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Safety Data Sheet EN

Toluene

CAS 108-88-3
EC 203-625-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Toluene
Product Form
Substance
Product Code
LC26170
Chemical Name
Toluene a.r.
Synonyms
benzyl hydride / methylbenzene / phenylmethane / tolunol / toluol oil / toluole

Regulatory Identifiers

CAS Number
108-88-3 Check regulations →
EC Number
203-625-9 Check regulations →
REACH No.
01-2119471310-51-0000

Identified Uses

Solvent

Manufacturers & Suppliers

LabChem Inc logo

LabChem Inc

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Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA

412-826-5230

www.labchem.com

Emergency Contacts

CHEMTREC

1-800-424-9300

CHEMTREC

011-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Skin Irrit. Cat. 2 H315
Repr. Cat. 2 H361
STOT SE Cat. 3 H336
STOT RE Cat. 2 H373
Asp. Tox. Cat. 1 H304
Aquatic Acute Cat. 3 H402

GHS Pictograms

GHS02 - Flammable

GHS02

GHS08 - Serious health hazard

GHS08

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs (central nervous system, liver, heart) through prolonged or repeated exposure.
H402 Harmful to aquatic life

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames, hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating, lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist, vapours, spray.
P264 Wash exposed skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection, face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER/doctor if you feel unwell.
P314 Get medical advice and attention if you feel unwell.
P331 Do NOT induce vomiting
P332+P313 If skin irritation occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam to extinguish.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to comply with local, state and federal regulations

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substance

Toluene (Main constituent)

Chemical Name CAS Number Concentration Hazardous
Toluene --- --- No

Notes

Full text of hazard classes and H-statements : see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: EXPOSURE TO HIGH CONCENTRATIONS: Headache. Nausea. Feeling of weakness. Dizziness. Central nervous system depression. Narcosis. Mental confusion. Drunkenness. Coordination disorders. Disturbed motor response. Disturbances of consciousness.

Skin contact

Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing agents. Remove clothing before washing. Take victim to a doctor if irritation persists. Take victim to a doctor/medical service if irritation persists.

Symptoms: Tingling/irritation of the skin. Red skin.

Eye contact

Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. Take victim to a doctor/medical service if irritation persists.

Symptoms: Irritation of the eye tissue.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not give milk/oil to drink. Do not induce vomiting. Give activated charcoal. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.

Symptoms: Risk of aspiration pneumonia. Nausea. Abdominal pain. Irritation of the gastric/intestinal mucosa. Symptoms similar to those listed under inhalation.

Immediate Medical Attention

Obtain medical assistance.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation.

Hands

Gloves

Eyes

Safety glasses

Respiratory

Full face mask with filter type A at conc. in air > exposure limit

Skin/Body

Head/neck protection. Protective clothing. Materials for protective clothing: GIVE GOOD RESISTANCE: tetrafluoroethylene. viton. PVA. GIVE LESS RESISTANCE: butyl rubber. natural rubber. neoprene. nitrile rubber. polyethylene. neoprene/natural rubber. nitrile rubber/PVC. GIVE POOR RESISTANCE: chloroprene rubber

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Relative Density
0.87 (20 C)
Molecular Weight
92.14 g/mol
Upper Explosive Limit
7 vol %
Odor Threshold
0.2 - 69 ppm 0.8 - 276 mg/m
Physical State
Liquid
Metal Corrosion
---
Cloud Point
---
Voc Content
100 %
Properties Status
---
Dynamic Viscosity
0.6 mPa.s (20 C)
Solubility
Insoluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in carbondisulfide. Soluble in acetic acid. Soluble in ethylacetate. Soluble in petroleum spirit. Water: 0.057 - 0.059 g/100ml (25 C) Ethanol: complete Ether: complete Acetone: > 10 g/100ml
Decomposition Temperature
No data available
Crystallisation Point
---
Partition Coefficient
2.73 (Experimental value, 20 C)
State Under Standard Conditions
---
Odor
Aromatic odour
Melting Point
-95 C (1013 hPa)
Softening Point
---
Boiling Point
110.6 C (1013 hPa)
Colour Intensity
---
Appearance
Liquid.
Flammability
No data available
Vapor Pressure
30.89 hPa (21.1 C)
Solubility In Fat
---
Bulk Density
---
Ph
No data available
Auto Ignition Temperature
480 C (1013 hPa)
Flash Point
4.4 C (Closed cup, 1013 hPa)
Lower Explosive Limit
1.3 vol %
Colour
Colourless
Vapor Density
---
Evaporation Rate
---
Physical State Data
liquid
Density
870 kg/m
Form
---
Kinematic Viscosity
0.69 mm/s (20 C)
Explosive Limits
---
Freezing Point
No data available
Relative Evaporation Rate
2.24
Solubility In Water
0.057 - 0.059 g/100ml (25 C)
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1294
Shipping Name
Toluene
Transport Class
3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing Group
II
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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Toluene known by?

Toluene is also known as: benzyl hydride / methylbenzene / phenylmethane / tolunol / toluol oil / toluole

What is the hazard signal word for Toluene?

The signal word is danger.

What is the physical form of Toluene?

Toluene is a liquid appearing as liquid. with colourless color. It has aromatic odour odor.

What is the solubility of Toluene?

Insoluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in carbondisulfide. Soluble in acetic acid. Soluble in ethylacetate. Soluble in petroleum spirit. Water: 0.057 - 0.059 g/100ml (25 C) Ethanol: complete Ether: complete Acetone: > 10 g/100ml

What is Toluene used for?

Solvent

What are the hazard statements for Toluene?

This substance has 7 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H361: Suspected of damaging fertility or the unborn child.
  • H373: May cause damage to organs (central nervous system, liver, heart) through prolonged or repeated exposure.
  • H402: Harmful to aquatic life

What is the melting point of Toluene?

The melting point is -95 C (1013 hPa) and the boiling point is 110.6 C (1013 hPa).

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