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Safety Data Sheet EN

Diketene

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Diketene
Product Code
422363

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+18003255832

Emergency Contacts

Emergency Contact

(314) 776-6555

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq.
Acute Tox.
Acute Tox.
Skin Irrit.

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

Hazard Statements

H226 Flammable Liquid
H302 Harmful if swallowed
H315 Causes skin irritation
H320 Causes eye irritation
H331 Toxic if inhaled
Causes respiratory tract irritation
May be harmful if absorbed through skin

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Diketene EC: 211-617-1 674-82-8 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Immediate Medical Attention

Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.

Unsuitable media

solid streams of water may be ineffective

Instructions

For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray. Cool all affected containers with flooding quantities of water.

Firefighter Protection

Wear self contained breathing apparatus for fire fighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Environmental

Do not let product enter drains.

Cleanup methods

collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal.

Materials: non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

Storage

Keep container tightly closed in a dry and well-ventilated place. Store in cool place.

Fire prevention

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves.

Eyes

Face shield and safety glasses

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Choose body protection according to the amount and concentration of the dangerous substance at the work place.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Odor
---
Solubility In Water
no data available
Physical State
liquid
Dynamic Viscosity
---
Upper Explosive Limit
no data available
Density
1.09 g/mL at 25 °C (77 °F)
Solubility In Fat
---
Colour Intensity
---
Explosive Limits
---
Auto Ignition Temperature
310 °C (590 °F)
Relative Evaporation Rate
---
Cloud Point
---
Colour
yellow
Freezing Point
---
Relative Density
---
State Under Standard Conditions
---
Lower Explosive Limit
no data available
Molecular Weight
---
Flammability
---
Flash Point
34 °C (93 °F) - closed cup
Form
clear, liquid
Vapor Pressure
10.5 hPa (7.9 mmHg) at 20 °C (68 °F); 68 hPa (51 mmHg) at 55 °C (131 °F)
Properties Status
---
Bulk Density
---
Kinematic Viscosity
---
Odor Threshold
---
Softening Point
---
Decomposition Temperature
---
Partition Coefficient
---
Boiling Point
69 - 70 °C (156 - 158 °F) at 133 hPa (100 mmHg) - lit.
Ph
no data available
Crystallisation Point
---
Vapor Density
---
Voc Content
---
Metal Corrosion
---
Solubility
---
Appearance
clear, liquid
Evaporation Rate
---
Melting Point
no data available
Physical State Data
liquid
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Hazardous reactions

Vapours may form explosive mixture with air.

Avoid

Do not allow water to enter container because of violent reaction. Heat, flames and sparks.

Incompatible

Strong oxidizing agentsacids, Bases, Amines, glass, Soda glass, Oxidizing agents

Decomposition

Hazardous decomposition products formed under fire conditions. - Carbon oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Burn in a chemical incinerator equipped with an afterburner and scrubber.

Disposal

Contact a licensed professional waste disposal service to dispose of this material.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2521
Shipping Name
Diketene, stabilized
Transport Class
6.1 (3)
Packing Group
I
IMDG

F-E, S-D

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

OSHA Hazards: Flammable Liquid, Toxic by inhalation., Harmful by ingestion., Irritant

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Diketene?

The signal word is danger.

What is the physical form of Diketene?

Diketene is a liquid appearing as clear, liquid with yellow color.

What are the hazard statements for Diketene?

This substance has 7 hazard statements:

  • H226: Flammable Liquid
  • H302: Harmful if swallowed
  • H315: Causes skin irritation
  • H320: Causes eye irritation
  • H331: Toxic if inhaled
  • Causes respiratory tract irritation
  • May be harmful if absorbed through skin

What is the melting point of Diketene?

The melting point is no data available and the boiling point is 69 - 70 °C (156 - 158 °F) at 133 hPa (100 mmHg) - lit..