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Safety Data Sheet EN

TCPP

CAS 1244733-77-4
EC 807-935-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TCPP
Product Code
13954
Chemical Name
Reaction products of phosphoryl trichloride and 2-methyloxirane
Synonyms
Tris(2-chlorisopropyl)phosphat

Regulatory Identifiers

CAS Number
1244733-77-4 Check regulations →
EC Number
807-935-0 Check regulations →
REACH No.
01-2119486772-26-XXXX

Identified Uses

Flame retardant.

Manufacturers & Suppliers

P

ProChema GmbH

manufacturer

Twin Towers A02, Wienerbergstraße 11, A-1100 Vienna

+43 (0)1 60560

Emergency Contacts

ChemTel

1-800-255-3924

24 h

ChemTel

+1-813-248-0585

24 h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Carc. Cat. 2 H351
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type uvcb

Reaction products of phosphoryl trichloride and 2-methyloxirane

Chemical Name CAS Number Concentration Hazardous
Reaction products of phosphoryl trichloride and 2-methyloxirane EC: 807-935-0 1244733-77-4 99.5 - 99.8% No

UVCB substance (substance with unknown or variable composition)

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation.

Skin contact

Immediately rinse with water. Take off contaminated clothing and wash it before reuse. Seek medical treatment.

Eye contact

Rinse opened eye for several minutes under running water. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical treatment.

Ingestion

Rinse out mouth and then drink plenty of water. Do NOT induce vomiting. Call a doctor immediately.

Immediate Medical Attention

Call a doctor immediately (for swallowing), Seek medical treatment (general/skin/eye).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Unsuitable media

Water with full jet

Specific hazards

Formation of toxic gases is possible during heating or in case of fire.

Instructions

Do not inhale explosion gases or combustion gases.

Firefighter Protection

Wear self-contained respiratory protective device. Wear fully protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Avoid contact with skin and eyes. Do not breathe vapour/spray.

Environmental

Do not allow to enter sewers/ surface or ground water.

Cleanup methods

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Materials: sand, diatomite, acid binders, universal binders, sawdust

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure good ventilation/exhaustion at the workplace. Keep receptacles tightly sealed. Avoid contact with skin and eyes. Avoid breathing mist/vapours/spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Observe protective measures and safety instructions.

Storage

Store in a cool location. Ensure adequate ventilation. Store in accordance with local/regional/national/international regulations. Protect from heat and direct sunlight. Keep container tightly sealed. Store in original container. Store locked up.

Hygiene

Avoid contact with skin and eyes.

Fire prevention

Keep ignition sources away - Do not smoke.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No further data; see section 7.

Hands

Protective gloves, EN 374. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eyes

Tightly sealed goggles, EN 166.

Respiratory

Use suitable respiratory protective device in case of insufficient ventilation.

Skin/Body

Protective work clothing.

Environmental

Do not allow to enter sewers/ surface or ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Fluid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Fluid
Colour
Colourless
Colour Intensity
---
Form
Fluid
Odor
Undistinguishable.
Odor Threshold
No information available.
Ph
Not applicable.
Melting Point
-20 °C
Boiling Point
288 °C
Flash Point
245 °C
Freezing Point
-20 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available.
Vapor Pressure
Not determined.
Vapor Density
No information available.
Relative Density
1.29
Bulk Density
---
Density
No information available.
Flammability
Not classified as a flammable liquid.
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
400 °C
Decomposition Temperature
No information available.
Solubility
---
Partition Coefficient
2.68 log POW
Solubility In Water
1.08 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
void
Dynamic Viscosity
68.5 mPas
Kinematic Viscosity
No information available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used and stored according to specifications.

Reactivity

No hazardous reactions known if stored and used as prescribed.

Hazardous reactions

No dangerous reactions known.

Avoid

Keep away from heat.

Incompatible

No further relevant information available.

Decomposition

No decomposition if used and stored according to specifications.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.3 Bioaccumulative potential

log Pow: 2.68 (30 °C) Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected.

Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected.

12.4 Mobility in soil

No further relevant information available.

12.1 Toxicity

Aquatic toxicity: CAS: 1244733-77-4 Reaction products of phosphoryl trichloride and 2-methyloxirane EC50 (48 h) 131 mg/l (daphnia) (Daphnia magna) EC50 (72 h) 82 mg/l (algae) (Pseudokirchneriella subcapitata) LC50 (96 h) 51 mg/l (fish) (Pimephales promelas) NOEC (72 h) 13 mg/l (algae) (Pseudokirchneriella subcapitata) NOEC (21 d) 32 mg/l (daphnia) (Daphnia magna) EC50 (3 h) 784 mg/l (Activated sludge) EC10 (3 h) 191 mg/l (Activated sludge)

12.2 Persistence and degradability

Not easily biodegradable

Not easily biodegradable

12.5 Results of PBT and vPvB assessment

PBT: Based on available data, the classification criteria are not met. vPvB: Based on available data, the classification criteria are not met.

The substance does not meet the criteria for PBT or vPvB classification based on available data.

12.6 Endocrine disrupting properties

For information on endocrine disrupting properties see section 11.

Information on endocrine disrupting properties is referenced in section 11.

12.7 Other adverse effects

Do not allow to enter sewers/ surface or ground water.

The substance is classified as harmful to aquatic life with long lasting effects and is slightly hazardous for water (Water hazard class 1).

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Only dispose of product residues via authorised companies according to local legislation.

Disposal

Must not be disposed together with household garbage.

Waste Codes

16 03 05* organic wastes containing hazardous substances EWC
HP6 Acute Toxicity national code
HP7 Carcinogenic national code
HP14 Ecotoxic national code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

Shipping Name
not regulated
Transport Class
not regulated
Packing Group
not regulated
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed

Employment restrictions concerning juveniles must be observed. Employment restrictions concerning pregnant and lactating women must be observed.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is TCPP known by?

TCPP is also known as: Tris(2-chlorisopropyl)phosphat

What is the hazard signal word for TCPP?

The signal word is warning.

What is the physical form of TCPP?

TCPP is a fluid appearing as fluid with colourless color. It has undistinguishable. odor.

What is TCPP used for?

Flame retardant.

What are the hazard statements for TCPP?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H351: Suspected of causing cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of TCPP?

The melting point is -20 °C and the boiling point is 288 °C.