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Safety Data Sheet EN

ε-Caprolactam

EC 203-313-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ε-Caprolactam
Product Form
no nanoform
Synonyms
lactam, ε-aminocaproic lactam, azepan-2-one, 6-aminohexanoic acid cyclic lactam, 6-hexanoic lactam, aminocaproic acid lactam

Regulatory Identifiers

CAS Number
N/A
EC Number
203-313-2 Check regulations →
REACH No.
01-2119457029-36-xxxx
UFI Code
not applicable; product is a substance

Identified Uses

Intermediate product for organic syntheses, Monomer for production of polyamide, Monomer for production of resins, Monomer for production of thermally curable resins, Softening agent for polyamide, Use for leather treatment and impregnation as well as component of colorants and coating agents

Uses advised against

Not required

Manufacturers & Suppliers

D

DOMO Caproleuna GmbH

manufacturer

Bau 3101 - Am Haupttor, D-06237 Leuna

+49 34 61 43-22 42

Emergency Contacts

Carechem 24

+44 1235 239670

Carechem 24

+44 1235 239671

Carechem 24

+1 215 207 0061

Carechem 24

+65 3158 1195

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Acute Tox. Cat. 4 H332
STOT SE Cat. 3 H335

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container acc. to Item 13.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Caprolactam EC: 203-313-2 105-60-2 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air. In case of respiratory arrest immediately employ artificial respiration and get medical attention. If the injured is unconscious, lay and transport him/her in recovery position.

Symptoms: narcotising effect, headache, dizziness and nausea

Skin contact

Immediately remove contaminated clothing. Wash affected skin with plenty of water and soap. Cool skin burns caused by liquid product immediately with cold water, get medical attention. Do not peel off solid product from the skin, but remove using water. If irritation persists, get medical attention.

Symptoms: Possible susceptibility to eczema.

Eye contact

Remove contact lenses, if present. Immediately wash for at least 15 minutes under running water with the lids wide open. If available, use Previn solution. Consult a physician.

Ingestion

Rinse the mouth. Drink plenty of water. Avoid vomiting due to danger of aspiration. Get medical advice immediately.

Symptoms: narcotising effect, headache, dizziness and nausea

Immediate Medical Attention

Get medical attention. Show the physician the label of the original product package. Indicate, that liquid caprolactam causes burns.

Medical Treatment

Treat according to symptoms

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, CO₂, foam, powder

Specific hazards

Vapours can form explosive mixtures with air. In case of fire, development of hazardous fire gases or vapours possible. Static charging of the flakes alone or between flakes and liquid may cause ignition of an explosive gas mixture. Product dust accumulating at the workplace may further increase the explosion risk and intensity.

Instructions

Cool affected containers by means of water fog.

Firefighter Protection

Staying in the danger zone is only permitted with self-contained breathing apparatus (with filter type A) and flame retardant full protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid skin contact and inhalation of vapours. Leakages of molten caprolactam involve danger of slipping; therefore isolate place of leakage. Seal the leak as good as possible. Avoid dust formation. Do not inhale dusts. Provide ample fresh air in enclosed rooms.

Environmental

Prevent the substance or contaminated firefighting water from running off into the soil, waterways or ground water.

Cleanup methods

Isolate molten caprolactam leakage, leave to solidify and take up mechanically. Flush away residual product with plenty of water.

Materials: solvent-resistant containers (steel, glass)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

When handling the substance, eye and body protection must be worn. When vapours occur, wear breathing apparatus with filter A.

Storage

Hygroscopic product. Avoid contact with moisture contained in the air. Take precautions against electro-static charging, protect from overheating. Store the liquid product in heatable, heat-insulated containers at a temperature of 80 to 90 °C under inert gas (e. g. nitrogen with a maximum O₂ content of 50 ppm.)

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Observe explosion and fire protection regulations. Have fire extinguisher ready. There must be no sources of ignition within the protected zone.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Suitable technical control devices: See exposure scenarios in Annex.

Hands

Chemical resistant protective gloves (EN 374) Suitable material, also for prolonged direct contact (recommended: protective index 6, i. e. permeation time as per EN 374 > 480 min.): Butyl rubber (butyl) – thickness ≥ 0.7 mm Nitrile rubber (NBR) – thickness 0.4 mm

Eyes

Wear frame goggles with lateral shields.

Respiratory

Ensure adequate ventilation if vapours/aerosols are present. Recommended filter type: FFP2.

Skin/Body

Depending on the activities being carried out and possible exposure wear clothing that covers or protects the entire body, e. g. apron, protective boots, chemical protective overall (as per DIN EN 465).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour Intensity
---
Solubility In Water
866.89 g/l
Solubility In Fat
---
Density
1.015 g/cm³
Appearance
colourless melt/white flakes
Relative Evaporation Rate
---
Upper Explosive Limit
no data available
Dynamic Viscosity
8.23 mPa*s
Solidification Point
---
Molecular Weight
---
State Under Standard Conditions
---
Vapor Density
---
Melting Point
69.3 °C
Evaporation Rate
---
Kinematic Viscosity
---
Solubility
---
Relative Density
1.105
Ph
7-8
Bulk Density
---
Odor Threshold
---
Flash Point
142 °C
Form
---
Metal Corrosion
---
Physical State
liquid (melt)/solid
Decomposition Temperature
no data available
Softening Point
---
Freezing Point
---
Boiling Point
270.8 °C
Cloud Point
---
Physical State Data
solid
Colour
colourless melt/white flakes
Odor
faint specific odour
Auto Ignition Temperature
no data available
Flammability
not flammable
Crystallisation Point
---
Properties Status
---
Vapor Pressure
0.0013 mbar
Explosive Limits
---
Voc Content
---
Partition Coefficient
0.12
Lower Explosive Limit
no data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Caprolactam is a hygroscopic product. No decomposition if used properly.

Reactivity

No dangerous reactions known. If the storage conditions described above are met, there will be no exothermic polymerisation.

Hazardous reactions

No dangerous reactions known.

Avoid

High temperatures and oxygen supply. Oxidation.

Incompatible

Strong oxidants, lyes and acids.

Decomposition

In case of thermal decomposition release of CO, H₂, H₂O, HCN and carbon residues.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

ADR

Keep dry. Faint specific odour. Keep separate from odour-sensitive goods. Keep separate from food and beverages.

IMDG

Keep dry. Faint specific odour. Keep separate from odour-sensitive goods. Keep separate from food and beverages.

IATA

Keep dry. Faint specific odour. Keep separate from odour-sensitive goods. Keep separate from food and beverages.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is ε-Caprolactam known by?

ε-Caprolactam is also known as: lactam, ε-aminocaproic lactam, azepan-2-one, 6-aminohexanoic acid cyclic lactam, 6-hexanoic lactam, aminocaproic acid lactam

What is the hazard signal word for ε-Caprolactam?

The signal word is warning.

What is the physical form of ε-Caprolactam?

ε-Caprolactam is a liquid (melt)/solid appearing as colourless melt/white flakes with colourless melt/white flakes color. It has faint specific odour odor.

What is ε-Caprolactam used for?

Intermediate product for organic syntheses, Monomer for production of polyamide, Monomer for production of resins, Monomer for production of thermally curable resins, Softening agent for polyamide, Use for leather treatment and impregnation as well as component of colorants and coating agents

What are the hazard statements for ε-Caprolactam?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.

What is the melting point of ε-Caprolactam?

The melting point is 69.3 °C and the boiling point is 270.8 °C.