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Safety Data Sheet EN

WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L

Regulatory Identifiers

CAS Number
N/A
UFI Code
UFI:6NAT-Y0X7-Q00A-AR2N

Identified Uses

Use according to manufacturer's directions.

Uses advised against

No specific uses advised against are identified.

Manufacturers & Suppliers

Wienerberger AG logo

Wienerberger AG

manufacturer

Wienerbergerplatz 1 1100 Vienna Austria

0031612548561

www.wienerberger.com

Emergency Contacts

CHEMWATCH EMERGENCY RESPONSE

+43 800 281336

24/7

CHEMWATCH EMERGENCY RESPONSE

+61 3 9573 3188

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1 H222
Skin Sens. Cat. 1 H317
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
STOT SE Cat. 3 H336
Carc. Cat. 2 H351

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H222 Extremely flammable aerosol. Pressurized container: may burst if heated.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing gas.
P302 + P352 IF ON SKIN: Wash with plenty of water and soap.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
methyl acetate EC: 201-185-2 79-20-9 20 - 40% Yes
4,4'-diphenylmethane diisocyanate (MDI) EC: 406-550-1 101-68-8 1 - 5% Yes
p-toluenesulfonyl isocyanate EC: 223-810-8 4083-64-1 1% Yes
dimethyl ether EC: 204-065-8 115-10-6 30 - 60% Yes

Notes

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respiration should be administered as needed.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Pulmonary symptoms include cough, burning, substernal pain and dyspnoea.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available).

Symptoms: Seek medical attention in event of irritation. Skin inflammation (erythema, pain vesiculation).

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Symptoms: Conjunctival irritation.

Ingestion

Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.

Symptoms: Clinical signs are usually limited to CNS, eyes and GI tract. Severe metabolic acidosis may produce dyspnea and profound systemic effects which may become intractable. Gastrointestinal disturbances occur soon after exposure.

Immediate Medical Attention

Transport to hospital or doctor without delay. Establish a patent airway with suction where necessary. Watch for signs of respiratory insufficiency and assist ventilation as necessary. Administer oxygen by non-rebreather mask at 10 to 15 l/min. Monitor and treat, where necessary, for shock. Anticipate and treat, where necessary, for seizures. All symptomatic patients should have arterial pH measured. Evaluate airway, breathing and circulation. Stabilise obtunded patients by giving naloxone, glucose and thiamine. Markedly symptomatic patients should receive oxygen, ventilatory support and an intravenous line.

Medical Treatment

Establish a patent airway with suction where necessary. Watch for signs of respiratory insufficiency and assist ventilation as necessary. Administer oxygen by non-rebreather mask at 10 to 15 l/min. A low-stimulus environment must be maintained. Monitor and treat, where necessary, for shock. Anticipate and treat, where necessary, for seizures. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool. Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. Positive-pressure ventilation using a bag-valve mask might be of use. Monitor and treat, where necessary, for arrhythmias. Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications. Drug therapy should be considered for pulmonary oedema. Hypotension without signs of hypovolaemia may require vasopressors. Treat seizures with diazepam. Proparacaine hydrochloride should be used to assist eye irrigation. Give activated charcoal. Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Stabilise obtunded patients by giving naloxone, glucose and thiamine. Decontaminate with Ipecac or lavage for patients presenting 2 hours post-ingestion. Haemodialysis is recommended where peak methanol levels exceed 50 mg/dL. Ethanol, maintained at levels between 100 and 150 mg/dL, inhibits formation of toxic metabolites and may be indicated when peak methanol levels exceed 20 mg/dL. An intravenous solution of ethanol in D5W is optimal. Folate, as leucovorin, may increase the oxidative removal of formic acid. 4-methylpyrazole may be an effective adjunct in the treatment. Phenytoin may be preferable to diazepam for controlling seizure. Methanol poisoning can be treated with fomepizole, or if unavailable, ethanol. Additional treatment may include sodium bicarbonate for metabolic acidosis, and hemodialysis or hemodiafiltration to remove methanol and formate from the blood. Folinic acid or folic acid is also administered to enhance the metabolism of formate. Treatment for asthma includes inhaled sympathomimetics (epinephrine [adrenalin], terbutaline) and steroids. Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) may be useful for ingestion. Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be used for corneal abrasions. There is no effective therapy for sensitised workers.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only.

Specific hazards

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. May be violently or explosively reactive. Closed containers may rupture due to pressure buildup under fire conditions. Empty solvent, paint, lacquer and flammable liquid drums present a severe explosion hazard if cut by flame torch or welded. Even when thoroughly cleaned or reconditioned the drum seams may retain sufficient solvent to generate an explosive atmosphere in the drum.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Consider evacuation (or protect in place). Prevent, by any means available, spillage from entering drains or water course.

Firefighter Protection

Wear breathing apparatus plus protective gloves in the event of a fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

For isocyanate spills of less than 40 litres (2 m2): Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, remove ignition sources and, if inside building, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment (suitable respiratory protection, face and eye protection, protective suit, gloves and impermeable boots). Control source of leakage (where applicable). Dike the spill to prevent spreading and to contain additions of decontaminating solution. Avoid contamination with water, alkalies and detergent solutions. Material reacts with water and generates gas, pressurises containers with even drum rupture resulting. DO NOT reseal container if contamination is suspected. Open all containers with care. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.

Small spill

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material.

Large spill

For isocyanate spills of less than 40 litres (2 m2): Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, remove ignition sources and, if inside building, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment (suitable respiratory protection, face and eye protection, protective suit, gloves and impermeable boots). Control source of leakage (where applicable). Dike the spill to prevent spreading and to contain additions of decontaminating solution. Avoid contamination with water, alkalies and detergent solutions. Material reacts with water and generates gas, pressurises containers with even drum rupture resulting. DO NOT reseal container if contamination is suspected. Open all containers with care. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.

Cleanup methods

Clean up all spills immediately. Contain and absorb small quantities. Dike the spill to prevent spreading and to contain additions of decontaminating solution.

Materials: vermiculite or other absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Contains low boiling substance: Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately. Check for bulging containers. Vent periodically Always release caps or seals slowly to ensure slow dissipation of vapours

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly.

Hands

The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. For esters: Do NOT use natural rubber, butyl rubber, EPDM or polystyrene-containing materials. Isocyanate resistant materials include Teflon, Viton, nitrile rubber and some PVA gloves. Protective gloves and overalls should be worn as specified in the appropriate national standard. Contaminated garments should be removed promptly and should not be re-used until they have been decontaminated. NOTE: Natural rubber, neoprene, PVC can be affected by isocyanates

Eyes

Safety glasses with side shields. Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.

Respiratory

Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate. Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.

Skin/Body

Protective gloves and overalls should be worn as specified in the appropriate national standard. Contaminated garments should be removed promptly and should not be re-used until they have been decontaminated. Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity. For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets). Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from a conductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipate static electricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to 500,000 ohms.

Environmental

See section 12

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
1.08
Solidification Point
---
Evaporation Rate
Not Available
Voc Content
746.28 g/L
Physical State Data
gas
Density
---
Molecular Weight
Not Available
Ph
Not Available
Upper Explosive Limit
16%
Crystallisation Point
---
Melting Point
Not Available
Odor Threshold
Not Available
Relative Evaporation Rate
---
Auto Ignition Temperature
Not Available
Boiling Point
57°C
Flash Point
-13°C
Kinematic Viscosity
>20.5 @ 40C
Decomposition Temperature
Not Available
Solubility In Fat
---
Solubility
---
Solubility In Water
Immiscible
Colour Intensity
---
Properties Status
---
State Under Standard Conditions
---
Vapor Pressure
Not Available
Bulk Density
---
Form
---
Cloud Point
---
Freezing Point
Not Available
Lower Explosive Limit
3%
Explosive Limits
---
Metal Corrosion
---
Softening Point
---
Odor
Not Available
Physical State
Dissolved Gas
Vapor Density
Not Available
Dynamic Viscosity
---
Partition Coefficient
Not Available
Flammability
HIGHLY FLAMMABLE.
Appearance
Coloured
Colour
Coloured
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Product is considered stable. Hazardous polymerisation will not occur.

Reactivity

See section 7.2 Unstable in the presence of incompatible materials.

Hazardous reactions

See section 7.2

Avoid

See section 7.2

Incompatible

See section 7.2

Decomposition

See section 5.3

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material).

Disposal

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material).

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3501
Shipping Name
CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. (contains methyl acetate)
Transport Class
2.1
Packing Group
Not Applicable
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

The signal word is danger.

What is the physical form of WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L is a dissolved gas appearing as coloured with coloured color. It has not available odor.

What is WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L used for?

Use according to manufacturer's directions.

What are the hazard statements for WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

This substance has 6 hazard statements:

  • H222: Extremely flammable aerosol. Pressurized container: may burst if heated.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.

What is the melting point of WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

The melting point is Not Available and the boiling point is 57°C.

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