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Safety Data Sheet EN

Furfural

CAS 98-01-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Furfural
Product Code
185914
Chemical Name
Furfural

Regulatory Identifiers

CAS Number
98-01-1 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4 H227
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 2 H330
Acute Tox. Cat. 4 H312
Eye Irrit. Cat. 2A H319
Carc. Cat. 2 H351
Aquatic Acute Cat. 3 H402

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H351 Suspected of causing cancer.
H402 Harmful to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 Wear respiratory protection.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-Furaldehyde EC: 202-627-7 98-01-1 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards

No data available

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Avoid breathing vapours, mist or gas.

Environmental

Discharge into the environment must be avoided.

Cleanup methods

collect with an electrically protected vacuum cleaner or by wet-brushing

Materials: suitable, closed containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

Storage

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Fire prevention

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing.

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0.3 mm, Break through time: 480 min, Material tested: Butoject® (KCL 897 / Aldrich Z677647, Size M). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.4 mm, Break through time: 30 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). Standards: EN374.

Eyes

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
clear, viscous, liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
clear, viscous, liquid
Colour
light brown
Colour Intensity
---
Form
clear, viscous, liquid
Odor
No data available
Odor Threshold
No data available
Ph
No data available
Melting Point
-36 °C (-33 °F)
Boiling Point
162 °C (324 °F)
Flash Point
61.7 °C (143.1 °F)
Freezing Point
-36 °C (-33 °F)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
18.0 hPa (13.5 mmHg) at 55 °C (131 °F); 2.3 hPa (1.7 mmHg) at 20 °C (68 °F)
Vapor Density
3.32 - (Air = 1.0)
Relative Density
1.16 g/cm³ at 25 °C (77 °F)
Bulk Density
---
Density
---
Flammability
No data available
Upper Explosive Limit
19.3 % (V)
Lower Explosive Limit
2.1 % (V)
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
soluble
Partition Coefficient
log Pow: 0.41
Solubility In Water
soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No data available

Hazardous reactions

No data available

Avoid

Heat, flames and sparks.

Incompatible

Oxidizing agents, Strong acids

Decomposition

Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 32 mg/l - 96 h Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 29 mg/l - 24 h other aquatic invertebrates Toxicity to algae EC50 - other microorganisms - 570 mg/l - 24 h

Persistence and degradability

Biodegradability aerobic Biochemical oxygen demand - Exposure time 28 d Result: 93.5% - Readily biodegradable. (OECD Test Guideline 301C)

Readily biodegradable.

Bioaccumulative potential

No data available

No data available

Mobility in soil

No data available

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life. No data available

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber.

Disposal

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1199
Shipping Name
Furaldehydes
Transport Class
6.1 (3)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

SARA 302: No chemicals in this material are subject to reporting requirements. SARA 313: Material does not contain any chemical components exceeding threshold reporting levels. SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard, Chronic Health Hazard. California Prop. 65: Product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Furfural?

The signal word is danger.

What is the physical form of Furfural?

Furfural is a clear, viscous, liquid appearing as clear, viscous, liquid with light brown color. It has no data available odor.

What is the solubility of Furfural?

soluble

What is Furfural used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Furfural?

This substance has 7 hazard statements:

  • H227: Combustible liquid.
  • H301: Toxic if swallowed.
  • H312: Harmful in contact with skin.
  • H319: Causes serious eye irritation.
  • H330: Fatal if inhaled.
  • H351: Suspected of causing cancer.
  • H402: Harmful to aquatic life.

What is the melting point of Furfural?

The melting point is -36 °C (-33 °F) and the boiling point is 162 °C (324 °F).