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Safety Data Sheet EN

Chloroform for gas chromatography ECD and FID SupraSolv®

CAS 67-66-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chloroform for gas chromatography ECD and FID SupraSolv®
Product Code
1.02432
Chemical Name
Chloroform

Regulatory Identifiers

CAS Number
67-66-3 Check regulations →
REACH No.
01-2119486657-20-XXXX

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 2 H351
Repr. Cat. 2 H361d
STOT SE Cat. 3 H336
STOT RE Cat. 1 H372

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Index-No. : 602-006-00-4 EC-No. : 200-663-8 Millipore- 1.02432 The life science business of Merck operates as MilliporeSigma in the US and Canada

Chemical Name CAS Number Concentration Hazardous
Chloroform EC: 200-663-8 67-66-3 90 - 100% Yes
ethanol EC: 200-578-6 64-17-5 1 - 10% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Fire may cause evolution of: Hydrogen chloride gas, Phosgene, Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Protected from light. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material : Viton® Break through time : 480 min Glove thickness : 0,7 mm Protective index : Full contact Manufacturer : Vitoject® (KCL 890 / Aldrich Z677698, Size M) Material : butyl-rubber Break through time : 10 min Glove thickness : 0,7 mm Protective index : Splash contact Manufacturer : Butoject® (KCL 898) Remarks: This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type : Filter type AX The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
sweet
Odor Threshold
84,9 - 201,5 ppm
Ph
No data available
Melting Point
-63 °C
Boiling Point
ca. 61 °C (1,013 hPa)
Flash Point
Method: DIN 51755 Part 1 does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
211 hPa (20 °C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,48 g/cm3 (20 °C)
Flammability
The product is not flammable.
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
not combustible
Decomposition Temperature
Distillable in an undecomposed state at normal pressure.
Solubility
---
Partition Coefficient
log Pow: 2 (25 °C) Method: (experimental) (IUCLID)
Solubility In Water
8,7 g/l (23 °C) Method: OECD Test Guideline 105
Solubility In Fat
---
Molecular Weight
119,38 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0,57 mPa.s (20 °C)
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabiliser(s): ethanol(1 %)

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Ammonia, Amines, nitrogen oxides, Bases, Oxygen, alkali amides, organic nitro compounds, strong alkalis, Fluorine, peroxi compounds, Alkaline earth metals. Alkali metals, Powdered metals, Methanol with alcoholates, Methanol with strong alkalis, Iron in powder form, various alloys sensitive to shock, Methanol with Sodium hydroxide, Magnesium in powder form, Oxygen with alkali compounds, Aluminium in powder form, Acetone with alkali compounds, Potassium sensitive to shock, sodium sensitive to shock. Violent reactions possible with: phosphines, bis(dimethylamino)dimethyl tin, nonmetallic hydrogen compounds, Powdered metals, Light metals, Ketones, mineral acids, Strong oxidizing agents, semimetallic hydrogen compounds

Avoid

heat-sensitive, Sensitivity to light

Incompatible

Ammonia, Amines, nitrogen oxides, Bases, Oxygen, alkali amides, organic nitro compounds, strong alkalis, Fluorine, peroxi compounds, Alkaline earth metals, Alkali metals, Powdered metals, Methanol with alcoholates, Methanol with strong alkalis, Iron in powder form, various alloys, Magnesium in powder form, Oxygen with alkali compounds, Aluminium in powder form, Acetone with alkali compounds, Potassium, sodium, phosphines, bis(dimethylamino)dimethyl tin, nonmetallic hydrogen compounds, Light metals, Ketones, mineral acids, Strong oxidizing agents, semimetallic hydrogen compounds

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1888
Shipping Name
CHLOROFORM, SOLUTION
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chloroform for gas chromatography ECD and FID SupraSolv®?

The signal word is danger.

What is the physical form of Chloroform for gas chromatography ECD and FID SupraSolv®?

Chloroform for gas chromatography ECD and FID SupraSolv® is a liquid with colourless color. It has sweet odor.

What is Chloroform for gas chromatography ECD and FID SupraSolv® used for?

Reagent for analysis

What are the hazard statements for Chloroform for gas chromatography ECD and FID SupraSolv®?

This substance has 8 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H331: Toxic if inhaled.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H361d: Suspected of damaging the unborn child.
  • H372: Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed.

What is the melting point of Chloroform for gas chromatography ECD and FID SupraSolv®?

The melting point is -63 °C and the boiling point is ca. 61 °C (1,013 hPa).