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Safety Data Sheet EN

WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L
Product Form
SPRAY ADHESIVE
Chemical Name
Not Applicable
Synonyms
WIENERBERGER AG

Regulatory Identifiers

CAS Number
N/A
UFI Code
6NAT-Y0X7-Q00A-AR2N

Identified Uses

Use according to manufacturer's directions. Chemical Product Category: PC1 (Adhesives, sealants). Sectors of Use: SU22 (Professional uses), SU3 (Industrial uses). Sector of Use - Sub Category: SU19 (Building and construction work).

Uses advised against

No specific uses advised against are identified.

Manufacturers & Suppliers

Wienerberger AG logo

Wienerberger AG

manufacturer

Wienerbergerplatz 1 1100 Vienna Austria

0031612548561

www.wienerberger.com

Emergency Contacts

CHEMWATCH EMERGENCY RESPONSE

+43 800 281336

24/7

CHEMWATCH EMERGENCY RESPONSE

+61 3 9573 3188

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1 H222
Skin Sens. Cat. 1 H317
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
STOT SE Cat. 3 H336
Carc. Cat. 2 H351

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H222 Extremely flammable aerosol. Pressurized container: may burst if heated.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing gas.
P302 + P352 IF ON SKIN: Wash with plenty of water and soap.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
methyl acetate EC: 201-185-2 79-20-9 20 - 40% Yes
4-4'-diphenylmethane diisocyanate (MDI) EC: 202-966-0 101-68-8 1 - 5% Yes
p-toluenesulfonyl isocyanate EC: 223-810-8 4083-64-1 1% Yes
dimethyl ether EC: 204-065-8 115-10-6 30 - 60% Yes

Notes

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respiration should be administered as needed.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Symptoms: irritation

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Symptoms: Conjunctival irritation, severe burning, redness, tearing.

Ingestion

Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.

Symptoms: Gastrointestinal disturbances, burning in mouth and throat, abdominal pain, nausea, vomiting.

Immediate Medical Attention

Transport to hospital or doctor without delay.

Medical Treatment

Treatment is essentially symptomatic. A physician should be consulted.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol stable foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide, Water spray or fog - Large fires only.

Specific hazards

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Prevent, by any means available, spillage from entering drains or water course.

Firefighter Protection

Wear breathing apparatus plus protective gloves in the event of a fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

See section 8

Small spill

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material.

Large spill

Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, remove ignition sources and, if inside building, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment. Control source of leakage. Dike the spill to prevent spreading. Avoid contamination with water, alkalies and detergent solutions. Alert Fire Brigade. Prevent spillage from entering drains or water course.

Environmental

See section 12

Cleanup methods

Clean up all spills immediately. Contain and absorb small quantities with vermiculite or other absorbent material.

Materials: vermiculite or other absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Contains low boiling substance: Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately. ▸ Check for bulging containers. ▸ Vent periodically ▸ Always release caps or seals slowly to ensure slow dissipation of vapours

Storage

Packing as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks.

Fire prevention

See section 5

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly.

Hands

NOTE: ▸ The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. For esters: ▸ Do NOT use natural rubber, butyl rubber, EPDM or polystyrene-containing materials. ▸ Isocyanate resistant materials include Teflon, Viton, nitrile rubber and some PVA gloves. ▸ Protective gloves and overalls should be worn as specified in the appropriate national standard. ▸ NOTE: Natural rubber, neoprene, PVC can be affected by isocyanates

Eyes

▸ Safety glasses with side shields. ▸ Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] ▸ Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Respiratory

Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). ▸ Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. ▸ The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. ▸ Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used.

Skin/Body

▸ Overalls. ▸ PVC Apron. ▸ PVC protective suit may be required if exposure severe. ▸ Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity. ▸ For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets). ▸ Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from a conductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot and shall dissipate static electricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to 500,000 ohms.

Environmental

See section 12

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Dissolved Gas
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Coloured
Colour
Coloured
Colour Intensity
---
Form
---
Odor
Not Available
Odor Threshold
Not Available
Ph
Not Available
Melting Point
Not Available
Boiling Point
57
Flash Point
-13
Freezing Point
Not Available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Available
Vapor Pressure
Not Available
Vapor Density
Not Available
Relative Density
1.08
Bulk Density
---
Density
---
Flammability
HIGHLY FLAMMABLE.
Upper Explosive Limit
16
Lower Explosive Limit
3
Explosive Limits
---
Auto Ignition Temperature
Not Available
Decomposition Temperature
Not Available
Solubility
Immiscible
Partition Coefficient
Not Available
Solubility In Water
Immiscible
Solubility In Fat
---
Molecular Weight
Not Available
Voc Content
746.28
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
>20.5 @ 40C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Product is considered stable. Unstable in the presence of incompatible materials.

Reactivity

See section 7.2

Hazardous reactions

Hazardous polymerisation will not occur.

Avoid

See section 7.2

Incompatible

See section 7.2

Decomposition

See section 5.3

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | methyl acetate | LOW | LOW |

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | 4,4'-diphenylmethane diisocyanate (MDI) | LOW (Half-life = 1 days) | LOW (Half-life = 0.24 days) |

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | p-toluenesulfonyl isocyanate | HIGH | HIGH |

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | dimethyl ether | LOW | LOW |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | methyl acetate | LOW (LogKOW = 0.18) |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | 4,4'-diphenylmethane diisocyanate (MDI) | LOW (BCF = 15) |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | p-toluenesulfonyl isocyanate | LOW (LogKOW = 2.3424) |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | dimethyl ether | LOW (LogKOW = 0.1) |

12.4. Mobility in soil

| Ingredient | Mobility | | --- | --- | | methyl acetate | MEDIUM (Log KOC = 3.324) | | 4,4'-diphenylmethane diisocyanate (MDI) | LOW (Log KOC = 376200) | | p-toluenesulfonyl isocyanate | LOW (Log KOC = 882.1) | | dimethyl ether | HIGH (Log KOC = 1.292) |

12.5. Results of PBT and vPvB assessment

| | P | B | T | | --- | --- | --- | --- | | Relevant available data | Not Available | Not Available | Not Available | | PBT | ☒ | ☒ | ☒ | | vPvB | ☒ | ☒ | ☒ | | PBT Criteria fulfilled? | | | No | | vPvB | | | No |

The substance does not fulfill the PBT or vPvB criteria.

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

No evidence of endocrine disrupting properties were found in the current literature.

12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

No evidence of ozone depleting properties were found in the current literature.

12.1. Toxicity

| methyl acetate | Endpoint | Test Duration (hr) | Species | Value | Source | | | NOEC(ECx) | 72h | Algae or other aquatic plants | >=120mg/l | 1 | | | EC50 | 72h | Algae or other aquatic plants | >120mg/l | 1 | | | EC50 | 48h | Crustacea | 1026.7mg/l | 1 | | | LC50 | 96h | Fish | 250mg/l | 1 |

12.1. Toxicity

| 4,4'-diphenylmethane diisocyanate (MDI) | Endpoint | Test Duration (hr) | Species | Value | Source | | | LC50 | 96h | Fish | 95.24-134.37mg/l | Not Available | | | EC50 | 48h | Crustacea | >100mg/l | 2 | | | NOEC(ECx) | 504h | Crustacea | >=10mg/l | 2 | | | BCF | 672h | Fish | 61-150 | 7 |

12.2 Persistence and degradability

Not available

12.3 Bioaccumulative potential

Not available

12.4 Mobility in soil

Not available

12.5 Results of PBT and vPvB assessment

Not available

12.6 Endocrine disrupting properties

Not available

12.7 Other adverse effects

Not available

12.1. Toxicity

| p-toluenesulfonyl isocyanate | Endpoint | Test Duration (hr) | Species | Value | Source | | | NOEC(ECx) | 72h | Algae or other aquatic plants | 10mg/l | 2 | | | EC50 | 72h | Algae or other aquatic plants | 25mg/l | 2 | | | EC50 | 48h | Crustacea | >100mg/l | 2 | | | LC50 | 96h | Fish | >45mg/l | 2 |

12.1. Toxicity

| dimethyl ether | Endpoint | Test Duration (hr) | Species | Value | Source | | | LC50 | 96h | Fish | 1783.04mg/l | 2 | | | EC50 | 48h | Crustacea | >4400mg/L | 2 | | | NOEC(ECx) | 48h | Crustacea | >4000mg/l | 1 | | | EC50 | 96h | Algae or other aquatic plants | 154.917mg/l | 2 |

12.2. Persistence and degradability

The substance can be classified as "readily biodegradable" on the basis of an available study according to OECD-guideline 301 D. This closed bottle test indicates 74% biodegradation after 14 days, 75% after 19 days and 70% after 28 days. There is no information on possible intermediates before ultimate degradation of methyl acetate. Probably methanol and acetic acid could be intermediates of the biodegradation. The degradation of the possible intermediates is included in the results of the biodegradation test. Most ethers are very resistant to hydrolysis, and the rate of cleavage of the carbon-oxygen bond by abiotic processes is expected to be insignificant. Direct photolysis will not be an important removal process since aliphatic ethers do not absorb light at wavelengths >290 nm Ingredient | Persistence: Water/Soil | Persistence: Air --- | --- | ---

Methyl acetate is considered readily biodegradable based on OECD 301 D testing, showing 70-75% degradation within 28 days. Abiotic processes like hydrolysis and direct photolysis are not significant removal pathways.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Not Available

Disposal

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material).

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3501
Shipping Name
CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. (contains methyl acetate)
Transport Class
2.1
Packing Group
Not Applicable
IMDG

274 362

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC, - 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Chemical Safety Assessment Not performed

Not Applicable

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L known by?

WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L is also known as: WIENERBERGER AG

What is the hazard signal word for WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

The signal word is danger.

What is the physical form of WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L is a dissolved gas appearing as coloured with coloured color. It has not available odor.

What is the solubility of WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

Immiscible

What is WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L used for?

Use according to manufacturer's directions. Chemical Product Category: PC1 (Adhesives, sealants). Sectors of Use: SU22 (Professional uses), SU3 (Industrial uses). Sector of Use - Sub Category: SU19 (Building and construction work).

What are the hazard statements for WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

This substance has 6 hazard statements:

  • H222: Extremely flammable aerosol. Pressurized container: may burst if heated.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.

What is the melting point of WIENERBERGER PU SPRAY ADHESIVE, CLEAR, 22L?

The melting point is Not Available and the boiling point is 57.