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Safety Data Sheet EN

Petroleum, Crude oil

CAS 8002-05-9
EC 232-298-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Petroleum, Crude oil
Chemical Name
Petroleum, Crude oil

Regulatory Identifiers

CAS Number
8002-05-9 Check regulations →
EC Number
232-298-5 Check regulations →

Identified Uses

Industrial use, Professional use, Consumer use

Manufacturers & Suppliers

M

Mercuria Energy Trading B.V. supplying for and on behalf of Mercuria Energy Trading S.A

national supplier

Herculesplein 108, 3584AA Utrecht, Netherlands

+41 22 594 7000

Emergency Contacts

SGS 24/7 Emergency Hotline

+32 3 575 11 30

National Poisons Information Centre, Beaumont Hospital

+353 18 37 99 64

National Poisons Information Centre, Beaumont Hospital

+353 1 809 21 66

National Poisons Information Service (Newcastle Centre), Regional Drugs and Therapeutics Centre, Wolfson Unit

0844 892 0111

Monday to Friday, 08.00 to 18.00 hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1 H224
Eye Irrit. Cat. 2 H319
Carc. Cat. 1B H350
STOT SE Cat. 3 H336
STOT RE Cat. 2 H373
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H224 Extremely flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/.
P331 Do NOT induce vomiting.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Petroleum, Crude oil EC: 232-298-5 8002-05-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing.

Symptoms: May cause drowsiness or dizziness.

Skin contact

Take off contaminated clothing. Gently wash with plenty of soap and water.

Symptoms: No adverse effects are expected.

Eye contact

Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: Causes serious eye irritation.

Ingestion

Rinse mouth thoroughly with water. Do NOT induce vomiting. Get immediate medical advice/attention.

Symptoms: May be fatal if swallowed and enters airways. The following symptoms may occur: Vomiting.

Immediate Medical Attention

Get immediate medical advice/attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, alcohol resistant foam, Dry extinguishing powder, Carbon dioxide

Unsuitable media

Strong water jet

Specific hazards

Extremely flammable liquid and vapour. Heating causes rise in pressure with risk of bursting. Vapours can form explosive mixtures with air. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours can travel considerable distances to a source of ignition where they can ignite, flash back, or explode.

Instructions

Use water spray jet to protect personnel and to cool endangered containers. Evacuate area.

Firefighter Protection

Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate area. Stay upwind/keep distance from source. Provide adequate ventilation. Do not breathe vapour/spray. Avoid contact with skin, eyes and clothes.

Small spill

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents)., Collect in closed and suitable containers for disposal.

Large spill

Large spills should be collected mechanically (remove by pumping) for disposal., Collect in closed and suitable containers for disposal.

Environmental

Do not allow to enter into ground-water, surface water or drains.

Cleanup methods

Use foam on spills to minimise vapours.

Materials: liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provide adequate ventilation. Use personal protective equipment as required. Do not breathe vapour/spray. Avoid contact with skin, eyes and clothes. Take any precaution to avoid mixing with incompatible materials. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Storage

Keep in a dry, cool and well-ventilated place. Do not store near or with any of the incompatible materials listed in section 10. Bund storage facilities to prevent soil and water pollution in the event of spillage. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Hygiene

Keep good industrial hygiene. Wash hands before breaks and immediately after using the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. Keep work clothes separately. Take off contaminated clothing. Wash contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure that the equipment is adequately grounded.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation. Organisational measures to prevent/limit releases, dispersion and exposure. Safe handling: see section 7. Use only outdoors or in a well-ventilated area. Store locked up. Take precautionary measures against static discharges. Ensure that the equipment is adequately grounded. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc.

Hands

Wear chemically resistant gloves (tested to EN374), The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances.

Eyes

Use suitable eye protection. (EN166): Goggles

Respiratory

In case of insufficient ventilation, wear suitable respiratory equipment. Half-face mask (EN 140) Full face mask (EN 136) Filter type: A / P (EN 143) The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. (EN 137)

Skin/Body

Wear suitable protective clothing.

Environmental

Do not allow contact with soil, surface or ground water. Comply with applicable Community environmental protection legislation.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Upper Explosive Limit
No data available
Physical State
liquid
Boiling Point
-1 - 565 °C (at 1013 hPa (with decomposition)
Odor
petroleum hydrocarbon odour, rotten-egg like
Molecular Weight
---
Vapor Pressure
408 hPa (at 37.7 °C)
Melting Point
-30 - 30 °C
Form
---
Ph
No data available
Colour Intensity
---
Flammability
Not applicable, liquid
Metal Corrosion
---
Decomposition Temperature
No data available
Flash Point
-7 - 32 °C (sweet and sour)
Partition Coefficient
No data available
Softening Point
---
Vapor Density
No data available
Crystallisation Point
---
Physical State Data
liquid
Cloud Point
---
Evaporation Rate
No data available
Density
0,8 - 1 g/cm³ (at 15 °C)
Freezing Point
No data available
Relative Density
No data available
Colour
black
Auto Ignition Temperature
No data available
Solidification Point
---
Voc Content
---
Explosive Limits
---
Relative Evaporation Rate
---
Properties Status
---
Kinematic Viscosity
---
Bulk Density
---
Solubility In Water
No data available
State Under Standard Conditions
---
Appearance
liquid
Odor Threshold
No data available
Solubility
No data available
Lower Explosive Limit
No data available
Dynamic Viscosity
---
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable under storage at normal ambient temperatures.

Reactivity

Extremely flammable liquid and vapour. Reference to other sections: 10.4 & 10.5

Hazardous reactions

Vapours can form explosive mixtures with air.

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Safe handling: see section 7

Incompatible

Oxidising substances, Safe handling: see section 7

Decomposition

Reference to other sections: 5.2

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow contact with soil, surface or ground water. Dispose of empty containers and wastes safely. Refer to manufacturer/supplier for information on recovery/recycling. Recycling is preferred to disposal or incineration. If recycling is not possible, eliminate in accordance with local valid waste disposal regulations.

Disposal

Do not allow contact with soil, surface or ground water. Dispose of empty containers and wastes safely. Refer to manufacturer/supplier for information on recovery/recycling. Recycling is preferred to disposal or incineration. If recycling is not possible, eliminate in accordance with local valid waste disposal regulations.

Waste Codes

Waste codes should be assigned by the user based on the application for which the product was used. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3295
Shipping Name
HYDROCARBONS, LIQUID, N.O.S. (Petroleum, Crude oil)
Transport Class
3
Packing Group
1
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

For this substance a chemical safety assessment has not been carried out. This substance is exempted according to REACH Article 2(7) and Annex V.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Petroleum, Crude oil?

The signal word is danger.

What is the physical form of Petroleum, Crude oil?

Petroleum, Crude oil is a liquid appearing as liquid with black color. It has petroleum hydrocarbon odour, rotten-egg like odor.

What is the solubility of Petroleum, Crude oil?

No data available

What is Petroleum, Crude oil used for?

Industrial use, Professional use, Consumer use

What are the hazard statements for Petroleum, Crude oil?

This substance has 7 hazard statements:

  • H224: Extremely flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.
  • H350: May cause cancer.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Petroleum, Crude oil?

The melting point is -30 - 30 °C and the boiling point is -1 - 565 °C (at 1013 hPa (with decomposition).