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Safety Data Sheet EN

LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst
Product Code
18398

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Adhesive

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608 (toll free)

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300 (toll free)

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 4
Eye Irrit. Cat. 2B
Carc. Cat. 2
STOT SE Cat. 3

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

EUH202 BONDS SKIN IN SECONDS.
H227 COMBUSTIBLE LIQUID.
H320 CAUSES EYE IRRITATION.
H335 MAY CAUSE RESPIRATORY IRRITATION.
H351 SUSPECTED OF CAUSING CANCER.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames, hot surfaces - no smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P261 Avoid breathing vapors, mist, or spray.
P264 Wash affected area thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, clothing, eye and face protection.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P312 Call a POISON CENTER or physician if you feel unwell.
P337 + P313 If eye irritation persists: Get medical attention.
P370 + P378 In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.
P403 Store in a well-ventilated place.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethyl 2-cyanoacrylate 7085-85-0 80 - 100% Yes
Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 1 - 5% Yes
Carbon black - Nano 1333-86-4 1 - 5% Yes
Hydroquinone 123-31-9 0.1 - 1% Yes
Phthalic anhydride 85-44-9 0.1 - 1% Yes

Notes

Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention.

Skin contact

Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force.

Symptoms: Bonded skin, thermal burns due to rapid generation of heat.

Eye contact

Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye open. Keep eye covered until debonding is complete, usually within 1-3 days. Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid caused abrasive damage.

Symptoms: Lachrymatory effect

Ingestion

Ensure breathing passages are not obstructed. Saliva will separate any solidified product in several hours. Prevent the patient from swallowing any separated mass.

Symptoms: Bonding to the mouth, making it almost impossible to swallow.

Immediate Medical Attention

If symptoms develop and persist (inhalation), if skin is burned (skin), or if solid particles of polymerized cyanoacrylate are trapped behind the eyelid.

Medical Treatment

Surgery is not necessary to separate accidentally bonded tissues. Experience has shown that bonded tissues are best treated by passive, non-surgical first aid. If rapid curing has caused thermal burns they should be treated symptomatically after adhesive is removed.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide.

Instructions

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

Firefighter Protection

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor.

Materials: water

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods. Contact with these materials may cause rapid polymerization which can generate smoke and strong irritating vapors, and cause thermal burns.

Storage

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep in a cool, well ventilated area away from heat, sparks and open flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use positive down-draft exhaust ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits.

Hands

Use nitrile gloves and aprons as necessary to prevent contact. Do not use PVC, nylon or cotton.

Eyes

Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists.

Respiratory

Use NIOSH approved respirator if there is potential to exceed exposure limit(s).

Skin/Body

Use nitrile gloves and aprons as necessary to prevent contact. Do not use PVC, nylon or cotton.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Odor
Sharp, Irritating
Cloud Point
---
Solubility In Water
Polymerises in presence of water.
Flammability
Not applicable
Properties Status
---
Auto Ignition Temperature
485 °C (905°F)
Solubility In Fat
---
Physical State
Gel
Melting Point
Not determined
Upper Explosive Limit
Not determined
Crystallisation Point
---
Boiling Point
> 149 °F (> 65°C)
Colour
Black
Partition Coefficient
Not applicable
Lower Explosive Limit
Not determined
Colour Intensity
---
Odor Threshold
1 - 2 ppm
Voc Content
< 2%; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Solidification Point
---
Metal Corrosion
---
Bulk Density
---
Softening Point
---
Vapor Density
3
Freezing Point
---
Evaporation Rate
Not available.
Relative Density
1.05
Solubility
---
Explosive Limits
---
State Under Standard Conditions
---
Decomposition Temperature
Not available.
Density
---
Vapor Pressure
< 0.2 mm hg
Form
---
Physical State Data
liquid
Relative Evaporation Rate
---
Flash Point
65 - 93 °C (149°F - 199.4 °F) Tagliabue closed cup
Kinematic Viscosity
---
Appearance
---
Dynamic Viscosity
---
Ph
Not applicable
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Not available.

Hazardous reactions

Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

Avoid

Spontaneous polymerization.

Incompatible

Water, amines, alkalis and alcohols.

Decomposition

Not available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of according to Federal, State and local governmental regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3334
Shipping Name
Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Transport Class
9
Packing Group
III
IATA

Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst?

The signal word is warning.

What is the physical form of LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst?

LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst is a gel with black color. It has sharp, irritating odor.

What is LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst used for?

Adhesive

What are the hazard statements for LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst?

This substance has 5 hazard statements:

  • EUH202: BONDS SKIN IN SECONDS.
  • H227: COMBUSTIBLE LIQUID.
  • H320: CAUSES EYE IRRITATION.
  • H335: MAY CAUSE RESPIRATORY IRRITATION.
  • H351: SUSPECTED OF CAUSING CANCER.

What is the melting point of LOCTITE 426 BLACK INSTANT ADHESIVE known as 426 Prism® Black Max® Gel Inst?

The melting point is Not determined and the boiling point is > 149 °F (> 65°C).