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Safety Data Sheet EN

Tetrahydrofuran a.r.

CAS 109-99-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tetrahydrofuran a.r.
Product Code
CL00.2016
Chemical Name
Tetrahydrofuran

Regulatory Identifiers

CAS Number
109-99-9 Check regulations →
REACH No.
01-2119444314-46

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

C

CHEM-LAB NV

Emergency Contacts

Emergency Contact

00 (32) 50.28.83.20

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335
Acute Tox. Cat. 4 H302
Carc. Cat. 2 H351

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.

Precautionary Statements

P210 Keep away from heat, sparks, open flames, hot surfaces. No smoking.
P233 Keep container tightly closed.
P243 Take precautionary measures against static discharge.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Tetrahydrofuran a.r. 99.9+% (Stabilised with 250 ppm BHT)

Chemical Name CAS Number Concentration Hazardous
Tetrahydrofuran a.r. EC: 203-726-8 109-99-9 99.9% Yes

Notes

Stabilised with 250 ppm BHT

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Fresh air.

Skin contact

Wash off with plenty of water. Remove contaminated clothing.

Eye contact

Rinse out with plenty of water for at least 10 minutes with the eyelid held wide open. Immediately call an ophthalmologist.

Ingestion

Never give anything by mouth to an unconscious person. Make the victim drink plenty of water, induce vomiting. Call in physician.

Immediate Medical Attention

Immediately call an ophthalmologist. Call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical or carbon dioxide.

Unsuitable media

Cool container with spray water from a save distance. Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or groundwater.

Specific hazards

Combustible. Vapours heavier than air. Forms explosive mixtures with air at ambient temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Cool container with spray water from a save distance. Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or groundwater.

Firefighter Protection

Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not inhale vapours/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms.

Environmental

Do not allow to enter sewerage system; risk of explosion!

Cleanup methods

Absorb on vermiculite, sand or a pillow from Chemical Spill Center.

Materials: vermiculite, sand or a pillow from Chemical Spill Center

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not inhale substance.

Storage

Closed in a well ventilated place. Recommended storage temperature see product label.

Fire prevention

Keep away from sources of ignition. Take measures to prevent electrostatic charging. Away from sources of ignition and heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. See section 7.1. Work under hood.

Hands

Required.

Eyes

Required.

Respiratory

Required when vapours/aerosols are generated. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Required.

Environmental

Do not allow to enter sewerage system; risk of explosion!

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Voc Content
---
Odor
specific
Auto Ignition Temperature
230°C
State Under Standard Conditions
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Solubility In Water
soluble
Odor Threshold
---
Flammability
---
Flash Point
-20°C
Evaporation Rate
---
Lower Explosive Limit
2 vol%
Molecular Weight
72.11 g/mol
Form
Liquid
Solubility
---
Ph
---
Density
0,89 g/ml
Softening Point
---
Explosive Limits
---
Colour Intensity
---
Freezing Point
---
Properties Status
---
Vapor Pressure
---
Cloud Point
---
Bulk Density
---
Vapor Density
---
Solubility In Fat
---
Crystallisation Point
---
Partition Coefficient
---
Melting Point
-108°C
Metal Corrosion
---
Upper Explosive Limit
12.4 vol%
Relative Density
---
Physical State Data
liquid
Boiling Point
66°C
Appearance
Liquid, Colourless, specific
Decomposition Temperature
---
Colour
Colourless
Physical State
Liquid
Relative Evaporation Rate
---
Solidification Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No further relevant information available.

Reactivity

See section 10.3

Hazardous reactions

Explosible with air in a vaporous/gaseous state when heated

Avoid

No further relevant information available.

Incompatible

No further relevant information available.

Decomposition

No further relevant information available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemicals must be disposed of in compliance with the respective national regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2056
Shipping Name
Tetrahydrofuran
Transport Class
3
Packing Group
II
ADR

no

IMDG

no

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

For this product an assessment was not carried out.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Tetrahydrofuran a.r.?

The signal word is danger.

What is the physical form of Tetrahydrofuran a.r.?

Tetrahydrofuran a.r. is a liquid appearing as liquid, colourless, specific with colourless color. It has specific odor.

What is Tetrahydrofuran a.r. used for?

Reagent for analysis

What are the hazard statements for Tetrahydrofuran a.r.?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.

What is the melting point of Tetrahydrofuran a.r.?

The melting point is -108°C and the boiling point is 66°C.