [d] | Species | Source | Method | | 64-17-5 | Ethanol, ethyl alcohol | | | Acute fish toxicity | LC50 14200 mg/l | 96 h | Pimephales promelas | ECHA Dossier | | | | Acute algae toxicity | ErC50 275 mg/l | 72 h | Chlorella vulgaris | ECHA Dossier | | | | Acute crustacea toxicity | EC50 5012 mg/l | 48 h | Ceriodaphnia dubia | ECHA Dossier | | | | Crustacea toxicity | NOEC 9,6 mg/l | 9 d | Daphnia magna | ECHA Dossier | | | 107-21-1 | ethanediol; ethylene glycol | | | Acute fish toxicity | LC50 72860 mg/l | 96 h | Pimephales promelas | ECHA Dossier | | | | Acute crustacea toxicity | EC50 >100 mg/l | 48 h | Daphnia magna | ECHA Dossier | | | | Fish toxicity | NOEC >40 mg/l | 28 d | Menidia peninsulae | ECHA Dossier | ASTM E-47.01 | | | Crustacea toxicity | NOEC 8590 mg/l | 7 d | Ceriodaphnia dubia | ECHA Dossier | EPA 600/4-89/001. U.S. Environmen | | | Acute bacteria toxicity | (EC50 >10000 mg/l) | | Pseudomonas putida | ECHA Dossier | | | 78-93-3 | butanone; ethyl methyl ketone | | | Acute fish toxicity | LC50 1656 mg/l | 96 h | Pimephales promelas | ECHA Dossier | | | | Acute algae toxicity | ErC50 1982 mg/l | 72 h | Pseudokirchnerella subcapitata | ECHA Dossier | | | | Acute crustacea toxicity | EC50 308 mg/l | 48 h | Daphnia magna | ECHA Dossier | | | | Acute bacteria toxicity | (EC50 1150 mg/l) | | Pseudomonas putida (16h) | ECHA Dossier | | | 34590-94-8 | (2-methoxymethylethoxy)-propanol | | | Acute fish toxicity | LC50 >1000 mg/l | 96 h | Poecilia reticulata | ECHA Dossier | OECD 203 | | | Acute algae toxicity | ErC50 >1000 mg/l | 72 h | Pseudokirchnerella subcapitata (OECD 201) | ECHA Dossier | OECD 201 | | | Acute crustacea toxicity | EC50 1919 mg/l | 48 h | Daphnia magna | ECHA Dossier | OECD 202 | | | Crustacea toxicity | NOEC >= 0.5 mg/l | 22 d | Daphnia magna | ECHA Dossier | OECD 211 |

Based on available data, the classification criteria are not met.

12.2. Persistence and degradability

12.2. Persistence and degradability | CAS No | Chemical name | | | | | --- | --- | --- | --- | --- | | | Method | Value | d | Source | | | Evaluation | | | | | 64-17-5 | Ethanol, ethyl alcohol | | | | | | other guideline: - | 84% | 20 | ECHA Dossier | | | Biodegradable. | | | | | 107-21-1 | ethanediol; ethylene glycol | | | | | | OECD 301A / ISO 7827 / EEC 92/69 annex V, C.4-A | 100% | 28 | ECHA Dossier | | | Easily biodegradable (concerning to the criteria of the OECD) | | | | | 78-93-3 | butanone; ethyl methyl ketone | | | | | | OECD 301D/ EEC 92/69/V, C.4-E | 98% | 28 | ECHA Dossier | | | Readily biodegradable (according to OECD criteria). | | | | | 34590-94-8 | (2-methoxymethylethoxy)-propanol | | | | | | OECD 301F / ISO 9408 / EEC 92/69 annex V, C.4-D | >60% | 28 | ECHA Dossier | | | Readily biodegradable (according to OECD criteria). | | | |

12.3. Bioaccumulative potential

Partition coefficient n-octanol/water CAS No | Chemical name | Log Pow 64-17-5 | Ethanol, ethyl alcohol | -0,35 107-21-1 | ethanediol; ethylene glycol | -1,36 78-93-3 | butanone; ethyl methyl ketone | 0,29 34590-94-8 | (2-methoxymethylethoxy)-propanol | 0,0043

12.4. Mobility in soil

Ethanol. (CAS-No.: 64-17-5): Volatility Henry constant: 3,3*10-6 atm. m3/mol; dimension less 1,28*10-4 (Calculation method.) Distribution: Calculation according to: Mackay, EPIWIN: Air. 45,0%; Water. 33,1%; soil: 13,7%; sediment: 0,1%

12.5. Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. The aforementioned statement applies to substances contained in the product with a minimum content of 0.1%.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Endocrine disrupting properties

This product does not contain a substance that has endocrine disrupting properties with respect to non-target organisms as no components meets the criteria. The aforementioned statement applies to substances contained in the product with a minimum content of 0.1%.

The product does not contain substances with endocrine disrupting properties at concentrations of 0.1% or higher.

12.7. Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 1993
Shipping Name
FLAMMABLE LIQUID, N.O.S. (Ethanol)
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (amended by Regulation (EU) No 2020/878). The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for KWClean?

The signal word is danger.

What is the physical form of KWClean?

KWClean is a liquid with blue color. It has characteristic odor.

What is KWClean used for?

Cleaner

What are the hazard statements for KWClean?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H319: Causes serious eye irritation.

What is the melting point of KWClean?

The melting point is not determined and the boiling point is ~78 °C.