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Safety Data Sheet EN

WSFR-TCPP

CAS 13674-84-5
EC 911-815-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
WSFR-TCPP
Product Form
Substance
Chemical Name
TCPP
Synonyms
TCPP Tris(2-chloro-1-methylethyl) phosphate multiconstituent substance, Tris(2-chloro-1-methylethyl) phosphate, Phosphoric acid tris (2-chloro-1-methylethyl) ester, Tris (2-chloro-isopropyl) phosphate, Tris (2-chloro-2-propyl) phosphate, 2-propanol-1-chloro-phosphate(3:1), TMCP

Regulatory Identifiers

CAS Number
13674-84-5 Check regulations →
EC Number
911-815-4 Check regulations →
REACH No.
01-2119486772-26-XXXX

Identified Uses

Fire-retarding agent, Production of polyurethane foam

Uses advised against

No additional information available

Manufacturers & Suppliers

I

Innovo Chemicals B.V.

Startbaan 8, 1185 XR, Amstelveen, Netherlands

+31 20 7585 732

Emergency Contacts

Belgium

+32 70 245 245

24hrs

France

+33 1 45 42 59 59

24hrs

Germany

+49 214 3099300

24hrs

Italy

+39 800 883 300

24hrs

Norway

+47 22 59 13 00

24hrs

Poland

+48 42 63 14 724

24hrs

Portugal

+351 808 250 143

24hrs

Romania

+402 212 106 282

24hrs

Spain

+34 156 20420

24hrs

Sweden

+46 8 33 12 31

24hrs

Sweden

112

24hrs

Switzerland

+41 44 251 5151

24hrs

The Netherlands

+31 30 274 8888

24hrs

Turkey

+90 312 433 7001

24hrs

Turkey

+90 800 314 7900

24hrs

United Kingdom of Great Britain and Northern Ireland

+44 844 892 0111

24hrs

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed

Precautionary Statements

P264 Wash thoroughly after handling.
P280 wear protective gloves/protective clothing/eye protection/face protection.
P330 Rinse mouth.
P501 Dispose of contents/container in accordance with local/regional/national/international regulation.
If swallowed, call a Poison Centre or Doctor /Physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Multi-constituent substance of Tris(2-chloro-1-methylethyl)phosphate, Bis(1-chloro-2-propyl)-2-chloropropyl phosphate, Bis(2-chloropropyl)-1-chloro-2-propyl phosphate and Tris(2-chloropropyl)phosphate EC: 911-815-4 --- 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs provide artificial respiration or oxygen by trained personnel. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as collar, tie, belt or waistband.

Symptoms: No data available

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Obtain medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Slight irritation

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Symptoms: Slight irritation

Ingestion

Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit doesn't enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in the recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as collar, tie, belt or waistband.

Symptoms: No data available

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital.

Medical Treatment

NOTES TO PHYSICIAN: All persons handling organic phosphorus ester materials regularly should undergo regular medical examination with special stress on the central nervous systems.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray (fog), foam, dry chemical or CO2

Specific hazards

Combustion products include: carbon dioxide (CO2), phosphorus oxides (POx), other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. In a fire or if heated, a pressure increase will occur and the container may burst. Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). May emit acrid smoke. Mists containing combustible materials may be explosive.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Wear full body protective clothing with breathing apparatus. Fire fighters should wear appropriate protective equipment and a self-contained breathing apparatus (SCBA) with a full face piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through split material. Avoid breathing vapour or mist. Provide adequate ventilation.

Small spill

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapors and contact with skin and eyes. Control personal contact by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labeled container for waste disposal.

Large spill

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labeled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labeled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.

Environmental

Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Collect recoverable product into labeled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labeled drums for disposal. Wash area and prevent runoff into drains.

Materials: sand, earth, vermiculite, inert material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storing and handling recommendations. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. DO NOT allow clothing wet with material to stay in contact with skin.

Storage

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10), food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in un-labeled containers.

Hygiene

When handling, DO NOT eat, drink or smoke. Always wash hands with soap and water after handling. Work clothes should be laundered separately.

Fire prevention

Avoid smoking, naked lights or ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations < 1 hours (breakthrough time): nitrile rubber, PVC.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Recommended: Tightly fitting safety goggles.

Respiratory

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: organic vapour filter (Type A) if product forms vapour/aerosol.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear protective clothing.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Crystallisation Point
---
Evaporation Rate
---
Explosive Limits
---
Flammability
Not applicable
State Under Standard Conditions
---
Vapor Density
---
Softening Point
---
Bulk Density
Not applicable
Density
1.290 kg/m³
Cloud Point
---
Voc Content
---
Flash Point
185°C
Lower Explosive Limit
Not applicable
Decomposition Temperature
>220°C
Appearance
Liquid
Kinematic Viscosity
---
Relative Evaporation Rate
---
Solubility In Fat
---
Solidification Point
---
Upper Explosive Limit
Not applicable
Solubility
---
Properties Status
---
Freezing Point
---
Colour
Clear
Dynamic Viscosity
68.5 cP (20°C)
Colour Intensity
---
Molecular Weight
---
Metal Corrosion
---
Odor
Mild
Melting Point
-42°C
Form
---
Odor Threshold
---
Physical State Data
liquid
Physical State
Liquid
Partition Coefficient
Log Kow= 2.68
Auto Ignition Temperature
>500°C
Ph
Not determined
Vapor Pressure
<1hPa
Boiling Point
341°C
Relative Density
---
Solubility In Water
Poor
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of use.

Reactivity

On burning release toxic and corrosive gases/vapours (phosphorus oxides, carbon monoxide-carbon dioxide). Reacts violently with (strong) oxidizers and with (some) acids/bases

Hazardous reactions

No additional information available

Avoid

Elevated temperatures (> 200 °C)

Incompatible

No material to be especially mentioned

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is WSFR-TCPP known by?

WSFR-TCPP is also known as: TCPP Tris(2-chloro-1-methylethyl) phosphate multiconstituent substance, Tris(2-chloro-1-methylethyl) phosphate, Phosphoric acid tris (2-chloro-1-methylethyl) ester, Tris (2-chloro-isopropyl) phosphate, Tris (2-chloro-2-propyl) phosphate, 2-propanol-1-chloro-phosphate(3:1), TMCP

What is the hazard signal word for WSFR-TCPP?

The signal word is warning.

What is the physical form of WSFR-TCPP?

WSFR-TCPP is a liquid appearing as liquid with clear color. It has mild odor.

What is WSFR-TCPP used for?

Fire-retarding agent, Production of polyurethane foam

What are the hazard statements for WSFR-TCPP?

This substance has 1 hazard statement:

  • H302: Harmful if swallowed

What is the melting point of WSFR-TCPP?

The melting point is -42°C and the boiling point is 341°C.