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Safety Data Sheet EN

Diethylamine

CAS 109-89-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Diethylamine
Product Code
471216
Chemical Name
Diethylamine

Regulatory Identifiers

CAS Number
109-89-7 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 4 H332
Acute Tox. Cat. 3 H311
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H225 Highly flammable liquid and vapor.
H301 + H311 Toxic if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
diethylamine EC: 203-716-3 109-89-7 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician (for inhalation, skin contact, and ingestion). Immediately call in ophthalmologist (for eye contact).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx), Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Instructions

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Flash back possible over considerable distance. Container explosion may occur under fire conditions. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Splash contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 120 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M)

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Density
0,707 g/mL at 25 °C
Explosive Limits
---
Melting Point
-50 °C
Dynamic Viscosity
0,319 mPa.s at 25 °C
Boiling Point
55 °C
Flammability
---
Solidification Point
---
Physical State
liquid
Vapor Pressure
316 hPa at 25 °C
Cloud Point
---
Relative Density
0,71 at 20 °C
Crystallisation Point
---
Odor
ammoniacal
State Under Standard Conditions
---
Colour
colorless
Solubility In Water
completely miscible
Metal Corrosion
---
Vapor Density
---
Molecular Weight
---
Decomposition Temperature
---
Relative Evaporation Rate
---
Voc Content
---
Odor Threshold
---
Auto Ignition Temperature
312 °C
Form
---
Properties Status
---
Lower Explosive Limit
2,0 % (V)
Bulk Density
---
Solubility In Fat
---
Ph
---
Softening Point
---
Colour Intensity
---
Flash Point
-26 °C
Evaporation Rate
---
Appearance
---
Physical State Data
liquid
Upper Explosive Limit
11,8 % (V)
Freezing Point
---
Partition Coefficient
log Pow: 0,58
Solubility
---
Kinematic Viscosity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines! Exothermic reaction with: nitrites, Strong acids, Acid anhydrides, Alcohols, Aldehydes, Ketones, Esters, Halogenated hydrocarbon, phenols, Mercury. Risk of ignition or formation of inflammable gases or vapours with: Oxidizing agents. Violent reactions possible with: Lead, Copper, Copper alloys, Zinc, zinc alloys, Tin, Iron, Mild steel.

Avoid

Warming.

Incompatible

Aldehydes, Alcohols, Dicyanofurazan, Ketones, phenols, Acids, Halogenated hydrocarbon, Oxidizing agents, Epoxides

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1154
Shipping Name
DIETHYLAMINE
Transport Class
3 (8)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Diethylamine?

The signal word is danger.

What is the physical form of Diethylamine?

Diethylamine is a liquid with colorless color. It has ammoniacal odor.

What is Diethylamine used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Diethylamine?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H301 + H311: Toxic if swallowed or in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.

What is the melting point of Diethylamine?

The melting point is -50 °C and the boiling point is 55 °C.