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Safety Data Sheet EN

Phosphorus(V) oxychloride

CAS 10025-87-3
EC 233-046-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phosphorus(V) oxychloride
Product Code
262099
Chemical Name
phosphoryl trichloride
Synonyms
Phosphorus(V) oxide chloride

Regulatory Identifiers

CAS Number
10025-87-3 Check regulations →
EC Number
233-046-7 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich BVBA/SPRL

Pegasuslaan 5 B-1831 DIEGEM

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 2 H330
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT RE Cat. 1 H372

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure if inhaled.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
phosphoryl trichloride EC: 233-046-7 10025-87-3 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

No data available

Medical Treatment

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 120 min Material tested:Butoject® (KCL 898). Conditions deviating from those stated in EN374 should prompt contact with the supplier of CE-approved gloves.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter B-(P2)

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Explosive Limits
---
Metal Corrosion
---
Flash Point
No data available
Physical State Data
liquid
Lower Explosive Limit
No data available
Solubility
---
Flammability
No data available
Colour
colorless
Odor
odorless
Relative Density
1,645 at 25 °C
Kinematic Viscosity
No data available
Cloud Point
---
Decomposition Temperature
No data available
Evaporation Rate
No data available
Auto Ignition Temperature
No data available
Colour Intensity
---
Upper Explosive Limit
No data available
Form
liquid
Properties Status
---
Solubility In Water
No data available
Freezing Point
---
State Under Standard Conditions
---
Crystallisation Point
---
Physical State
liquid
Vapor Pressure
37 hPa at 20 °C
Density
---
Softening Point
---
Relative Evaporation Rate
---
Voc Content
---
Solubility In Fat
---
Solidification Point
---
Odor Threshold
Not applicable
Ph
1 at 20 °C
Appearance
Form: liquid, Color: colorless
Bulk Density
---
Melting Point
1,25 °C
Vapor Density
5,29 - (Air = 1.0)
Dynamic Viscosity
No data available
Molecular Weight
---
Boiling Point
105,8 °C
Partition Coefficient
Not applicable for inorganic substances
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

sensitive to moisture

Reactivity

Reacts violently with water. Contact with water liberates toxic gas.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Zinc carbon disulfide boron triiodide Organic Substances chromyl chloride A risk of explosion and/or of toxic gas formation exists with the following substances: Dimethylformamide Alkali metals dimethyl sulfoxide Water Possible formation of: Hydrogen chloride gas phosphine Violent reactions possible with: Acetone

Avoid

Avoid contact with combustible material (paper, wool, oil). Moisture.

Incompatible

Strong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1810
Shipping Name
PHOSPHORUS OXYCHLORIDE
Transport Class
6.1 (8)
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Phosphorus(V) oxychloride known by?

Phosphorus(V) oxychloride is also known as: Phosphorus(V) oxide chloride

What is the hazard signal word for Phosphorus(V) oxychloride?

The signal word is danger.

What is the physical form of Phosphorus(V) oxychloride?

Phosphorus(V) oxychloride is a liquid appearing as form: liquid, color: colorless with colorless color. It has odorless odor.

What is Phosphorus(V) oxychloride used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Phosphorus(V) oxychloride?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H330: Fatal if inhaled.
  • H372: Causes damage to organs through prolonged or repeated exposure if inhaled.

What is the melting point of Phosphorus(V) oxychloride?

The melting point is 1,25 °C and the boiling point is 105,8 °C.

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