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Safety Data Sheet EN

N,N-Dimethylformamide

CAS 68-12-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
N,N-Dimethylformamide
Product Code
SLD4261, SLD3331
Chemical Name
N,N-Dimethylformamide
Synonyms
DMF; Dimethyl Formamide

Regulatory Identifiers

CAS Number
68-12-2 Check regulations →

Manufacturers & Suppliers

Sciencelab.com, Inc. logo

Sciencelab.com, Inc.

manufacturer

14025 Smith Rd. Houston, Texas 77396

1-281-441-4400

http://ScienceLab.com

Emergency Contacts

CHEMTREC

1-800-424-9300

24HR

International CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

EUH031 Mutagenic for bacteria and/or yeast.
H312 Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation.
H341 MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
H351 CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC.
H360D TERATOGENIC EFFECTS: Classified POSSIBLE for human.
H360F DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].
H373 The substance is toxic to kidneys, liver, central nervous system (CNS).
H373 The substance may be toxic to blood, the nervous system.
H373 Repeated or prolonged exposure to the substance can produce target organs damage.
Potential Chronic Health Effects:

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Name {N,N-}Dimethylformamide 68-12-2 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation.

Skin contact

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.

Symptoms: irritated skin

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Ingestion

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Immediate Medical Attention

Get medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog.

Specific hazards

Flammable liquid, soluble or dispersed in water. Flammable in presence of open flames and sparks, of heat.

Instructions

Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Small spill

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Large spill

Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep locked up. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.

Storage

Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use.

Hygiene

Do not ingest. Avoid contact with skin and eyes.

Fire prevention

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Avoid all possible sources of ignition (spark or flame).

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.

Hands

Gloves.

Eyes

Splash goggles.

Respiratory

Vapor respirator. Be sure to use an approved/certified respirator or equivalent. In case of a large spill: A self contained breathing apparatus should be used to avoid inhalation of the product.

Skin/Body

Lab coat. In case of a large spill: Full suit, Boots.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
0.949
Cloud Point
---
Physical State Data
liquid
Molecular Weight
73.09 g/mole
Metal Corrosion
---
Solidification Point
---
Vapor Pressure
0.3 kPa (@ 20°C)
Decomposition Temperature
---
Relative Evaporation Rate
---
Flammability
---
Properties Status
---
Odor
Amine like. (Slight.)
Melting Point
-61°C (-77.8°F)
Density
---
Odor Threshold
100 ppm
Flash Point
---
Boiling Point
153°C (307.4°F)
Dynamic Viscosity
---
Solubility In Water
---
Solubility
Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible organic solvents. Soluble in benzene, and chloroform.
Appearance
Liquid
Physical State
Liquid
Colour
Colorless to light yellow
Partition Coefficient
log (oil / water) = -1
Upper Explosive Limit
---
Auto Ignition Temperature
---
Form
---
Colour Intensity
---
Solubility In Fat
---
Kinematic Viscosity
---
Voc Content
---
Crystallisation Point
---
Evaporation Rate
---
Explosive Limits
---
Freezing Point
---
Ph
---
Vapor Density
2.51
State Under Standard Conditions
---
Bulk Density
---
Lower Explosive Limit
---
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

Can react vigorously with oxidizing agents, halogenated hydrocarbons, and inorganic nitrates. Reaction with inorganic acid chlorides, such as phosphorous oxychloride and thionyl chloride, may form dimethylcarbamoyl, a suspect carcinogen.

Hazardous reactions

Will not occur.

Avoid

Heat, ignition sources (sparks, flames), incompatible materials

Incompatible

oxidizing agents, acids, carbon tetrachloride, alkyl aluminums, sodium tetrahydroborate, nitrates, chromic acid, diisocyanatomethane, triethylaluminum, sodium hydride, lithium azide, metallic sodium, bromine, magnesium nitrate, potassium permanganate, nitric acid, chromium trioxide, borohydrides, phosphorus trioxide, diborane, octafluoroisobutyrate, sodium nitrite, perchloryl fluoride, postassium methyl 4,4'-dinitrobutyrate, copper, tin and their alloys.

Decomposition

May release dimethylamine and carbon monooxide if heated above 350°C (662 F).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2265
Shipping Name
N,N-Dimethylformamide
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is N,N-Dimethylformamide known by?

N,N-Dimethylformamide is also known as: DMF; Dimethyl Formamide

What is the hazard signal word for N,N-Dimethylformamide?

The signal word is danger.

What is the physical form of N,N-Dimethylformamide?

N,N-Dimethylformamide is a liquid appearing as liquid with colorless to light yellow color. It has amine like. (slight.) odor.

What is the solubility of N,N-Dimethylformamide?

Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible organic solvents. Soluble in benzene, and chloroform.

What are the hazard statements for N,N-Dimethylformamide?

This substance has 10 hazard statements:

  • EUH031: Mutagenic for bacteria and/or yeast.
  • H312: Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation.
  • H341: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
  • H351: CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC.
  • H360D: TERATOGENIC EFFECTS: Classified POSSIBLE for human.
  • H360F: DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].
  • H373: The substance is toxic to kidneys, liver, central nervous system (CNS).
  • H373: The substance may be toxic to blood, the nervous system.
  • H373: Repeated or prolonged exposure to the substance can produce target organs damage.
  • Potential Chronic Health Effects:

What is the melting point of N,N-Dimethylformamide?

The melting point is -61°C (-77.8°F) and the boiling point is 153°C (307.4°F).