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Safety Data Sheet EN

Toluene

CAS 108-88-3
EC 203-625-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Toluene
Product Form
substance
Product Code
1761
Chemical Name
Tolueen p.a.
Synonyms
handelskwaliteit

Regulatory Identifiers

CAS Number
108-88-3 Check regulations →
EC Number
203-625-9 Check regulations →
REACH No.
01-2119471310-51-0036

Identified Uses

Solvent Lacquer solvent/ Varnish thinner Use as an intermediate Other registered uses: See exposure scenario attached

Uses advised against

No further relevant information available.

Manufacturers & Suppliers

v

versalis S.p.A.

manufacturer

Piazza Boldrini, 1 I-20097 San Donato Milanese (MI)

+39 02 520 1

Emergency Contacts

S.E.T.

800 452 661

24h

S.E.T.

+39 (0)362512868

24h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Skin Irrit. Cat. 2 H315
Repr. Cat. 2 H361
STOT SE Cat. 3 H336
STOT RE Cat. 2 H373
Asp. Tox. Cat. 1 H304

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/ regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substances
Chemical Name CAS Number Concentration Hazardous
Tolueen p.a. EC: 203-625-9 108-88-3 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air; consult doctor in case of complaints. In case of unconsciousness place patient stably in side position for transportation.

Symptoms: Irritation of respiratory tract.

Skin contact

Immediately flush affected area with plenty of water. Immediately remove any clothing soiled by the product.

Symptoms: Skin irritations and dermatitis. In case of irritation, swelling or redness, consult a doctor.

Eye contact

Irrigate eyes with copious amounts of water for at least 10-15 min, holding eyelids apart to ensure thorough rinsing.

Symptoms: Conjunctival irritation; corneal ulcerations may occur. In case of irritation, blurred vision or swelling persist, consult a doctor.

Ingestion

Do not induce vomit. Wash the mouth with clean water. Call a doctor and/ or carry immediately to first aid. Do not give anything by mouth to an unconscious person. If vomiting occurs, the head should be kept low so that the vomit does not enter the lungs (aspiration).

Symptoms: Nervous system effects, headache, nausea, vomiting, drowsiness, narcosis. Aspiration into the lungs may cause chemical pneumonia.

Immediate Medical Attention

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. If swallowed then seek immediate medical assistance.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure good ventilation / exhaustion at the workplace. Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).

Hands

Wear suitable gloves tested to EN374. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation The following materials may provide suitable chemical protection: Fluorocarbon rubber (Recommended thickness of the material: 0.3 mm; Permeation time: > > 480 min) The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Eyes

In case of possible or foreseeable exposure to vapours or aerosol (and anyway in case of simultaneous use of respiratory protective equipment), it is preferable to wear a EN 136 certified full face mask for a better eye/ face protection.

Respiratory

Wear a EN 136 certified full face mask equipped with a EN 14387 certified gas filter of type A (Colour code: brown) In case filter respirators are not suitable (e.g.: high concentration of particles or aerosol, oxygen concentrations below 17% volume, unknown concentrations of vapours and/or gases or concentrations above the usage limits for filter devices as specified by the manufacturer, presence of other vapours and gases in the air, etc.) use EN 14594 certified continuous flow compressed air line breathing apparatus or EN 14593-1 certified compressed air line breathing apparatus with demand valve or EN 145 certified self-contained closed-circuit breathing apparatus or EN 137 certified self-contained open-circuit compressed air breathing apparatus. Keep a self-contained breathing apparatus or other insulating device ready for use in case of an emergency (e.g.: unintentional release of the substance), .

Skin/Body

If release of liquid chemicals is possible or foreseeable, wear a EN 14605 certified protective suit against liquid chemicals with liquid-tight connections. Wear flameproof (according to EN ISO 11612) and electrostatic dissipative (according to EN 1149-5) protective clothing. Chemical-resistant safety footwear (conforming EN 20345 & 13832). Footwear should be anti-static.

Environmental

Take all the technical precautions necessary to prevent the diffusion of the product in the environment For further details, see Exposure Scenarios

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Pressure
30.89 hPa
Upper Explosive Limit
7.1 Vol %
Physical State Data
liquid
Freezing Point
-95 C
Flammability
Based on physical-chemical property this test is not required
Molecular Weight
---
Physical State
---
Colour Intensity
---
Explosive Limits
---
Bulk Density
---
Properties Status
---
Colour
Colourless
Solubility
---
Vapor Density
3.18
Crystallisation Point
---
Appearance
---
Odor Threshold
8,02 mg/m3
Cloud Point
---
Solubility In Fat
---
Density
---
Relative Evaporation Rate
---
Dynamic Viscosity
0.56 mPas
Solubility In Water
0.587 g/l
Auto Ignition Temperature
480 C
Kinematic Viscosity
---
Partition Coefficient
2.73 log POW
Form
Fluid
Boiling Point
110.6 C
Evaporation Rate
Not determined.
Softening Point
---
Melting Point
-95 C
Lower Explosive Limit
1.1 Vol %
Decomposition Temperature
Not determined.
Relative Density
0.866 g/cm
State Under Standard Conditions
---
Solidification Point
---
Voc Content
---
Odor
Aromatic
Flash Point
4.4 C
Ph
Not determined.
Metal Corrosion
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1294
Shipping Name
TOLUENE
Transport Class
3
Packing Group
II
ADR

Warning: Flammable liquids.

IMDG

Warning: Flammable liquids.

IATA

Warning: Flammable liquids.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Toluene known by?

Toluene is also known as: handelskwaliteit

What is the hazard signal word for Toluene?

The signal word is danger.

What is Toluene used for?

Solvent Lacquer solvent/ Varnish thinner Use as an intermediate Other registered uses: See exposure scenario attached

What are the hazard statements for Toluene?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H361: Suspected of damaging the unborn child.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of Toluene?

The melting point is -95 C and the boiling point is 110.6 C.

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