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Safety Data Sheet EN

Tetrahydrofuran a.r.

CAS 109-99-9
EC 203-726-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tetrahydrofuran a.r.
Product Form
Substance
Product Code
CL00.2016
Chemical Name
Tetrahydrofuran
Synonyms
1,4-epoxybutane / agrisynth THF / butane, 1,4-epoxy- / butane, alpha,delta-oxide / butylene oxide / cyclotetramethylene oxide / diethylene oxide (=tetrahydrofuran) / furan, tetrahydro- / furanidine / hydrofuran / oxacyclopentane / oxolane / oxyl / tetrahydrofuran / tetramethylene oxide / THF

Regulatory Identifiers

CAS Number
109-99-9 Check regulations →
EC Number
203-726-8 Check regulations →
REACH No.
01-2119444314-46

Identified Uses

Laboratory chemical

Manufacturers & Suppliers

Chem-Lab nv logo

Chem-Lab nv

national supplier

Industriezone 'De arend 2', Zedelgem – Belgium

+32 50 288320

https://www.chem-lab.be

Emergency Contacts

Emergency Contact

+32 50 28 83 20

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Carc. Cat. 2 H351
Acute Tox. Cat. 4 H302
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P233 Keep container tightly closed.
P243 Take action to prevent static discharges.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Mono-constituent

Chemical Name CAS Number Concentration Hazardous
Tetrahydrofuran a.r. EC: 203-726-8 109-99-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. In case of respiratory problems, consult a doctor/medical service.

Symptoms: EXPOSURE TO HIGH CONCENTRATIONS: Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Nausea. Headache. Respiratory difficulties. Dizziness. Coughing. Disturbances of consciousness. Central nervous system depression. Feeling of weakness. Sensorial disturbances. Ringing in the ears.

Skin contact

If possible, wipe up/dry remove chemical. Then rinse/shower immediately with (lukewarm) water. If irritation persists, consult a doctor/medical service.

Symptoms: Dry skin. Red skin.

Eye contact

Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, consult a doctor/medical service.

Symptoms: Irritation of the eye tissue. Redness of the eye tissue.

Ingestion

Rinse mouth with water. Immediately consult a doctor/medical service. Do not wait for symptoms to occur to consult Poison Center.

Symptoms: Dry/sore throat. Risk of aspiration pneumonia. Symptoms similar to those listed under inhalation.

Immediate Medical Attention

Immediately consult a doctor/medical service.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (alcohol-resistant). Water spray if puddle cannot expand.

Unsuitable media

Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle expansion.

Specific hazards

DIRECT FIRE HAZARD: Highly flammable liquid and vapour. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD: May be ignited by sparks. May build up electrostatic charges: risk of ignition. Substance contains stabilizer against peroxidation. DIRECT EXPLOSION HAZARD: Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD: may be ignited by sparks. May form explosive peroxides. Reactions with explosion hazards: see 'Reactivity Hazard'.

Instructions

Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Take account of toxic fire-fighting water.

Firefighter Protection

Heat/fire exposure: self-contained breathing apparatus (EN 136 + EN 137).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes.

Large spill

Large spills/in enclosed spaces: self-contained breathing apparatus (EN 136 + EN 137).

Environmental

Prevent spreading in sewers.

Cleanup methods

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite, kieselguhr, powdered limestone. Take up liquid spill into inert absorbent material. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

Materials: sand, earth, vermiculite, kieselguhr, powdered limestone

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the concentration in the air regularly. Work under local exhaust/ventilation. Comply with the legal requirements. Clean contaminated clothing. Before use: check for peroxides and eliminate them. Handle and open the container with care. Cool before opening. Keep container tightly closed. Handle uncleaned empty containers as full ones. Do not discharge the waste into the drain. Do not use compressed air for pumping over.

Storage

2 – 8 °C. Store in a cool area. Store in a dry area. Store in a dark area. Keep container in a well-ventilated place. Detached building. May be stored under nitrogen. May be stored under argon. Store only in a stabilised state.

Hygiene

Observe strict hygiene.

Fire prevention

Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Fireproof storeroom. Provide the tank with earthing.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No additional information available

Hands

Protective gloves against chemicals (EN 374). Materials for protective clothing: Excellent resistance: Polyethylene. Good resistance: Tetrafluoroethylene. Less resistance: Polyvinylalcohol (PVA). Poor resistance: Butyl rubber. Chlorinated polyethylene. Natural rubber. Nitrile rubber. Polyvinylchloride (PVC). neoprene/natural rubber. Nitrile rubber/PVC. Viton

Eyes

Protective goggles (EN 166)

Respiratory

Full face mask with filter type A at conc. in air > exposure limit

Skin/Body

Protective clothing (EN 14605 or EN 13034)

Environmental

No additional information available

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Fruity odour. Ether-like odour.
Odor Threshold
Not available
Ph
No data available in the literature
Melting Point
-108 °C
Boiling Point
65 °C
Flash Point
-21 °C
Freezing Point
Not available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
8 (butylacetate=1), 2.3 (ether=1)
Evaporation Rate
Relative evaporation rate (butylacetate=1) : 8, Relative evaporation rate (ether=1) : 2.3
Vapor Pressure
170 hPa (20 °C)
Vapor Density
---
Relative Density
0.88 (25 °C)
Bulk Density
---
Density
883 kg/m³ (25 °C)
Flammability
Not available
Upper Explosive Limit
11.8 vol %
Lower Explosive Limit
1.8 vol %
Explosive Limits
---
Auto Ignition Temperature
215 °C
Decomposition Temperature
No data available in the literature
Solubility
Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in dimethyl sulfoxide. Soluble in oils/fats. Water: miscible, Ethanol: > 10 g/100ml, Acetone: > 10 g/100ml
Partition Coefficient
0.45 (Experimental value, Equivalent or similar to OECD 107, 25 °C)
Solubility In Water
miscible
Solubility In Fat
Soluble in oils/fats.
Molecular Weight
72.11 g/mol
Voc Content
100 %
Metal Corrosion
---
Dynamic Viscosity
0.456 mPa.s (25 °C)
Kinematic Viscosity
No data available in the literature
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable on exposure to light. Unstable on exposure to air. Unstable on exposure to moisture.

Reactivity

Reacts violently with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with (some) bases. Unstabilised product reacts on exposure to air: peroxidation resulting in increased fire or explosion risk. Unstabilised product: on exposure to light: peroxidation resulting in increased fire or explosion risk. May form explosive peroxides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not discharge into drains or the environment. Dispose of at authorized waste collection point. Remove waste in accordance with local and/or national regulations.

Disposal

Do not discharge into drains or the environment. Dispose of at authorized waste collection point. Remove waste in accordance with local and/or national regulations.

Waste Codes

15 01 10* packaging containing residues of or contaminated by dangerous substances EWC
07 01 04* other organic solvents, washing liquids and mother liquors EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2056
Shipping Name
tetrahydrofuran
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Tetrahydrofuran a.r. known by?

Tetrahydrofuran a.r. is also known as: 1,4-epoxybutane / agrisynth THF / butane, 1,4-epoxy- / butane, alpha,delta-oxide / butylene oxide / cyclotetramethylene oxide / diethylene oxide (=tetrahydrofuran) / furan, tetrahydro- / furanidine / hydrofuran / oxacyclopentane / oxolane / oxyl / tetrahydrofuran / tetramethylene oxide / THF

What is the hazard signal word for Tetrahydrofuran a.r.?

The signal word is danger.

What is the physical form of Tetrahydrofuran a.r.?

Tetrahydrofuran a.r. is a liquid appearing as liquid. with colourless. color. It has fruity odour. ether-like odour. odor.

What is the solubility of Tetrahydrofuran a.r.?

Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in dimethyl sulfoxide. Soluble in oils/fats. Water: miscible, Ethanol: > 10 g/100ml, Acetone: > 10 g/100ml

What is Tetrahydrofuran a.r. used for?

Laboratory chemical

What are the hazard statements for Tetrahydrofuran a.r.?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.

What is the melting point of Tetrahydrofuran a.r.?

The melting point is -108 °C and the boiling point is 65 °C.