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Safety Data Sheet EN

Heavy Crude Oil, Non-toxic

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Heavy Crude Oil, Non-toxic
Product Code
UN1267 PG I
Synonyms
CHV; Nipisi Heavy CRD; Nipisi Heavy Crude; Wabasca Heavy CRD; Wabasca Heavy Crude; WH; Seal Heavy Crude; Seal Heavy CRD; Rainbow Heavy Crude; Rainbow Heavy CRD; SH.

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Refinery feedstock.

Uses advised against

Not available.

Manufacturers & Suppliers

P

Pembina Pipeline Corporation

manufacturer

4000, 585 - 8th Avenue SW Calgary, Alberta T2P 1G1

Emergency Contacts

Emergency Contact

1-800-360-4706

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1
Skin Irrit. Cat. 2
Muta. Cat. 1B
Carc. Cat. 1A
Repr. Cat. 2
STOT SE Cat. 3
STOT RE Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H224 Extremely flammable liquid and vapor.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H350i May cause cancer.
May cause genetic defects.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical, ventilating, and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe mist, vapours, or spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves, protective clothing and eye protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison center or doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
In case of fire: Use dry chemical, CO2, water spray or regular foam to extinguish.
Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
Store locked up.
Dispose of contents/container in accordance with applicable regional, national and local laws and regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Petroleum 8002-05-9 100% Yes
Nonane 111-84-2 0.1 - 7% Yes
Octane 111-65-9 0.1 - 7% Yes
Heptane 142-82-5 0.1 - 7% Yes
Hexane 110-54-3 1 - 5% Yes
Pentane 109-66-0 0.5 - 5% Yes
Benzene, dimethyl- 1330-20-7 0.1 - 5% Yes
Benzene 71-43-2 1% Yes
Benzene, methyl- 108-88-3 0.1 - 5% Yes
Benzene, ethyl- 100-41-4 1% Yes
Polycyclic Aromatic Hydrocarbons 130498-29-2 --- Yes
Hydrogen sulfide (H2S) 7783-06-4 0.0001% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. If breathing or the heart stops, trained personnel should immediately begin artificial respiration (AR) or cardiopulmonary resuscitation (CPR) respectively. Get medical attention immediately.

Symptoms: May cause drowsiness or dizziness. May cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Excessive inhalation may cause headache, dizziness, confusion, loss of appetite and/or loss of consciousness. This product may contain small amounts of Hydrogen sulphide which may accumulate in confined spaces. Inhalation of Hydrogen sulphide may cause loss of sense of smell, major irritation of the respiratory tract, headache, nausea, vomiting, dizziness, and fluid buildup in the lungs (pulmonary edema), which can be fatal. At 300 ppm unconsciousness may occur after 20 minutes. From 300 to 500 ppm, death can occur within minutes of continuous exposure. Above 500 ppm Hydrogen sulphide may cause instantaneous loss of consciousness and immediate death.

Skin contact

If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Symptoms: Causes skin irritation. Signs/symptoms may include localized redness, swelling, and itching.

Eye contact

If in eyes: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center or doctor if you feel unwell.

Symptoms: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion

If swallowed: Call a poison center or doctor if you feel unwell. If vomiting occurs naturally, have victim lean forward to reduce the risk of aspiration. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If breathing or the heart stops, trained personnel should immediately begin artificial respiration (AR) or cardiopulmonary resuscitation (CPR) respectively. Get medical attention immediately.

Symptoms: May cause gastrointestinal irritation. Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Immediate Medical Attention

Call a poison center or doctor if you feel unwell. Get medical attention immediately if breathing or the heart stops. If skin irritation occurs, get medical advice/attention. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible).

Medical Treatment

For inhalation of Hydrogen Sulphide, consider oxygen.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry chemical, CO2, water spray or regular foam. For large fires, use water spray, fog or regular foam. Move containers from fire area if you can do it without risk.

Unsuitable media

Do not use straight streams. Use of water spray when fighting fire may be inefficient due to very low flash point.

Specific hazards

Extremely flammable liquid and vapor. Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. When heated, this material may evolve toxic and flammable Hydrogen sulphide.

Instructions

If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Firefighter Protection

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. Hydrogen sulphide is heavier than air and may collect in low lying areas and confined spaces. Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded.

Environmental

Prevent entry into waterways, sewers, basements or confined areas.

Cleanup methods

Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

Materials: dry earth, sand or other non-combustible material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not swallow. Do not breathe mist, vapours, or spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames, and hot surfaces. – No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. See Section 8 for information on Personal Protective Equipment.

Storage

Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Store away from incompatible materials. See Section 10 for information on Incompatible Materials. Keep out of the reach of children. Head spaces in storage containers may contain toxic hydrogen sulphide gas. Structural materials and lighting and ventilation systems should be corrosion resistant.

Hygiene

Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Fire prevention

Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapour, gas, etc.) below recommended exposure limits. Use explosion-proof electrical, ventilating, and lighting equipment.

Hands

Wear protective gloves. Consult manufacturer specifications for further information.

Eyes

Wear safety glasses. Use equipment for eye protection that meets the standards referenced by CSA Standard CAN/CSA-Z94.3-92 and OSHA regulations in 29 CFR 1910.133 for Personal Protective Equipment.

Respiratory

If engineering controls and ventilation are not sufficient to control exposure to below the allowable limits then an appropriate NIOSH/MSHA approved air-purifying respirator that meets the requirements of CSA Standard CAN/CSA-Z94.4-11, with organic vapor cartridge, or self-contained breathing apparatus must be used. Supplied air breathing apparatus must be used when oxygen concentrations are low or if airborne concentrations exceed the limits of the air-purifying respirators.

Skin/Body

Wear protective clothing. Flame resistant clothing that meets the NFPA 2112 and CAN/CGSB 155.20 standards is recommended in areas where material is stored or handled.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Brown liquid.
Colour
Brown.
Colour Intensity
---
Form
---
Odor
Petroleum.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
< 35 °C (95 °F)
Flash Point
< -20.5 °C (-4.9 °F)
Freezing Point
Not available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
< 103 kPa at 37.8 °C (100 °F)
Vapor Density
Not available.
Relative Density
0.9 to 1 (Water = 1) at 15 °C (59 °F)
Bulk Density
---
Density
900 to 1000 kg/m³ at 15 °C (59 °F)
Flammability
Not applicable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Insoluble in water.
Partition Coefficient
Not available.
Solubility In Water
Insoluble in water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
Not available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
40 to 75 cSt at 40 °C (104 °F)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal storage conditions.

Reactivity

Contact with incompatible materials. Sources of ignition. Exposure to heat.

Hazardous reactions

None known.

Avoid

Contact with incompatible materials. Sources of ignition. Exposure to heat.

Incompatible

Strong oxidizers.

Decomposition

Not available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1267
Shipping Name
PETROLEUM CRUDE OIL
Transport Class
3
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Heavy Crude Oil, Non-toxic known by?

Heavy Crude Oil, Non-toxic is also known as: CHV; Nipisi Heavy CRD; Nipisi Heavy Crude; Wabasca Heavy CRD; Wabasca Heavy Crude; WH; Seal Heavy Crude; Seal Heavy CRD; Rainbow Heavy Crude; Rainbow Heavy CRD; SH.

What is the hazard signal word for Heavy Crude Oil, Non-toxic?

The signal word is danger.

What is the physical form of Heavy Crude Oil, Non-toxic?

Heavy Crude Oil, Non-toxic is a liquid. appearing as brown liquid. with brown. color. It has petroleum. odor.

What is the solubility of Heavy Crude Oil, Non-toxic?

Insoluble in water.

What is Heavy Crude Oil, Non-toxic used for?

Refinery feedstock.

What are the hazard statements for Heavy Crude Oil, Non-toxic?

This substance has 7 hazard statements:

  • H224: Extremely flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H350i: May cause cancer.
  • May cause genetic defects.
  • Suspected of damaging fertility or the unborn child.
  • May cause damage to organs through prolonged or repeated exposure.

What is the melting point of Heavy Crude Oil, Non-toxic?

The melting point is Not available. and the boiling point is < 35 °C (95 °F).

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