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Safety Data Sheet EN

Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO
Product Code
107210

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis In compliance with the conditions described in the annex to this safety data sheet.

Manufacturers & Suppliers

M

Merck Chemicals Ltd

regional supplier

Boulevard Industrial Park, Padge Road, Beeston, Nottingham, NG9 2JR

01159 430840

Emergency Contacts

Emergency Contact

+49 (0) 6151 722440

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Eye Dam. Cat. 1 H318
Aquatic Chronic Cat. 4 H413

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H318 Causes serious eye damage.
H413 May cause long lasting harmful effects to aquatic life.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear eye protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hydrogen Peroxide 7722-84-1 25 - 35% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air.

Symptoms: Dizziness, Unconsciousness, Headache

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Symptoms: Irritation and corrosion

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Symptoms: Conjunctivitis, Risk of serious damage to eyes.

Ingestion

immediately make victim drink water (two glasses at most). Consult a physician.

Symptoms: Diarrhoea, Nausea, Vomiting

Immediate Medical Attention

Immediately call in ophthalmologist. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours. Has a fire-promoting effect due to release of oxygen.

Instructions

Prevent skin contact by keeping a safe distance.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Protected from light. Do not store near combustible materials. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: natural latex Glove thickness: 0.6 mm Break through time: > 480 min splash contact: Glove material: Nitrile rubber Glove thickness: 0.11 mm Break through time: > 480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 706 Lapren® (full contact), KCL 741 Dermatril® L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: filter NO. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
colourless
Colour
colourless
Colour Intensity
---
Form
---
Odor
slight, stinging
Odor Threshold
No information available.
Ph
<= 3.5 (at 20 °C)
Melting Point
-25.7 °C
Boiling Point
107 °C (at 1,013 hPa)
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available.
Vapor Pressure
ca.18 hPa (at 20 °C)
Vapor Density
No information available.
Relative Density
No information available.
Bulk Density
---
Density
1.11 g/cm3 (at 20 °C)
Flammability
No information available.
Upper Explosive Limit
No information available.
Lower Explosive Limit
No information available.
Explosive Limits
---
Auto Ignition Temperature
No information available.
Decomposition Temperature
> 100 °C
Solubility
---
Partition Coefficient
log Pow: -1.57 (calculated)
Solubility In Water
completely miscible (at 20 °C)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No information available.
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

heat-sensitive, Sensitivity to light. Stabilizer: 2,6-Pyridinedicarboxylic acid

Reactivity

Has a fire-promoting effect due to release of oxygen.

Hazardous reactions

Risk of explosion with: Acetaldehyde, Acetone, Activated charcoal, Alcohols, formic acid, Ammonia, combustible substances, vinyl acetate, Organic Substances, Powdered metals, Dust., hydrazine and derivatives, hydrides, Ether, Potassium, anilines, metallic salts, acetic acid, Acetic anhydride, formaldehyde, furfuryl alcohol, oils, sodium, Lithium, lithium aluminium hydride, organic solvents, magnesium, metallic oxides, Methanol, Reducing agents, Oxides of phosphorus. butanol, with, Sulphuric acid. alkali hydroxides, with, Heavy metals. Exothermic reaction with: alkali hydroxides, antimony sulfide, tin (II) chloride, Sulphides, THIOPHENE, nitric acid (conc.), ethanol, glycerol, Potassium hydroxide, phosphorus, metallic oxides, Sodium hydroxide, Aldehydes, nonmetals, nonmetallic oxides, strong alkalis, Amines, Acids, Oxidizing agents, alkali salts, Alkali metals, Alkaline earth metals, iodides, peroxi compounds, brass, organic nitro compounds. phenol, with, metal catalysts. Risk of ignition or formation of inflammable gases or vapours with: potassium permanganate, Wood/Sawdust. vinyl acetate, with, Catalyst

Avoid

Heating.

Incompatible

Metals

Decomposition

no information available

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2014
Shipping Name
HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Transport Class
5.1 (8)
Packing Group
II
ADR

Not permitted for transport

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO?

The signal word is danger.

What is the physical form of Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO?

Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO is a liquid appearing as colourless with colourless color. It has slight, stinging odor.

What is Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO used for?

Reagent for analysis In compliance with the conditions described in the annex to this safety data sheet.

What are the hazard statements for Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H318: Causes serious eye damage.
  • H413: May cause long lasting harmful effects to aquatic life.

What is the melting point of Hydrogen peroxide 30% (Perhydrol®) (stabilized for higher storage temp.) for analysis EMSURE® ISO?

The melting point is -25.7 °C and the boiling point is 107 °C (at 1,013 hPa).