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Safety Data Sheet EN

Cyclohexanone

CAS 108-94-1
EC 203-631-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Cyclohexanone
Product Form
Substance
Chemical Name
cyclohexanone

Regulatory Identifiers

CAS Number
108-94-1 Check regulations →
EC Number
203-631-1 Check regulations →
REACH No.
01-2119453616-35-0057

Identified Uses

Professional use, Industrial use. Formulation or re-packing- Formulation of the substance (industrial) (ES Ref.: 1); Use as an intermediate (ES Ref.: 02)

Uses advised against

No additional information available

Manufacturers & Suppliers

Kolmar NL B.V. logo

Kolmar NL B.V.

national supplier

Claude Debussylaan 10, 1082MD Amsterdam, The Netherlands

+31 20 705 5400

http://www.kolmargroup.com

Emergency Contacts

National Poisons Information Centre Beaumont Hospital

+353 1 809 2566

24/7

National Poisons Information Centre Beaumont Hospital

+353 1 809 2166

8am - 10pm, 7/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P270 Do not eat, drink or smoke when using this product.
P280 Wear eye protection, protective clothing, protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER, a doctor.
P403 + P235 Store in a well-ventilated place. Keep cool.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
cyclohexanone EC: 203-631-1 108-94-1 99% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep warm and at rest.

Symptoms: May cause respiratory irritation. Harmful if inhaled.

Skin contact

Remove contaminated clothing and shoes. Gently wash with plenty of soap and water. In case of doubt or persistent symptoms, consult always a physician.

Symptoms: Causes skin irritation. Harmful in contact with skin.

Eye contact

Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

Symptoms: Causes serious eye damage.

Ingestion

Rinse mouth thoroughly with water. Get medical advice/attention.

Symptoms: Harmful if swallowed. The following symptoms may occur: May cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Immediate Medical Attention

Get immediate medical advice/attention (for eyes). In case of doubt or persistent symptoms, consult always a physician.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

carbon dioxide (CO2), powder, alcohol-resistant foam, water spray.

Unsuitable media

Strong water jet.

Specific hazards

Flammable liquid and vapour. Heating will cause a rise in pressure with a risk of bursting. Vapours may form explosive mixture with air. Vapours are heavier than air and may travel considerable distance to an ignition source and flash back to source of vapours.

Instructions

Evacuate area. Use water spray or fog for cooling exposed containers. Contain the extinguishing fluids by bunding. Prevent fire fighting water from entering the environment.

Firefighter Protection

Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate unnecessary personnel. Keep upwind. Provide adequate ventilation. Ensure procedures and training for emergency decontamination and disposal are in place.

Small spill

Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal.

Large spill

Recover large spills by pumping (use an explosion proof or hand pump).

Environmental

Do not allow to enter into surface water or drains.

Cleanup methods

Stop leak if safe to do so. Dam up the liquid spill. Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Recover large spills by pumping (use an explosion proof or hand pump). Place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Cover the spilled liquid product with foam to slow down evaporation.

Materials: non-combustible absorbent material, foam

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provide adequate ventilation. Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. Do not breathe vapours. Avoid contact with skin, eyes and clothing. Take any precaution to avoid mixing with Incompatible materials, Refer to Section 10 on Incompatible Materials. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Avoid release to the environment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools.

Storage

Store in a dry, cool and well-ventilated place. Do not store near or with any of the incompatible materials listed in section 10. Bund storage facilities to prevent soil and water pollution in the event of spillage. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Hygiene

Keep good industrial hygiene. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. Keep away from food, drink and animal feedingstuffs. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. Wash contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Organisational measures to prevent/limit releases, dispersion and exposure. See Section 7 for information on safe handling. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use only outdoors or in a well-ventilated area. Take precautionary measures against static discharges. Ensure equipment is adequately earthed. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc.

Hands

Wear chemically resistant gloves (tested to EN374). Suitable material: Not determined. Thickness. Not determined. Breakthrough time : refer to the recommendations of the supplier. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances.

Eyes

Use suitable eye protection (EN166): goggles. face shield

Respiratory

In case of insufficient ventilation, wear suitable respiratory equipment. Half-face mask (DIN EN 140). full face mask (DIN EN 136). Filter type: ABEK(EN14387). The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. (EN 137)

Skin/Body

Wear suitable coveralls to prevent exposure to the skin. (Use chemically protective clothing)

Environmental

Avoid release to the environment. Comply with applicable Community environmental protection legislation.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
---
Relative Density
0,947 g/cm³ (20 °C)
Upper Explosive Limit
Not available
Decomposition Temperature
No data available
Physical State Data
liquid
Odor Threshold
No data available
Melting Point
-31 °C (101,3 kPa)
Kinematic Viscosity
No data available
Relative Evaporation Rate
---
Physical State
Liquid
State Under Standard Conditions
---
Appearance
Liquid.
Crystallisation Point
---
Explosive Limits
---
Partition Coefficient
0,86 (25 °C)
Solubility In Fat
---
Flash Point
44 °C (101,3 kPa)
Ph
No data available
Cloud Point
---
Solubility In Water
0,86 g/l (20 °C)
Dynamic Viscosity
2,2 mPa·s (25 °C)
Properties Status
---
Metal Corrosion
---
Lower Explosive Limit
Not available
Solubility
Water: 0,86 g/l (20 °C)
Molecular Weight
---
Form
---
Vapor Pressure
7 hPa (30 °C)
Flammability
Flammable
Voc Content
---
Evaporation Rate
---
Freezing Point
Not available
Colour
Colourless.
Solidification Point
---
Auto Ignition Temperature
420 °C (101,3 kPa)
Colour Intensity
---
Density
---
Boiling Point
154,3 °C (101,3 kPa)
Vapor Density
No data available
Odor
acetone-like.
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Flammable liquid and vapour. Reference to other sections: 10.4 & 10.5.

Hazardous reactions

Vapours may form explosive mixture with air. No dangerous reactions known under normal conditions of use.

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible

oxidising substances

Decomposition

Reference to other sections 5.2.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1915
Shipping Name
CYCLOHEXANONE
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Cyclohexanone?

The signal word is danger.

What is the physical form of Cyclohexanone?

Cyclohexanone is a liquid appearing as liquid. with colourless. color. It has acetone-like. odor.

What is the solubility of Cyclohexanone?

Water: 0,86 g/l (20 °C)

What is Cyclohexanone used for?

Professional use, Industrial use. Formulation or re-packing- Formulation of the substance (industrial) (ES Ref.: 1); Use as an intermediate (ES Ref.: 02)

What are the hazard statements for Cyclohexanone?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of Cyclohexanone?

The melting point is -31 °C (101,3 kPa) and the boiling point is 154,3 °C (101,3 kPa).