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Safety Data Sheet EN

42B19STKIL

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
42B19STKIL

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Electric Storage battery

Manufacturers & Suppliers

HYUNDAI SUNGWOO SOLITE logo

HYUNDAI SUNGWOO SOLITE

manufacturer

200. Yongmyeonggondan-gil, Geoncheon-up, Gyengju-si, Gyeonbuk, Korea

82-54-750-7114

www.hdswsolite.co.kr

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Not Classified
Met. Corr. Cat. 1
Acute Tox. Cat. 2
Skin Corr. Cat. 1
Eye Dam. Cat. 1
Carc. Cat. 1A
Muta. Cat. 2
Repr. Cat. 1A
STOT SE Cat. 1
STOT RE Cat. 1
Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H330 Fatal if inhaled
H341 Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H350 May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H360 May damage fertility or the unborn child (state specific effect if known)(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H370 Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H372 Causes damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash the contact area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 Wear respiratory protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P307 + P311 IF exposed: Call a POISON CENTER or doctor/physician.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see ... on this label).
P321 Specific treatment (see ... on this label).
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P406 Store in corrosive resistant (decided by the manufacturer or authority) container, as this is a metal corrosive material.
P501 Dispose of contents/container in accordance with local/ regional /national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Lead 7439-92-1 56.5 - 59.3% No
Sulfuric acid 7664-93-9 29.7 - 31.2% No
Polypropylene 9003-07-0 9.7 - 9.9% No
Separator 9002-88-4 1 - 1.2% No

European Inventory of Existing Commercial Chemical Substances (EINECS).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. Call in physician.

Symptoms: harmful or fatal if inhaled in a confined area. May cause severe irritation and burns of the nose, throat and respiratory tract.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Symptoms: severely irritating to the skin and may result in redness, swelling, burns and severe skin damage. Skin contact may aggravate an existing dermatitis condition.

Eye contact

Rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Symptoms: tearing, redness, swelling, corneal damage and irreversible eye damage. Splashes in the eyes will cause severe burns.

Ingestion

Make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Symptoms: Causes serious burns of the mouth or perforation of the esophagus or stomach. May be fatal if swallowed.

Immediate Medical Attention

Call in ophthalmologist or a physician immediately.

Medical Treatment

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing media appropriate for surrounding fire. If a battery ruptures, use CO2, foam, dry chemical or sand.

Specific hazards

Combustible. Development of hazardous combustion gases or vapours possible in the event of fire. Battery may rupture due to pressure buildup when exposed to excessive heat and may be result in the release of corrosive materials.

Firefighter Protection

Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Remove all ignition sources. If not dangerous, stop leaking. Be aware of substances and conditions to avoid. Ventilate the contaminated area. Do not touch nudity or walk around. Prevent dust formation. Wipe off spills immediately and follow protective equipment Precautions. Isolate contaminated areas. Do not enter anyone who does not need to enter or is not Equipped with protective equipment. Keep away from flammable materials and spills. Reduce steam with a water spray, but do not allow water to enter the container or leakage. If not dangerous, stop leaking. Do not touch broken containers or leaks without wearing appropriate protective clothing.

Small spill

In case of a small amount of leakage, wash the contaminated area with a large amount of water. In case of small amount leakage, absorb sand, non-flammable material and put in container.

Large spill

In case of large amount of leakage, make a ditch away from liquid leakage. In case of large leakage, make a ditch by moving away from liquid leakage.

Environmental

Wear full-scale vapor protection in case of leakage without fire Cover with plastic sheet to prevent spread. Prevent dust formation. Be aware of substances and conditions to avoid. Do not breathe dust/fume/gas/mist/vapours/spray. Prevent ingress into waterways, sewers, basements, and confined spaces. Leaks can cause contamination. Prevent ingress into waterways, sewers, basements, and confined spaces. Do not discharge into the environment.

Cleanup methods

Wash contaminated area with a large amount of water (for small spills). Absorb spills with sand, non-flammable material, or inert material (e.g., dry sand or soil) and place in containers. For powder leakage, cover with plastic sheet to prevent spread and keep dry. For liquids, absorb and flush contaminated areas with detergent and water. Collect leaks using clean shovels or clean, explosion-proof tools and place in clean, dry, loosely covered plastic containers. Dissolve in water and collect if applicable. Absorb and collect leakage to prevent material damage.

Materials: Water, sand, non-flammable material, inert material (e.g. dry sand or soil), detergent.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Be aware of substances and conditions to avoid. Wash thoroughly after handling. Work with reference to engineering management and PPE. Pay attention to high temperatures. Follow all MSDS/label precautions as product residue may remain after the container is emptied. Use with care for handling/storage. Carefully open cap before opening. Do not breathe steam from heated material. Do not enter storage areas without proper ventilation. When working in a confined space in a low-lying area, there is a risk of oxygen deficiency, so measure the oxygen concentration in the air and ventilate during work. Do not handle all safety precautions until you have read and understood them.

Storage

Keep sealed. Store in a cool, dry place. Be aware of substances and conditions to avoid. Drain the empty drum completely, block it properly, and immediately return it to the drum regulator or position it properly. Keep away from food and drink. Store only in original container. Store in a lockable storage area. Lock and store. As it is a metal corrosive substance, store it in a corrosion-resistant container (as determined by the manufacturer or administrative office).

Hygiene

Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use process isolation, local exhaust, or keep air levels below exposure standards. Use process isolation, local exhaust, or other engineering controls to control air levels below exposure standards. For equipment that stores or uses this substance, install a washing system and a safety shower.

Hands

Considering the physical and chemical properties of the chemical, wear protective gloves of appropriate material

Eyes

Wear eye protection or breathable goggles to protect your eyes from steamy organic substances that may irritate your eyes or cause other health hazards. Install emergency washing facilities (shower-type) and face wash equipment in locations that are easily accessible to workers.

Respiratory

Sulfuric acid: If the exposure concentration is lower than 2 ㎎/㎥, wear a half-type respirator with an appropriate filter or purification bottle. If the exposure concentration is lower than 5 ㎎/㎥, wear a loose-fitting hood/helmet-type electric respirator or continuous flow dust mask/respirator with an appropriate filter or purification bottle. (dust masks are liquid aerosols only) If the exposure concentration is lower than 10 ㎎/㎥, wear a full-face or motorized half-mounted or air-supplied continuous/pressure-demanding half-respirator with appropriate filter or purification bottle. If the exposure concentration is lower than 200 ㎎/㎥, wear a full-face, helmet/hood type, pressure-demanding air mask with an appropriate filter or purification bottle. If the exposure concentration is lower than 2000 ㎎/㎥, wear a self-supplied (SCBA) or pressure-demanding self-air-supplied (SCBA) respirator with appropriate filter or purification bottle. Lead: If the exposure concentration is lower than 0.5 ㎎/㎥, wear a half-type respirator with an appropriate type of filter. If the exposure concentration is lower than 1.25 ㎎/㎥, wear a loose-fitting hood/helmet-type electric respirator or continuous flow dust mask with an appropriate type of filter. If the exposure concentration is lower than 2.5 ㎎/㎥, wear a full-face or motorized half-type or air-supplied continuous-flow/pressure-demanding half-respirator with appropriate filter. If the exposure concentration is lower than 50 ㎎/㎥, wear a full-face, helmet/hood type, pressure-demanding air mask with appropriate filters. If the exposure concentration is lower than 500 ㎎/㎥, wear a self-supplied (SCBA) or pressure-demanding self-air-supplied (SCBA) respirator with an appropriate filter. ABS Resin: For particulate matter, the following respiratory protection is recommended - Face filtration dust mask or air-filtered dust mask (high-efficiency particulate filter material) or dust mask with electric fan. (dust, mist, fume filter material) If you are low on oxygen (<19.6%), wear a mask or self-contained respirator.

Skin/Body

Considering the physical and chemical properties of the chemical, wear protective gloves of appropriate material

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Lower Explosive Limit
-/-
Softening Point
---
Evaporation Rate
---
Relative Evaporation Rate
---
Decomposition Temperature
340 ℃
Physical State
liquid
Auto Ignition Temperature
340 ℃
Flammability
No flammability
Solidification Point
---
Vapor Density
1.8 (Water = 1, 20℃)
Explosive Limits
---
Molecular Weight
98.079
Upper Explosive Limit
-/-
Voc Content
---
Density
1.81 ㎏/l (20℃)
Solubility
Miscible with water, with generation of much heat, also with ethanol
Dynamic Viscosity
21 cP
Freezing Point
10.4~10.94 ℃ (For 100% sulfuric acid)
Vapor Pressure
6 hPa(20℃, 90% aqueous sulfuric acid : solution)
Form
liquid
Odor Threshold
1 ㎎/㎥
Crystallisation Point
---
Boiling Point
337 ℃
Kinematic Viscosity
22.5 cP
Colour Intensity
---
Flash Point
Non-flammable
Relative Density
1.8 (Water = 1, 20℃)
Odor
Odorless
Solubility In Water
Miscible with water, with generation of much heat
State Under Standard Conditions
---
Colour
Colorless
Appearance
Colorless liquid(Oil of vitriol)
Cloud Point
---
Partition Coefficient
-2.2 (Estimates)
Properties Status
---
Solubility In Fat
---
Physical State Data
liquid
Bulk Density
---
Metal Corrosion
---
Melting Point
10.4~10.94 ℃ (For 100% sulfuric acid)
Ph
0.3 (1N solution)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

ABS Resin is stable under normal temperature and atmospheric pressure conditions. Sulfuric acid and Lead can decompose at high temperatures.

Reactivity

Sulfuric acid: May be corrosive to metals. May ignite flammable materials (wood, paper, oil, clothing, etc.). May corrode metals and generate combustible hydrogen gas. Can be ignited by heat, sparks, and flames. Corrosive/toxic: Inhalation, ingestion, or contact with vapours, dust, or substances can cause serious injury, burns, or death. Contact with molten substances can cause serious skin and eye burns. Lead and ABS Resin: Some can ride but do not ignite easily. Non-flammable, the material itself does not burn. Some liquids may cause dizziness and suffocation-inducing vapors.

Hazardous reactions

Sulfuric acid: Can decompose at high temperatures to produce toxic gases. Heated or contaminated with water can cause the container to explode. Reacts violently with water and releases corrosive/toxic gases. May cause flammable/toxic gases to accumulate in confined spaces. Lead and ABS Resin: Container may explode when heated. Non-flammable, but may decompose when heated to produce corrosive/toxic fumes. May produce irritating and toxic gases in case of fire.

Avoid

Overcharging. Sources of ignition. Mechanical impact. Contact within compatible chemicals.

Incompatible

If a battery ruptures, avoid contact with organic materials, alkaline materials and inflammable materials.

Decomposition

Sulfuric acid and Lead can decompose at high temperatures to produce toxic gases. Non-flammable materials may decompose when heated to produce corrosive/toxic fumes. May produce irritating and toxic gases in case of fire. During burning, pyrolysis or combustion may produce irritating and highly toxic gases.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

A. Aquatic ecology toxicity Fish - Sulfuric acid LC5016-28 mg/l 96hr Lepomis macrochirus (National Institute of Environmental Sciences Notice No. 2020-8 "Regulations on the Classification and Labeling of - : Chemical Substances" [Attachment 4] Mercury Compounds Chronic Classification 3) Lead : LC50 1170 ㎍/ℓ 96 hr Oncorhynchus mykiss ABS Resin : LC50 11.5 ㎎/ℓ 96 hr Pimephales promelas Daphnia Sulfuric acid : EC50 > 100㎎/ℓ 48 hr Daphnia magna (OECD TG 201, still water, fresh water, GLP) Lead : LC50 596.83㎍/ℓ 48 hr Ceriodaphnia dubia (US EPA(1993), still water, fresh water) ABS Resin : N/A Algae Sulfuric acid : EC50 > 100㎎/ℓ 72 hr Desmodesmus subspicatus (OECD TG 201 , still water, fresh water, GLP) Lead : EC10 32㎍/ℓ 72 hr Pseudokirchneriella subcapitata (OECD TG 201 , still water, fresh water) ABS Resin : N/A

12.2 Persistence and degradability

B. Persistence and degradability Persistence Sulfuric acid : log Kow -2.2 (Estimates) Lead : 01 2.98 log Kow ABS Resin : N/A Degradability Sulfuric acid : N/A Lead : N/A ABS Resin : N/A

12.3 Bioaccumulative potential

C. Bioaccumulative potential Bioaccumulation Sulfuric acid : (The pKa of sulfuric acid is 1.92 at 25 °C, indicating that this compound will exist almost entirely in anionic form in the environment; sulfuric acid easily separates from water to form hydrated protons with sulfate ions, and dissociation at pH 3.92 is 99%; this ionization means that sulfuric acid itself does not accumulate in living tissues.) Lead : 02 6750 BAF(ℓ/㎏, Conc./dose: 2㎍/ℓ) ABS Resin : N/A Biodegradation Sulfuric acid : N/A Lead : N/A ABS Resin : N/A

12.4 Mobility in soil

C. Mobility in soil Sulfuric acid : N/A Lead : N/A ABS Resin : N/A

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

D. Other hazardous effects Sulfuric acid : N/A Lead : N/A ABS Resin : N/A
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility.

Disposal

Dispose of in accordance with local, state, and federal regulations. Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal regulations for specific requirements.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 2794
Shipping Name
BATTERIES, WET, FILLED WITH ACID, electric storage
Transport Class
8
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Refer to all applicable national, international and local regulations or provisions.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 42B19STKIL?

The signal word is danger.

What is the physical form of 42B19STKIL?

42B19STKIL is a liquid appearing as colorless liquid(oil of vitriol) with colorless color. It has odorless odor.

What is the solubility of 42B19STKIL?

Miscible with water, with generation of much heat, also with ethanol

What is 42B19STKIL used for?

Electric Storage battery

What are the hazard statements for 42B19STKIL?

This substance has 11 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H330: Fatal if inhaled
  • H341: Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
  • H350: May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
  • H360: May damage fertility or the unborn child (state specific effect if known)(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
  • H370: Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
  • H372: Causes damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
  • H400: Very toxic to aquatic life
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of 42B19STKIL?

The melting point is 10.4~10.94 ℃ (For 100% sulfuric acid) and the boiling point is 337 ℃.

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