OLOA 61007

No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. If exposure to hydrogen sulfide (H2S) gas is possible during an emergency, wear an approved, positive pressure air-supplying respirator. Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention.

Symptoms: May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. Hydrogen sulfide has a strong rotten-egg odor. However, with continued exposure and at high levels, H2S may deaden a person's sense of smell. If the rotten egg odor is no longer noticeable, it may not necessarily mean that exposure has stopped. At low levels, hydrogen sulfide causes irritation of the eyes, nose, and throat. Moderate levels can cause headache, dizziness, nausea, and vomiting, as well as coughing and difficulty breathing. Higher levels can cause shock, convulsions, coma, and death. After a serious exposure, symptoms usually begin immediately.

Wash skin with water immediately and remove contaminated clothing and shoes. Get medical attention if any symptoms develop. To remove the material from skin, apply a waterless hand cleaner, mineral oil, or petroleum jelly. Then wash with soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse.

Symptoms: Contact with the skin may cause an allergic skin reaction. Symptoms may include pain, itching, discoloration, swelling, and blistering.

No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water.

Symptoms: Not expected to cause prolonged or significant eye irritation. At low levels, hydrogen sulfide causes irritation of the eyes.

No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice.

Symptoms: Not expected to be harmful if swallowed.

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Combustion may form oxides of: Zinc, Nitrogen, Magnesium, Molybdenum, Sulfur, Calcium, Boron, Phosphorus.

This material will burn although it is not easily ignited. See Section 7 for proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus.

Eliminate all sources of ignition in vicinity of spilled material. Refer to Sections 5 and 8 for more information. Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater.

Contain release to prevent further contamination of soil, surface water or groundwater.

Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil and dispose of in a manner consistent with applicable requirements. Place other contaminated materials in disposable containers and dispose of in a manner consistent with applicable requirements.

Materials: non-combustible absorbent materials

The maximum handling temperature is 85°C. The recommended reheating medium is hot water or regulated low pressure steam. Care must be taken not to exceed the temperatures stated above when reheating this material in order to avoid decomposition that releases hazardous fumes. Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. If adequate engineering controls are used, short term activities such as loading, unloading and in-line blending may occur at temperatures ranging from 80-85°C (176-185°F). During shipment by railcar or tank truck, loading temperatures as high as 80-85°C (176-185°F) may be used and are expected to drop to 66°C (150°F) or lower within 7 days. Storage temperatures for up to 2 weeks should not exceed 66°C (150°F). The recommended long-term (2 weeks or more) storage temperature is ambient to 45°C (113°F) maximum. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not breathe gas. Wash thoroughly after handling. Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks and bulk transport vessels which contain or have contained this material. Persons opening or entering these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection - Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied-air or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or portable devices.

During shipment by railcar or tank truck, loading temperatures as high as 80-85°C (176-185°F) may be used and are expected to drop to 66°C (150°F) or lower within 7 days. Storage temperatures for up to 2 weeks should not exceed 66°C (150°F). The recommended long-term (2 weeks or more) storage temperature is ambient to 45°C (113°F) maximum. The maximum short-term (<2 week(s)) storage temperature is 66°C. The maximum long-term (>2 week(s)) storage temperature is 45°C.

Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not breathe gas. Wash thoroughly after handling.

Use general ventilation, local exhaust ventilation, or a combination of both.

Refer to PPE manufacturers to obtain breakthrough time information to determine how long PPE can be used before it needs to be replaced. Unless specific glove manufacturer data indicates otherwise, the below table is based upon available industry data to assist in the glove selection process and is intended to be used as reference only. | Chemical Glove Material | Thickness (mm) | Typical Breakthrough Time (minutes) | | --- | --- | --- | | Butyl | 0.35 | 5 | | Neoprene | 1.4 | 30 | | Nitrile | 0.8 | 30 | | Nitrile | 0.23 | 7 | | Polyvinyl Chloride (PVC) | 1.1 | 15 | Viton Butyl 0.3 120

Wear protective equipment to prevent eye contact. Selection of protective equipment may include safety glasses, chemical goggles, face shields, or a combination depending on the work operations conducted.

No respiratory protection is normally required. If material is heated and emits hydrogen sulfide, determine if airborne concentrations are below the occupational exposure limit for hydrogen sulfide. If not, wear an approved positive pressure air-supplying respirator. For more information on hydrogen sulfide, see Chevron SDS No. 301. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge.

Wear chemical personal protective equipment (PPE) to prevent skin contact. Selection of chemical protective clothing should be performed by an Occupational Hygienist or Safety Professional and be based upon applicable standards (ASTM F739 or EN 374). Using chemical PPE depends upon operations conducted and may include chemical gloves, boots, chemical apron, chemical suit, and complete facial protection.

See relevant Community environmental protection legislation or the Annex, as applicable.

This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.

Hazardous polymerization will not occur.

Do not exceed handling and storage temperatures listed in SDS Section 7 (Handling and Storage).

Not applicable

Alkyl Mercaptans (See Section 7), Hydrogen Sulfide (See Section 7)