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Safety Data Sheet EN

DAB Away 1

CAS 7664-93-9
EC 231-639-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DAB Away 1
Product Code
SK301
Chemical Name
Electrolyte (sulfuric acid / water / solution)
Synonyms
diwaterstofsulfaat, oplossingen, 94%≤conc≤98% / vitriool, oplossingen, 94%≤conc≤98% / waterstofsulfaat, oplossingen, 94%≤conc≤98% / zwavelzuur, oplossingen, 94%≤conc≤98%

Regulatory Identifiers

CAS Number
7664-93-9 Check regulations →
EC Number
231-639-5 Check regulations →
REACH No.
01-2119458838-20

Identified Uses

Laboratory use

Manufacturers & Suppliers

Dako Denmark A/S logo

Dako Denmark A/S

national supplier

Produktionsvej 42 DK-2600 Glostrup

+45 44 85 95 00

www.agilent.com

Emergency Contacts

CHEMTREC

+(44)-870-8200418

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary Statements

P234 Keep only in original packaging.
P280 Wear protective gloves. Wear eye or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P406 Store in corrosive resistant container with a resistant inner liner.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixture
Chemical Name CAS Number Concentration Hazardous
Sulphuric acid EC: 231-639-5 7664-93-9 10 - 25% Yes

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Causes skin irritation. Adverse symptoms may include the following: irritation, redness.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering, redness.

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediate Medical Attention

Get medical attention (for eye and skin contact). Get medical attention if adverse health effects persist or are severe (for inhalation and ingestion). If unconscious, place in recovery position and get medical attention immediately (for inhalation and ingestion). Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

The spilled material may be neutralized with sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal contractor.

Materials: sodium carbonate, sodium bicarbonate or sodium hydroxide

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store between the following temperatures: 15 to 30C (59 to 86F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Form
---
Bulk Density
---
Physical State
Liquid.
Relative Evaporation Rate
---
Flash Point
Not available.
Metal Corrosion
---
Molecular Weight
---
Vapor Pressure
Not available.
Freezing Point
Not available.
Decomposition Temperature
Not available.
Dynamic Viscosity
Not available.
Cloud Point
---
Crystallisation Point
---
Physical State Data
liquid
Ph
<1
Solubility In Water
Soluble in the following materials: cold water and hot water.
Odor Threshold
Not available.
Solubility
Soluble in the following materials: cold water and hot water.
Solubility In Fat
---
Melting Point
Not available.
Flammability
Not applicable.
Softening Point
---
Lower Explosive Limit
Not available.
Evaporation Rate
Not available.
Appearance
---
Boiling Point
Not available.
Density
---
Vapor Density
Not available.
Colour Intensity
---
Partition Coefficient
Not available.
Explosive Limits
---
State Under Standard Conditions
---
Upper Explosive Limit
Not available.
Solidification Point
---
Colour
Colourless.
Kinematic Viscosity
Not available.
Odor
Sharp.
Relative Density
Not available.
Voc Content
---
Auto Ignition Temperature
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

Attacks many metals producing extremely flammable hydrogen gas which can form explosive mixtures with air. Reactive or incompatible with the following materials: alkalis. Reactive or incompatible with the following materials: reducing materials, organic materials and moisture.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible.

Disposal

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3264
Shipping Name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Sulphuric acid, solution)
Transport Class
8
Packing Group
III
ADR

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is DAB Away 1 known by?

DAB Away 1 is also known as: diwaterstofsulfaat, oplossingen, 94%≤conc≤98% / vitriool, oplossingen, 94%≤conc≤98% / waterstofsulfaat, oplossingen, 94%≤conc≤98% / zwavelzuur, oplossingen, 94%≤conc≤98%

What is the hazard signal word for DAB Away 1?

The signal word is warning.

What is the physical form of DAB Away 1?

DAB Away 1 is a liquid. with colourless. color. It has sharp. odor.

What is the solubility of DAB Away 1?

Soluble in the following materials: cold water and hot water.

What is DAB Away 1 used for?

Laboratory use

What are the hazard statements for DAB Away 1?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.

What is the melting point of DAB Away 1?

The melting point is Not available. and the boiling point is Not available..

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