NextSDS Logo
Safety Data Sheet EN

Phosphorus(V) oxychloride

CAS 10025-87-3

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report.

Get Free Audit
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phosphorus(V) oxychloride
Product Code
262099
Chemical Name
Phosphorus(V) oxychloride

Regulatory Identifiers

CAS Number
10025-87-3 Check regulations →
REACH No.
01-2119433306-46-XXXX

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich BVBA/SPRL

distributor

Pegasuslaan 5, B-1831 DIEGEM

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 2 H330
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT RE Cat. 1 H372

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure if inhaled.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report

Free Audit
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
phosphoryl trichloride EC: 233-046-7 10025-87-3 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

Water Foam

Specific hazards

Oxides of phosphorus, Hydrogen chloride gas, Not combustible. May not get in touch with: Water. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®).

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Keep workplace dry. Do not allow product to come into contact with water.

Storage

Store under inert gas. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Keep away from water. Never allow product to get in contact with water during storage.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Splash contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 120 min, Material tested: Butoject® (KCL 898)

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter B-(P2). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid, colorless
Colour
colorless
Colour Intensity
---
Form
liquid
Odor
odorless
Odor Threshold
Not applicable
Ph
1 at 20 °C
Melting Point
1,25 °C
Boiling Point
105,8 °C
Flash Point
No data available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
37 hPa at 20 °C
Vapor Density
5,29 - (Air = 1.0)
Relative Density
1,645 at 25 °C
Bulk Density
---
Density
---
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
Not applicable for inorganic substances
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

sensitive to moisture

Reactivity

Reacts violently with water. Contact with water liberates toxic gas.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Zinc, carbon disulfide, boron triiodide, Organic Substances, chromyl chloride. A risk of explosion and/or of toxic gas formation exists with the following substances: Dimethylformamide, Alkali metals, dimethyl sulfoxide, Water. Possible formation of: Hydrogen chloride gas, phosphine. Violent reactions possible with: Acetone.

Avoid

Avoid contact with combustible material (paper, wool, oil). Moisture.

Incompatible

Strong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Disposal

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1810
Shipping Name
PHOSPHORUS OXYCHLORIDE
Transport Class
6.1 (8)
Packing Group
I
ADR

No data available

IMDG

No data available

IATA

No data available

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Phosphorus(V) oxychloride?

The signal word is danger.

What is the physical form of Phosphorus(V) oxychloride?

Phosphorus(V) oxychloride is a liquid appearing as liquid, colorless with colorless color. It has odorless odor.

What is Phosphorus(V) oxychloride used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Phosphorus(V) oxychloride?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H330: Fatal if inhaled.
  • H372: Causes damage to organs through prolonged or repeated exposure if inhaled.

What is the melting point of Phosphorus(V) oxychloride?

The melting point is 1,25 °C and the boiling point is 105,8 °C.