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Safety Data Sheet EN

Allyl bromide

CAS 106-95-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Allyl bromide
Product Code
A29585

Regulatory Identifiers

CAS Number
106-95-6 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapor.
H301 + H331 Toxic if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H340 May cause genetic defects.
H350 May cause cancer.
H400 Very toxic to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
3-bromo-1-propene EC: 203-446-6 106-95-6 100% Yes
propylene oxide EC: 200-879-2 75-56-9 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards

Carbon oxides, Hydrogen bromide gas, Flash back possible over considerable distance., Container explosion may occur under fire conditions.

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Cleanup methods

collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Avoid inhalation of vapor or mist.

Storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Hygiene

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Fire prevention

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: Fluorinated rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash contact Material: Fluorinated rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Form
clear, liquid
Flash Point
-1 °C
Crystallisation Point
---
Explosive Limits
---
Solidification Point
---
Decomposition Temperature
---
Softening Point
---
Solubility In Fat
---
Melting Point
-119 °C
Lower Explosive Limit
4,3 % (V)
Metal Corrosion
---
Properties Status
---
Evaporation Rate
---
Relative Density
---
Flammability
---
Density
1,398 g/mL at 25 °C
Relative Evaporation Rate
---
Solubility In Water
3,83 g/l at 25 °C
Vapor Pressure
---
Partition Coefficient
log Pow: 1,79 at 20 °C
Physical State
liquid
Cloud Point
---
Voc Content
---
Solubility
---
Bulk Density
---
State Under Standard Conditions
---
Ph
---
Boiling Point
70 - 71 °C
Vapor Density
---
Physical State Data
liquid
Odor
unpleasant
Upper Explosive Limit
7,3 % (V)
Colour
colorless
Odor Threshold
---
Appearance
clear, liquid
Freezing Point
---
Molecular Weight
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Auto Ignition Temperature
---
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. Contains the following stabilizer(s): propylene oxide (<=0,1 %)

Reactivity

No data available

Hazardous reactions

No data available

Avoid

May polymerize on exposure to light. Exposure to moisture. Exposure to air. Heat, flames and sparks.

Incompatible

Oxidizing agents, Alkali metals, Alkaline earth metals, Light metals, Amides, Amines, Powdered metals

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1099
Shipping Name
ALLYL BROMIDE
Transport Class
3 (6.1)
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Allyl bromide?

The signal word is danger.

What is the physical form of Allyl bromide?

Allyl bromide is a liquid appearing as clear, liquid with colorless color. It has unpleasant odor.

What is Allyl bromide used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Allyl bromide?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H301 + H331: Toxic if swallowed or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H400: Very toxic to aquatic life.

What is the melting point of Allyl bromide?

The melting point is -119 °C and the boiling point is 70 - 71 °C.