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Safety Data Sheet EN

Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®
Product Code
188015

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H311
STOT SE Cat. 1 H370

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H370 Causes damage to organs.

Precautionary Statements

P210 Keep away from heat.
P233 Keep container tightly closed.
P280 Wear protective gloves/ protective clothing.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P403 + P235 Store in a well-ventilated place. Keep cool.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Mixture of inorganic and organic compounds

Chemical Name CAS Number Concentration Hazardous
methanol 67-56-1 50 - 100% Yes
Iodine 7553-56-2 0.25 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. If breathing stops: immediately apply artificial respiration, if necessary oxygen. Immediately call in physician.

Skin contact

wash off with plenty of water. Remove contaminated clothing. Call a physician immediately.

Symptoms: Drying-out effect resulting in rough and chapped skin.

Eye contact

rinse out with plenty of water with the eyelid held wide open. Call in ophthalmologist if necessary.

Ingestion

fresh air. Make victim drink ethanol (e.g. 1 drinking glass of a 40% alcoholic beverage). Call a doctor immediately (mention methanol ingestion). Only in exceptional cases, if no medical care is available within one hour, induce vomiting (only in fully conscious persons) and make victim drink ethanol again (approx. 0.3 ml of a 40% alcoholic beverage/kg body weight/hour).

Symptoms: Nausea, Vomiting, Headache, blindness, Impairment of vision, Coma

Immediate Medical Attention

Immediately call in physician.

Medical Treatment

mention methanol ingestion

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapours are heavier than air and may spread along floors. Pay attention to flashback. Forms explosive mixtures with air at ambient temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet. Cool closed containers exposed to fire with water spray.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid substance contact. Do not breathe vapours, aerosols. Keep away from heat and sources of ignition. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Observe label precautions.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: butyl-rubber, Glove thickness: 0,7 mm, Break through time: > 480 min. splash contact: Glove material: Viton (R), Glove thickness: 0,70 mm, Break through time: >120 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL 890 Vitoject® (splash contact).

Eyes

Safety glasses

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter AX (EN 371). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing

Environmental

Do not empty into drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Appearance
---
Metal Corrosion
---
Softening Point
---
Boiling Point
No information available.
Upper Explosive Limit
No information available.
Explosive Limits
---
Kinematic Viscosity
---
Dynamic Viscosity
No information available.
Solubility In Water
No information available.
Vapor Pressure
No information available.
Physical State
liquid
Voc Content
---
Cloud Point
---
State Under Standard Conditions
---
Form
liquid
Bulk Density
---
Flash Point
11 °C
Odor
methanolic
Physical State Data
liquid
Vapor Density
---
Lower Explosive Limit
No information available.
Flammability
No information available.
Ph
No information available.
Decomposition Temperature
No information available.
Freezing Point
---
Solubility In Fat
---
Colour
colourless
Molecular Weight
---
Relative Evaporation Rate
---
Relative Density
0,90 g/cm³ at 20 °C
Crystallisation Point
---
Solubility
---
Solidification Point
---
Evaporation Rate
No information available.
Odor Threshold
No information available.
Density
---
Melting Point
No information available.
Properties Status
---
Partition Coefficient
No information available.
Auto Ignition Temperature
No information available.
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapours may form explosive mixture with air.

Hazardous reactions

Risk of explosion with: Oxidizing agents, perchloric acid, perchlorates, salts of oxyhalogenic acids, chromium(VI) oxide, halogen oxides, nitrogen oxides, nonmetallic oxides, chromosulfuric acid, chlorates, hydrides, zinc diethyl, halogens, magnesium, hydrogen peroxide, Nitric acid. Exothermic reaction with: acid halides, Acid anhydrides, Reducing agents, acids. Generates dangerous gases or fumes in contact with: Alkaline earth metals, Alkali metals.

Avoid

Warming. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Incompatible

various plastics, zinc alloys, magnesium

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1230
Shipping Name
METHANOL SOLUTION
Transport Class
3 (6.1)
Packing Group
II
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®?

The signal word is danger.

What is the physical form of Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®?

Solvent solvent for volumetric Karl Fischer titration with two component reagents apura® is a liquid with colourless color. It has methanolic odor.

What is Solvent solvent for volumetric Karl Fischer titration with two component reagents apura® used for?

Reagent for analysis

What are the hazard statements for Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H301: Toxic if swallowed.
  • H311: Toxic in contact with skin.
  • H331: Toxic if inhaled.
  • H370: Causes damage to organs.

What is the melting point of Solvent solvent for volumetric Karl Fischer titration with two component reagents apura®?

The melting point is No information available. and the boiling point is No information available..