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Safety Data Sheet EN

DESMODUR HL BA

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DESMODUR HL BA

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Hardener for coating materials or adhesives for industrial and trade applications

Uses advised against

Not suitable for use in homeworker (DIY) applications.

Manufacturers & Suppliers

C

Covestro Deutschland AG

manufacturer

Covestro-IO-S&A-PSRA-PSI 51365 Leverkusen

+49 214 6009 4068

Emergency Contacts

Sicherheitszentrale Bayer

+49 214 30 99300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P280 Wear protective gloves/ eye protection/ face protection.
P284 Wear respiratory protection.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician.
P403 + P235 Store in a well-ventilated place. Keep cool.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
polyisocyanate based on hexamethylene diisocyanate/toluene diisocyanate 26426-91-5 60% Yes
n-Butyl acetate EC: 204-658-1 123-86-4 40% Yes
Hexamethylene-1,6-diisocyanate 822-06-0 0.5% Yes
toluene 2,4-diisocyanate EC: 209-544-5 584-84-9 0.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If aerosol or vapor is inhaled in high concentrations: Take the person into the fresh air and keep him warm, let him rest; if there is difficulty in breathing, medical advice is required.

Skin contact

In case of skin contact wash affected areas thoroughly with soap and plenty of water. Consult a doctor in the event of a skin reaction.

Eye contact

Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.

Ingestion

DO NOT induce the patient to vomit, medical advice is required.

Medical Treatment

Basic first aid, decontamination, symptomatic treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, extinguishing powder, in cases of larger fires, water spray should be used.

Unsuitable media

High volume water jet

Specific hazards

Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen, isocyanate vapors and traces of hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes.

Firefighter Protection

In the event of fire and/or explosion do not breathe fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Put on protective equipment (see section 8). Keep away from sources of ignition. Ensure adequate ventilation/exhaust extraction. Keep unauthorized persons away.

Environmental

Do not allow to escape into waterways, wastewater or soil.

Cleanup methods

Remove mechanically; cover the remainder with wet, absorbent material. After approx. one hour transfer to waste container and do not seal (evolution of CO2!). Keep damp in a safe ventilated area for several days.

Materials: wet, absorbent material (e.g. sawdust, chemical binder based on calcium silicate hydrate, sand)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

The personal protective measures described in section 8 must be observed. The precautions required in the handling of solvents and isocyanates must be taken. Avoid contact with skin and eyes and the inhalation of vapor.

Storage

Keep container dry and tightly closed in a cool and well ventilated place.

Hygiene

Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at end of work and use skin-protecting ointment. Keep working clothes separately. Take off all contaminated clothing immediately.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Conditionally suitable materials for protective gloves; EN 374: Nitrile rubber - NBR (>= 0.35 mm) Only suitable as splash protection. Only suitable for brief exposure. In the event of contamination, change protective gloves immediately.

Eyes

Wear eye/face protection.

Respiratory

Respiratory protection required in insufficiently ventilated working areas and during spraying. An air-fed mask, or for short periods of work, a combination of charcoal filter and particulate filter is recommended. In case of hypersensitivity of the respiratory tract and skin (e.g. asthmatics and those who suffer from chronic bronchitis and chronic skin complaint) it is inadvisable to work with the product. Symptoms affecting the respiratory tract can also occur several hours after overexposure.

Skin/Body

Wear suitable protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
yellowish
Colour Intensity
---
Form
---
Odor
solvent-like
Odor Threshold
not established
Ph
not applicable
Melting Point
ca. -15 °C
Boiling Point
ca. 125 °C at 1.013 hPa
Flash Point
ca. 28 °C DIN 53213
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not established
Vapor Pressure
< 20 hPa at 20 °C
Vapor Density
not established
Relative Density
---
Bulk Density
---
Density
ca. 1,13 g/cm³ at 20 °C DIN 51757
Flammability
not applicable
Upper Explosive Limit
n-Butyl acetate upper: 7,5 %(V) / Hexamethylene-1,6-diisocyanate upper: 9,5 %(V)
Lower Explosive Limit
n-Butyl acetate lower: 1,2 %(V) / Hexamethylene-1,6-diisocyanate lower: 0,9 %(V)
Explosive Limits
---
Auto Ignition Temperature
ca. 440 °C DIN 51794
Decomposition Temperature
not established
Solubility
---
Partition Coefficient
---
Solubility In Water
immiscible at 15 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
ca. 2.200 mPa.s at 23 °C DIN EN ISO 3219/A.3
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

This information is not available.

Reactivity

This information is not available.

Hazardous reactions

Exothermic reaction with amines and alcohols; reacts with water forming CO2; in closed containers, risk of bursting owing to increase of pressure.

Avoid

This information is not available.

Incompatible

This information is not available.

Decomposition

No hazardous decomposition products when stored and handled correctly.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1866
Shipping Name
RESIN SOLUTION
Transport Class
3
Packing Group
III
ADR

See section 6 - 8. Additional information: Combustible. Keep dry. Avoid heat above +40 °C. Keep separated from foodstuffs.

IMDG

See section 6 - 8. Additional information: Combustible. Keep dry. Avoid heat above +40 °C. Keep separated from foodstuffs.

IATA

See section 6 - 8. Additional information: Combustible. Keep dry. Avoid heat above +40 °C. Keep separated from foodstuffs.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DESMODUR HL BA?

The signal word is danger.

What is the physical form of DESMODUR HL BA?

DESMODUR HL BA is a liquid appearing as liquid with yellowish color. It has solvent-like odor.

What is DESMODUR HL BA used for?

Hardener for coating materials or adhesives for industrial and trade applications

What are the hazard statements for DESMODUR HL BA?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapour.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H336: May cause drowsiness or dizziness.

What is the melting point of DESMODUR HL BA?

The melting point is ca. -15 °C and the boiling point is ca. 125 °C at 1.013 hPa.