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Safety Data Sheet EN

Hexane-(n) a.r.

CAS 110-54-3
EC 203-777-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hexane-(n) a.r.
Product Form
Substance
Product Code
CL00.0802
Chemical Name
n-hexane
Synonyms
dipropyl / gettysolve-B / hex (=normal-hexane) / hexane- / hexane, anhydrous / hexane,pure grade / hexyl hydride / high purity normal hexane / n-caproylhydride / n-hexane / n-hexyl hydride / normal-caproyl hydride / normal-hexane / normal-hexyl hydride / skellysolve B / solvent hexane

Regulatory Identifiers

CAS Number
110-54-3 Check regulations →
EC Number
203-777-6 Check regulations →
REACH No.
01-2119480412-44

Identified Uses

Laboratory chemical

Manufacturers & Suppliers

Chem-Lab nv logo

Chem-Lab nv

manufacturer

Industriezone 'De arend 2', Zedelgem – Belgium

+32 50 288320

https://www.chem-lab.be

Emergency Contacts

Chem-Lab nv

+32 50 28 83 20

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Repr. Cat. 2 H361f
Asp. Tox. Cat. 1 H304
STOT RE Cat. 2 H373
Skin Irrit. Cat. 2 H315
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361f Suspected of damaging fertility.
H373 May cause damage to organs (nervous system) through prolonged or repeated exposure (if inhaled).
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P240 Ground and bond container and receiving equipment.
P273 Avoid release to the environment.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P331 Do NOT induce vomiting.
P403 + P235 Store in a well-ventilated place. Keep cool.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Hexane-(n) a.r. EC: 203-777-6 110-54-3 100% Yes

Notes

Full text of H- and EUH-statements: see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. In case of respiratory problems, consult a doctor/medical service.

Symptoms: EXPOSURE TO HIGH CONCENTRATIONS: Nausea. Headache. Dizziness. Disturbances of consciousness. Central nervous system depression. Narcosis. Drunkenness. Drowsiness.

Skin contact

If possible, wipe up/dry remove chemical. Then rinse/shower immediately with (lukewarm) water. If irritation persists, consult a doctor/medical service.

Symptoms: Tingling/irritation of the skin.

Eye contact

Rinse immediately with (lukewarm) water. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, consult a doctor/medical service.

Symptoms: No effects known.

Ingestion

Rinse mouth with water. If you feel unwell, consult a doctor/medical service. Do not wait for symptoms to occur to consult Poison Center.

Symptoms: Nausea. Vomiting. Risk of aspiration pneumonia. Symptoms similar to those listed under inhalation.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (not alcohol-resistant).

Unsuitable media

Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle expansion.

Specific hazards

DIRECT FIRE HAZARD: Highly flammable liquid and vapour. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD: May be ignited by sparks. May build up electrostatic charges: risk of ignition. DIRECT EXPLOSION HAZARD: Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD: may be ignited by sparks.

Instructions

Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Firefighter Protection

Heat/fire exposure: self-contained breathing apparatus (EN 136 + EN 137).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes.

Large spill

Large spills/in enclosed spaces: self-contained breathing apparatus (EN 136 + EN 137). Large spills/in enclosed spaces: gas-tight suit (EN 943).

Environmental

Prevent soil and water pollution. Prevent spreading in sewers.

Cleanup methods

Take up liquid spill into inert absorbent material. Take up liquid spill into a non combustible material e.g.: sand/earth or kieselguhr. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority.

Materials: inert absorbent material, non combustible material e.g.: sand/earth or kieselguhr

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the concentration in the air regularly. Work under local exhaust/ventilation. Comply with the legal requirements. Clean contaminated clothing. Keep container tightly closed. Handle uncleaned empty containers as full ones. Do not discharge the waste into the drain. Do not use compressed air for pumping over.

Storage

Keep container in a well-ventilated place. Fireproof storeroom. Provide for a tub to collect spills. Provide the tank with earthing.

Hygiene

Observe strict hygiene. Clean contaminated clothing.

Fire prevention

Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Fireproof storeroom.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Protective gloves against chemicals (EN 374). Materials for protective clothing: Excellent resistance: Nitrile rubber. Polyvinylalcohol (PVA). Tetrafluoroethylene. Viton. Poor resistance: Butyl rubber. Natural rubber. neoprene (chloroprene rubber). Polyethylene. Polyvinylchloride (PVC). Styrene-butadiene rubber

Eyes

Protective goggles (EN 166)

Respiratory

Full face mask with filter type A at conc. in air > exposure limit

Skin/Body

Protective clothing (EN 14605 or EN 13034). Head/neck protection

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Petroleum-like odour. Mild odour.
Odor Threshold
Not available
Ph
7 (< 0.01 %, 25 °C)
Melting Point
-95 °C
Boiling Point
69 °C
Flash Point
-22 °C
Freezing Point
Not available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
> 10 (butylacetate=1), 1.3 (ether=1)
Evaporation Rate
> 10 (butylacetate=1), 1.3 (ether=1)
Vapor Pressure
100 hPa
Vapor Density
---
Relative Density
0.66
Bulk Density
---
Density
661 kg/m³
Flammability
Not available
Upper Explosive Limit
7.5 vol %
Lower Explosive Limit
1.1 vol %
Explosive Limits
---
Auto Ignition Temperature
280 °C
Decomposition Temperature
No data available in the literature
Solubility
Insoluble in water. Substance floats in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in oils/fats.
Partition Coefficient
4 (Experimental value, Equivalent or similar to OECD 107, 20 °C)
Solubility In Water
0.001 g/100ml (25 °C)
Solubility In Fat
Soluble in oils/fats.
Molecular Weight
86.18 g/mol
Voc Content
100 %
Metal Corrosion
---
Dynamic Viscosity
0.3 mPa.s (25 °C)
Kinematic Viscosity
No data available in the literature
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Reacts with (strong) oxidizers: (increased) risk of fire/explosion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not discharge into drains or the environment. Dispose of at authorized waste collection point. Remove waste in accordance with local and/or national regulations.

Disposal

Do not discharge into drains or the environment. Dispose of at authorized waste collection point. Remove waste in accordance with local and/or national regulations.

Waste Codes

15 01 10* packaging containing residues of or contaminated by dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1208
Shipping Name
hexanes
Transport Class
3
Packing Group
II
ADR

Subject to the provisions

IMDG

Subject to the provisions

IATA

Subject to the provisions

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

No additional information available

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Hexane-(n) a.r. known by?

Hexane-(n) a.r. is also known as: dipropyl / gettysolve-B / hex (=normal-hexane) / hexane- / hexane, anhydrous / hexane,pure grade / hexyl hydride / high purity normal hexane / n-caproylhydride / n-hexane / n-hexyl hydride / normal-caproyl hydride / normal-hexane / normal-hexyl hydride / skellysolve B / solvent hexane

What is the hazard signal word for Hexane-(n) a.r.?

The signal word is danger.

What is the physical form of Hexane-(n) a.r.?

Hexane-(n) a.r. is a liquid appearing as liquid. with colourless. color. It has petroleum-like odour. mild odour. odor.

What is the solubility of Hexane-(n) a.r.?

Insoluble in water. Substance floats in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in oils/fats.

What is Hexane-(n) a.r. used for?

Laboratory chemical

What are the hazard statements for Hexane-(n) a.r.?

This substance has 7 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H361f: Suspected of damaging fertility.
  • H373: May cause damage to organs (nervous system) through prolonged or repeated exposure (if inhaled).
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Hexane-(n) a.r.?

The melting point is -95 °C and the boiling point is 69 °C.

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