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Safety Data Sheet EN

Tetramethylthiuram disulfide

CAS 137-26-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tetramethylthiuram disulfide
Product Code
AC138480000; AC138480010; AC138480050; AC138485000
Synonyms
Thiram; TMTD; Bis(dimethylthiocarbamyl) disulfide

Regulatory Identifiers

CAS Number
137-26-8 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

distributor

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

distributor

One Reagent Lane Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
Skin Sens. Cat. 1
STOT RE Cat. 2
Combustible dust

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
May form combustible dust concentrations in air
May cause damage to organs through prolonged or repeated exposure

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
Contaminated work clothing should not be allowed out of the workplace
Do not breathe dust/fume/gas/mist/vapors/spray
Get medical attention/advice if you feel unwell
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Store in a well-ventilated place. Keep container tightly closed
Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Thiram 137-26-8 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: trouble breathing

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Symptoms: allergic skin reaction, rash, itching, swelling

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Immediate Medical Attention

Get medical attention if symptoms occur or persist. If not breathing, give artificial respiration.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Carbon dioxide (CO₂). Dry chemical. Chemical foam.

Specific hazards

Fine dust dispersed in air may ignite. Do not allow run-off from fire-fighting to enter drains or water courses.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.

Cleanup methods

Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves and clothing to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Softening Point
---
Form
Powder
Cloud Point
---
Boiling Point
129 °C / 264.2 °F @ 20 mmHg
Molecular Weight
240.41
Crystallisation Point
---
Metal Corrosion
---
Dynamic Viscosity
---
Vapor Density
Not applicable
Relative Density
No information available
Colour
White
Bulk Density
---
Voc Content
---
Solubility In Water
---
Physical State
Powder Solid
Freezing Point
---
Properties Status
---
Odor Threshold
No information available
Melting Point
> 145 °C / 293 °F
Density
---
Explosive Limits
---
Partition Coefficient
No data available
Odor
Strong
Solubility In Fat
---
Decomposition Temperature
No information available
Solubility
No information available
Kinematic Viscosity
---
Upper Explosive Limit
No data available
Appearance
White
Evaporation Rate
Not applicable
Physical State Data
solid
State Under Standard Conditions
---
Flammability
No information available
Ph
No information available
Colour Intensity
---
Solidification Point
---
Vapor Pressure
negligible
Lower Explosive Limit
No data available
Flash Point
No information available
Auto Ignition Temperature
No information available
Relative Evaporation Rate
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. No information available.

Avoid

Incompatible products.

Incompatible

Acids, Reducing Agent, Oxidizing agent

Decomposition

Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO₂), Sulfur oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Tetramethylthiuram disulfide known by?

Tetramethylthiuram disulfide is also known as: Thiram; TMTD; Bis(dimethylthiocarbamyl) disulfide

What is the hazard signal word for Tetramethylthiuram disulfide?

The signal word is warning.

What is the physical form of Tetramethylthiuram disulfide?

Tetramethylthiuram disulfide is a powder solid appearing as white with white color. It has strong odor.

What is the solubility of Tetramethylthiuram disulfide?

No information available

What is Tetramethylthiuram disulfide used for?

Laboratory chemicals.

What are the hazard statements for Tetramethylthiuram disulfide?

This substance has 6 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H315: Causes skin irritation
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • May form combustible dust concentrations in air
  • May cause damage to organs through prolonged or repeated exposure

What is the melting point of Tetramethylthiuram disulfide?

The melting point is > 145 °C / 293 °F and the boiling point is 129 °C / 264.2 °F @ 20 mmHg.

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