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Safety Data Sheet EN

Menadione

CAS 58-27-5
EC 200-372-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Menadione
Product Code
1T96
Chemical Name
Menadione
Synonyms
Menadione

Regulatory Identifiers

CAS Number
58-27-5 Check regulations →
EC Number
200-372-6 Check regulations →

Identified Uses

Laboratory and analytical use Laboratory chemical

Uses advised against

Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Centre, Beaumont Hospital

+353 1 809 2166

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P280 Wear protective gloves/eye protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell
P302 + P352 IF ON SKIN: Wash with plenty of water
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Name of substance Menadione Molecular formula C₁₁H₈O₂ Molar mass 172,2[g] /mol CAS No 58-27-5 EC No 200-372-6

Chemical Name CAS Number Concentration Hazardous
Menadione EC: 200-372-6 58-27-5 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air.

Symptoms: Cough, Dyspnoea

Skin contact

Rinse skin with water/shower. After contact with skin, wash immediately with plenty of water. In case of skin reactions, consult a physician. In case of skin irritation, consult a physician.

Eye contact

Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist.

Ingestion

Rinse mouth with water (only if the person is conscious). Call a doctor.

Symptoms: Vomiting

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings! water, foam, dry extinguishing powder, ABC-powder

Unsuitable media

water jet

Specific hazards

Combustible.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin, eyes and clothes. Do not breathe dust.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Take up mechanically.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provision of sufficient ventilation. Avoid dust formation.

Storage

Store in a dry place.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: NBR (Nitrile rubber). Material thickness: >0,11 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P2 (filters at least 94 % of airborne particles, colour code: White).

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Explosive Limits
---
Solubility In Fat
---
Properties Status
---
Relative Density
---
Dynamic Viscosity
---
Solubility In Water
0,0915[g] /l at 20 °C (ECHA)
Partition Coefficient
2,43 (pH value: 6,2, 30 °C) (ECHA)
Appearance
---
Colour
light yellow
Crystallisation Point
---
Vapor Density
---
Odor
characteristic
Bulk Density
---
Decomposition Temperature
not relevant
Upper Explosive Limit
not relevant (solid)
Colour Intensity
---
Molecular Weight
---
Physical State
solid
State Under Standard Conditions
---
Vapor Pressure
0,0695 Pa at 25 °C
Freezing Point
---
Relative Evaporation Rate
---
Metal Corrosion
---
Boiling Point
not determined
Solubility
---
Lower Explosive Limit
not relevant (solid)
Cloud Point
---
Kinematic Viscosity
not relevant
Evaporation Rate
---
Ph
not applicable
Softening Point
---
Solidification Point
---
Flammability
this material is combustible, but will not ignite readily
Auto Ignition Temperature
not determined
Melting Point
105 – 107 °C
Flash Point
not applicable
Voc Content
---
Physical State Data
solid
Form
crystalline
Odor Threshold
---
Density
not determined
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

May cause decomposition by long-term light influence.

Reactivity

The product in the delivered form is not dust explosion capable; the enrichment of fine dust however leads to the danger of dust explosion.

Hazardous reactions

Violent reaction with: strong oxidiser, Alkalis, Acids

Avoid

Direct light irradiation. Protect from moisture. Keep away from heat.

Incompatible

There is no additional information.

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport Class
9
Packing Group
III
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Menadione known by?

Menadione is also known as: Menadione

What is the hazard signal word for Menadione?

The signal word is warning.

What is the physical form of Menadione?

Menadione is a solid with light yellow color. It has characteristic odor.

What is Menadione used for?

Laboratory and analytical use Laboratory chemical

What are the hazard statements for Menadione?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed
  • H315: Causes skin irritation
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of Menadione?

The melting point is 105 – 107 °C and the boiling point is not determined.