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Safety Data Sheet EN

Nitrobenzene

CAS 98-95-3
EC 202-716-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitrobenzene
Product Code
447650000; 447650010; 447652500
Chemical Name
Nitrobenzene
Synonyms
Essence of mirbane; Mirbane oil; Nitrobenzol

Regulatory Identifiers

CAS Number
98-95-3 Check regulations →
EC Number
202-716-0 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

A

Acros Organics BVBA

distributor

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Number US

001-201-796-7100

Emergency Number Europe

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Carc. Cat. 2 H351
Repr. Cat. 1B H360F
STOT RE Cat. 1 H372
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H351 Suspected of causing cancer
H360F May damage fertility
H372 Causes damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Nitrobenzene EC: 202-716-0 98-95-3 99% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Immediate medical attention is required. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Symptoms: Difficulty in breathing.

Skin contact

Immediate medical attention is required. Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: nausea and vomiting

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available.

Specific hazards

Flammable. Combustible material. Containers may explode when heated.

Instructions

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat, sparks and flame.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Viton (R). Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement). Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Eyes

If splashes are likely to occur: Goggles Face protection shield (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
Not applicable
Partition Coefficient
1.9
Boiling Point
210 - 211 °C / 410 - 411.8 °F
Appearance
Yellow
Voc Content
---
Kinematic Viscosity
---
Explosive Limits
---
Decomposition Temperature
No data available
Melting Point
5 - 6 °C / 41 - 42.8 °F
Auto Ignition Temperature
480 °C / 896 °F
Vapor Pressure
0.2 mbar @ 20 °C
Properties Status
---
Lower Explosive Limit
1.8
Density
---
Physical State Data
liquid
Ph
Not applicable
State Under Standard Conditions
---
Form
---
Odor Threshold
No data available
Flammability
Combustible liquid
Cloud Point
---
Crystallisation Point
---
Metal Corrosion
---
Dynamic Viscosity
---
Relative Evaporation Rate
---
Solubility In Fat
---
Evaporation Rate
---
Colour
---
Flash Point
88 °C / 190.4 °F
Solidification Point
---
Solubility
---
Odor
bitter almonds
Upper Explosive Limit
40
Colour Intensity
---
Softening Point
---
Molecular Weight
123.11
Vapor Density
4.25
Relative Density
1.205
Freezing Point
---
Physical State
Liquid
Solubility In Water
slightly soluble
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions, Unstable if heated.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Reducing Agent. Acids. Bases. Alkali metals. Oxidizing agent.

Decomposition

Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1662
Shipping Name
NITROBENZENE
Transport Class
6.1
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Nitrobenzene known by?

Nitrobenzene is also known as: Essence of mirbane; Mirbane oil; Nitrobenzol

What is the hazard signal word for Nitrobenzene?

The signal word is danger.

What is the physical form of Nitrobenzene?

Nitrobenzene is a liquid appearing as yellow . It has bitter almonds odor.

What is Nitrobenzene used for?

Laboratory chemicals.

What are the hazard statements for Nitrobenzene?

This substance has 6 hazard statements:

  • H227: Combustible liquid
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H351: Suspected of causing cancer
  • H360F: May damage fertility
  • H372: Causes damage to organs through prolonged or repeated exposure
  • H412: Harmful to aquatic life with long lasting effects

What is the melting point of Nitrobenzene?

The melting point is 5 - 6 °C / 41 - 42.8 °F and the boiling point is 210 - 211 °C / 410 - 411.8 °F.