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Methyl Tert-Butyl Ether (MTBE)

NO SIGNAL WORD liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Methyl Tert-Butyl Ether (MTBE)
Product Form
Ether

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Chemical Feedstock, Octane Booster, Fuel Additive

Overview

Methyl Tert-Butyl Ether (MTBE) is a clear ,colourless liquid substance commonly used chemical feedstock, octane booster, fuel additive.

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Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

no signal word

Hazard Classifications

Flam. Liq. Category 2
Acute Tox. Category 5
Skin Irrit. Category 2
Eye Irrit. Category 2B
Carc. Category 2
STOT SE Category 3
Asp. Tox. Category 1

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

Precautionary Statements

  • Keep container tightly closed.
  • Keep away from heat/sparks/open flames/hot surfaces. โ€“ No smoking.
  • Wear protective gloves/protective clothing/eye protection/face protection
  • Ground/Bond container and receiving equipment
  • Use explosion-proof electrical/ventilating/lighting equipment.
  • Take precautionary measures against static discharge.
  • Use only non-sparking tools.
  • Wear protective gloves
  • Wash thoroughly after handling.
  • Obtain special instructions before use.
  • Do not handle until all safety precautions have been read and understood.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Use only outdoors or in well-ventilated area.
  • IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • Call a POISON CENTER/doctor/physician if you feel unwell.
  • In case of fire: Use appropriate media for extinction.
  • If INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  • IF ON SKIN: Wash with plenty of soap and water.
  • Take off contaminated clothing and wash before re-use.
  • If skin irritation occurs: Get medical advice/attention.
  • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.
  • Wash hands after handling
  • IF exposed or concerned: Get medical attention/advice.
  • IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
  • Store in well-ventilated place. Keep cool. Keep container tightly closed.
  • Store locked up.
  • Dispose of the contents in accordance to the local mandatory rules and regulations

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Petrochemical Corporation of Singapore (Private) Limited

global supplier

๐Ÿ“

100 Ayer Merbau Road, Singapore 628277

๐ŸŒ

SG

๐Ÿ“ž

+65 68672102

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

Asia Pacific

๐Ÿ“ž

+65 3158 1074

๐ŸŒ

SG

๐Ÿ•’

24-Hour

China

๐Ÿ“ž

+86 10 5100 3039

๐ŸŒ

CN

๐Ÿ•’

24-Hour

Europe, Israel & Americas

๐Ÿ“ž

+44 (0) 1235 239 670

๐ŸŒ

GB

๐Ÿ•’

24-Hour

Middle East & Africa

๐Ÿ“ž

+44 (0) 1235 239 671

๐ŸŒ

GB

๐Ÿ•’

24-Hour

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

mixture

General Composition

The product contains Tert-Butyl Methyl Ether (MTBE) at a minimum of 98 wt%, with minor components including C4 Mixture (0.1-0.5 wt%), Tert-butyl alcohol (0.1-1.0 wt%), Di-isobutene (0.1-1.0 wt%), and Methanol (0.1-1.0 wt%).

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Tert-Butyl Methyl Ether
EC: 216-653-1
1634-04-4 98% โœ“ Non-hazardous
C4 N/A 0.1-0.5% โœ“ Non-hazardous
Tert-butyl alcohol 75-65-0 0.1-1% โœ“ Non-hazardous
Di-isobutene 25167-70-8 0.1-1% โœ“ Non-hazardous
Methanol 67-56-1 0.1-1% โœ“ Non-hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

๐Ÿซ Inhalation Exposure

Remove source of contamination or have victim move to fresh air. If not breathing, ensure clear airway and institute cardiopulmonary resuscitation (CPR). If breathing is difficult, administer oxygen if available. Obtain medical advice immediately.

Symptoms:

If symptoms are experienced

๐Ÿ–๏ธ Skin Contact

As quickly as possible, flush with lukewarm, gently flowing water for at least 20 minutes, or until the chemical is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts). Obtain medical attention immediately. Completely decontaminate clothing, shoes and leather goods before re-use or discard.

๐Ÿ‘๏ธ Eye Contact

Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for at least 5 minutes or until the chemical is removed, while holding the eyelid(s) open. Obtain medical advice immediately.

๐Ÿฝ๏ธ Ingestion/Swallowing

Never give anything by mouth if victim is rapidly losing consciousness, is unconscious or convulsing. Have victim rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 240 to 300 ml (8 to 10 ozs) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Repeat administration of water. Rinse mouth. Give slurry of activated charcoal in water to drink. Obtain medical attention immediately.

๐Ÿšจ Immediate Medical Attention Required

Obtain medical advice immediately (for inhalation, eye contact, ingestion). Obtain medical attention immediately (for skin contact). Consult a doctor and/or the nearest Poison Control Centre for all exposures, except minor instances of inhalation or skin contact.

Medical Treatment

In the unlikely event of ingestion of MTBE, appropriate lavage procedures should be considered to avoid accidental aspiration of the product.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

๐Ÿงช Physical State
liquid
Critical Property
๐Ÿ“Š Physical State Data
liquid
๐Ÿ“Š State Under Standard Conditions
Not available
๐Ÿ‘๏ธ Appearance
Clear ,colourless liquid
๐ŸŽจ Colour
colourless
๐Ÿ“Š Colour Intensity
Not available
๐Ÿ“Š Form
Not available
๐Ÿ‘ƒ Odor
Characteristic ethereal odour
๐Ÿ“Š Odor Threshold
Not available
๐Ÿงช Ph
Not available
๐ŸงŠ Melting Point
-109 C
Critical Property
๐Ÿ’จ Boiling Point
55 degC
Critical Property
๐Ÿ”ฅ Flash Point
โ€“33 degC
Critical Property
๐Ÿ“Š Freezing Point
-109 C
๐Ÿ“Š Softening Point
Not available
๐Ÿ“Š Solidification Point
Not available
๐Ÿ“Š Cloud Point
Not available
๐Ÿ“Š Crystallisation Point
Not available
๐Ÿ“Š Relative Evaporation Rate
8.04(Normal Butyl Acetate = 1)
๐Ÿ’จ Evaporation Rate
8.04(Normal Butyl Acetate = 1)
๐Ÿ’จ Vapor Pressure
27.9 kPa at 20 degC
๐Ÿ“Š Vapor Density
3.1g/l
๐Ÿ“Š Relative Density
0.74
๐Ÿ“Š Bulk Density
Not available
โš–๏ธ Density
Not available
๐Ÿ”ฅ Flammability
Not available
๐Ÿ“Š Upper Explosive Limit
15%[vol% in air]
๐Ÿ“Š Lower Explosive Limit
2%[vol% in air]
๐Ÿ“Š Explosive Limits
Not available
๐Ÿ“Š Auto Ignition Temperature
374 degC
๐Ÿ“Š Decomposition Temperature
Not available
๐Ÿ’ง Solubility
4.8 G/100G OF WATER
๐Ÿ“Š Partition Coefficient
Not available
๐Ÿ“Š Solubility In Water
4.8 G/100G OF WATER
๐Ÿ“Š Solubility In Fat
Not available
๐Ÿ“Š Molecular Weight
88.2
๐Ÿ“Š Voc Content
Not available
๐Ÿ“Š Metal Corrosion
Not available
๐Ÿ“Š Dynamic Viscosity
Not Available
๐Ÿ“Š Kinematic Viscosity
Not Available
๐Ÿ“Š Properties Status
Not available

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

๐Ÿญ Engineering Controls

Ventilation and other forms of engineering controls are often the preferred means for controlling chemical exposures.

๐Ÿงค Hand Protection

wear appropriate chemical protective gloves.

๐Ÿ‘๏ธ Eye Protection

Avoid eye contact with this material. Wear safety glasses or chemical goggles. Provide an eyewash station in the work area. Do not wear contact lenses when working with this substance.

๐Ÿ˜ท Respiratory Protection

If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection should be worn. Normally, a NIOSH approved respirator for organic vapours are generally acceptable. For high concentrations and for oxygen-deficient atmospheres, use a NIOSH approved air-supplied respirator. Ventilation and other forms of engineering controls are often the preferred means for controlling chemical exposures. Respiratory protection may be needed for non-routine or emergency situations.

๐Ÿฆบ Skin/Body Protection

Avoid skin contact. When working with this substance, wear appropriate chemical protective gloves. Depending upon conditions of use, additional protection may be necessary such as face shield, apron, armcovers, etc.

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

โœ… Chemical Stability

Stable under conditions of normal use.

โš—๏ธ Reactivity

Stable under conditions of normal use.

โš ๏ธ Hazardous Reactions

No hazardous polymerization. Much less likely to form peroxides than other ethers.

๐Ÿšซ Conditions to Avoid

Avoid high temperatures, open flames-sparks and the use of Un-grounded electrical equipment.

๐Ÿงช Incompatible Materials

Avoid contact with strong oxidizers, acids or bases. The use of Viton and Flourel elastomers in seals is not recommended.

๐Ÿ’จ Hazardous Decomposition Products

Combustion may produce CO, CO2 and reactive hydrocarbons.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

๐Ÿท๏ธ UN Number

2398

๐Ÿ“ฆ Proper Shipping Name

METHYL tert-BUTYL ETHER

โš ๏ธ Transport Hazard Class

3

๐Ÿ“‹ Packing Group

II

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Methyl Tert-Butyl Ether (MTBE)?

The signal word for this substance is "no signal word".

What is the physical form of Methyl Tert-Butyl Ether (MTBE)?

Methyl Tert-Butyl Ether (MTBE) is a liquid appearing as clear ,colourless liquid with colourless color. It has characteristic ethereal odour odor.

What is the solubility of Methyl Tert-Butyl Ether (MTBE)?

4.8 G/100G OF WATER

What is Methyl Tert-Butyl Ether (MTBE) used for?

Chemical Feedstock, Octane Booster, Fuel Additive

What is the melting point of Methyl Tert-Butyl Ether (MTBE)?

The melting point is -109 C and the boiling point is 55 degC.