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Safety Data Sheet EN

Allyl chloride, stabilized

CAS 107-05-1
EC 203-457-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Allyl chloride, stabilized
Product Code
102910000; 102910010; 102911000; 102910025
Chemical Name
Allyl chloride
Synonyms
3-Chloropropene

Regulatory Identifiers

CAS Number
107-05-1 Check regulations →
EC Number
203-457-6 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

manufacturer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Muta. Cat. 2 H341
Carc. Cat. 2 H351
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapor
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 Ground and bond container and receiving equipment
P243 Take action to prevent static discharges
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P332 + P313 If skin irritation occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P403 + P235 Store in a well-ventilated place. Keep cool

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
1-Propene, 3-chloro- EC: 203-457-6 107-05-1 95% Yes
Propylene oxide EC: 200-879-2 75-56-9 0.05 - 0.09% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. If not breathing, give artificial respiration.

Symptoms: Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Immediate medical attention is required. Get medical attention.

Ingestion

Do NOT induce vomiting. Get medical attention.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO₂). Dry chemical. Water mist may be used to cool closed containers. Chemical foam.

Unsuitable media

No information available.

Specific hazards

Flammable. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.

Cleanup methods

Soak up with inert absorbent material

Materials: sand, silica gel, acid binder, universal binder, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure adequate ventilation. Wear personal protective equipment/face protection. Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Handle product only in closed system or provide appropriate exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Use only non-sparking tools. Remove all sources of ignition. Take precautionary measures against static discharges. Keep away from open flames, hot surfaces and sources of ignition. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded.

Storage

Flammables area. Keep away from heat, sparks and flame. Keep container tightly closed in a dry and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Use spark-proof tools and explosion-proof equipment. Use only non-sparking tools. Remove all sources of ignition. Take precautionary measures against static discharges. Keep away from open flames, hot surfaces and sources of ignition. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Viton (R). Breakthrough time: See manufacturers recommendations. Glove thickness: -. EU standard: EN 374. Glove comments: (minimum requirement).

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: low boiling organic solvent Type AX Brown conforming to EN371. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Appearance
Colorless
Relative Density
---
Flash Point
-29 °C / -20.2 °F
Partition Coefficient
1-Propene, 3-chloro-: 2.1; Propylene oxide: 1
Odor
pungent
Relative Evaporation Rate
---
Flammability
Highly flammable
Odor Threshold
No data available
Density
0.939
Evaporation Rate
---
Solubility In Fat
---
Auto Ignition Temperature
390 °C / 734 °F
Colour Intensity
---
Vapor Pressure
395 mbar @ 20 °C
Cloud Point
---
Bulk Density
Not applicable
Decomposition Temperature
No data available
Solidification Point
---
Vapor Density
---
Explosive Limits
---
Boiling Point
44 - 46 °C / 111.2 - 114.8 °F
Properties Status
---
Melting Point
-136 °C / -212.8 °F
State Under Standard Conditions
---
Physical State
Liquid
Lower Explosive Limit
3.3 Vol%
Freezing Point
---
Ph
No information available
Form
---
Solubility
---
Metal Corrosion
---
Colour
---
Voc Content
---
Crystallisation Point
---
Dynamic Viscosity
0.34 mPa.s at 20 °C
Kinematic Viscosity
---
Molecular Weight
76.53
Solubility In Water
3.6 g/L (20°C)
Physical State Data
liquid
Upper Explosive Limit
11.2 Vol%
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

May form explosive peroxides.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous Polymerization may occur. Hazardous Reactions No information available.

Avoid

Keep away from open flames, hot surfaces and sources of ignition. Excess heat. Exposure to light. Incompatible products. Exposure to moist air or water.

Incompatible

Acids. Bases. Amines. Metals. Finely powdered metals.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂). Phosgene. Hydrogen chloride gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1100
Shipping Name
ALLYL CHLORIDE
Transport Class
3
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Allyl chloride, stabilized known by?

Allyl chloride, stabilized is also known as: 3-Chloropropene

What is the hazard signal word for Allyl chloride, stabilized?

The signal word is danger.

What is the physical form of Allyl chloride, stabilized?

Allyl chloride, stabilized is a liquid appearing as colorless . It has pungent odor.

What is Allyl chloride, stabilized used for?

Laboratory chemicals.

What are the hazard statements for Allyl chloride, stabilized?

This substance has 9 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation
  • H341: Suspected of causing genetic defects
  • H351: Suspected of causing cancer
  • H373: May cause damage to organs through prolonged or repeated exposure
  • H400: Very toxic to aquatic life

What is the melting point of Allyl chloride, stabilized?

The melting point is -136 °C / -212.8 °F and the boiling point is 44 - 46 °C / 111.2 - 114.8 °F.