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Safety Data Sheet EN

Ammonium fluoride for analysis EMSURE® ACS

CAS 12125-01-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ammonium fluoride for analysis EMSURE® ACS
Product Code
1.01164

Regulatory Identifiers

CAS Number
12125-01-8 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H311

GHS Pictograms

GHS06 - Acute toxicity

GHS06

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary Statements

P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.
IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ammonium fluoride EC: 235-185-9 12125-01-8 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. Keep respiratory tract clear. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

Rinse with plenty of water for at least 10 minutes. Immediately remove contaminated clothes. Apply calcium gluconate gel (preparation: boil 5 g of calcium gluconate in 85 ml of hot distilled water, add 10 g glycerol. Allow 5 g of Carmellose-sodium to swell in the hot solution. Stable for 6 months, store in a cool place) and massage into the skin until the pain subsides, in between rinse with water and apply fresh gel. Continue gel therapy for another 15 minutes after the pain has subsided. If no calcium gluconate gel is available, apply several dressings thoroughly moistened with 20 % calcium gluconate solution.

Eye contact

Rinse with plenty of water keeping eyelids open, protecting the unaffected eye (at least 10 minutes). Seek medical advice immediately! Remove contact lenses.

Ingestion

Immediately give to drink plenty of water, add calcium (in the form of calcium gluconate or calcium lactate). Caution: In the case of vomiting risk of perforation! Administer more calcium gluconate solution. Laxative: Sodium sulfate (1 tablespoon/1/4 l water). Seek medical advice immediately. Ensure that injured persons remain calm and protect them against heat loss.

Immediate Medical Attention

Immediately call in physician (inhalation). Medical advice absolutely required! Call a physician immediately (skin). Seek medical advice immediately! (eyes). Seek medical advice immediately (ingestion).

Medical Treatment

It is recommended to consult a doctor with experience in the treatment of lesions caused by hydrofluoric acid. Caution, ventricular fibrillation due to electrolyte imbalance.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Nitrogen oxides (NOx), Hydrogen fluoride. Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter B-(P3). The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
---
Odor
ammoniacal
Odor Threshold
---
Ph
ca.6 at 50 g/l at 20 °C
Melting Point
Melting point: (sublimed)
Boiling Point
Not applicable
Flash Point
does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
---
Relative Density
No data available
Bulk Density
ca.250 - 350 kg/m3
Density
ca.1,01 g/cm3 at 20 °C
Flammability
The product is not flammable.
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
ca. 100 °C
Solubility
---
Partition Coefficient
No data available
Solubility In Water
820 g/l at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Generates dangerous gases or fumes in contact with: acids. Release of: Hydrogen fluoride. Risk of explosion with: halogen-halogen compounds

Avoid

hygroscopic

Incompatible

glass, Metals, quartzes/silicate ceramics

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2505
Shipping Name
AMMONIUM FLUORIDE
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Ammonium fluoride for analysis EMSURE® ACS?

The signal word is danger.

What is the physical form of Ammonium fluoride for analysis EMSURE® ACS?

Ammonium fluoride for analysis EMSURE® ACS is a solid with white color. It has ammoniacal odor.

What is Ammonium fluoride for analysis EMSURE® ACS used for?

Reagent for analysis

What are the hazard statements for Ammonium fluoride for analysis EMSURE® ACS?

This substance has 1 hazard statement:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.

What is the melting point of Ammonium fluoride for analysis EMSURE® ACS?

The melting point is Melting point: (sublimed) and the boiling point is Not applicable.