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Safety Data Sheet EN

Triisopropanolamine 99

CAS 122-20-3
EC 204-528-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Triisopropanolamine 99
Chemical Name
1,1',1'-nitrilotripropan-2-ol

Regulatory Identifiers

CAS Number
122-20-3 Check regulations →
EC Number
204-528-4 Check regulations →
REACH No.
01-2119475482-34-0001

Identified Uses

Manufacture of substance, industrial. Formulation & (re)packing of substances and mixtures, industrial. Use as an intermediate, industrial. Road and construction applications, professional. Use of concrete and cement, consumer. Use as binders and release agents, industrial. Use as binders and release agents, professional. Metal working fluids / rolling oils, industrial. Metal working fluids / rolling oils, professional. Uses in Coatings, professional. Use in Cleaning Agents, professional. Rubber production and processing, industrial. Use in laboratories, professional. Use as a Fuel Additive, Industrial. Use as a fuel, industrial. Use as a fuel, professional. Use as a fuel, consumer. Use in Cleaning Agents, consumer. Use in wood protection formulations, industrial. Use in wood protection formulations, consumer. Used in personal care products. Other Consumer Uses. For details on use descriptors and exposure scenarios, please refer to the extended part of the Safety Data Sheet.

Manufacturers & Suppliers

D

DOW EUROPE GMBH

global supplier

BACHTOBELSTRASSE 3 8810 HORGEN SWITZERLAND

31 115 67 2626

D

DOW BENELUX B.V.

national supplier

HERBERT H.DOWWEG 5 HOEK 4542 NM TERNEUZEN NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

00 41 447 28 2820

24-Hour

Emergency Contact

0049 4141 3679

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.

Precautionary Statements

P264 Wash skin thoroughly after handling.
P280 Wear eye protection and/or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice and/or attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,1',1'-nitrilotripropan-2-ol EC: 204-528-4 122-20-3 99% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air; if effects occur, consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist.

Ingestion

If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Immediate Medical Attention

If burn is present, treat as any thermal burn, after decontamination.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray.. Dry chemical fire extinguishers.. Carbon dioxide fire extinguishers.. Foam.. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective..

Unsuitable media

Do not use direct water stream.. May spread fire..

Specific hazards

Container may rupture from gas generation in a fire situation..

Instructions

Keep people away. Isolate fire and deny unnecessary entry.. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed.. Burning liquids may be extinguished by dilution with water.. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage..

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves).. Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.. For protective equipment in post-fire or non-fire clean-up situations, see Section 8 of the safety data sheet..

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Isolate area. Keep unnecessary and unprotected personnel from entering the area.

Small spill

Absorb with materials such as: Non-combustible material. Sand. Clay. Vermiculite. Zorb-all®. Do NOT use absorbent materials such as: Cellulose. Sawdust.

Large spill

Contain spilled material if possible. Pump into suitable and properly labeled containers.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Cleanup methods

Absorb with materials such as: Non-combustible material. Sand. Clay. Vermiculite. Zorb-all®. Pump into suitable and properly labeled containers.

Materials: Non-combustible material. Sand. Clay. Vermiculite. Zorb-all®.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes, skin, and clothing. Do not use sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

Hygiene

Wash thoroughly after handling.

Fire prevention

Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Polyethylene. Chlorinated polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Viton. Butyl rubber. Natural rubber ("latex"). Neoprene. Polyvinyl chloride ("PVC" or "vinyl"). Nitrile/butadiene rubber ("nitrile" or "NBR"). Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if handling at elevated temperatures without sufficient ventilation, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 °C, meeting standard EN 14387).

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour Intensity
---
Kinematic Viscosity
No data available
Relative Density
0,988 at 70 °C / 4,00 °C Literature
Evaporation Rate
No test data available
Ph
10,3 Literature 1% aqueous solution.
Density
1 g/cm3 at 20 °C Literature
State Under Standard Conditions
---
Boiling Point
301 °C at 1 013 hPa Literature
Molecular Weight
No test data available
Vapor Pressure
< 0,001 hPa at 20 °C Literature
Upper Explosive Limit
Not determined
Dynamic Viscosity
100 mPa.s at 60 °C Literature
Bulk Density
---
Metal Corrosion
---
Odor Threshold
No test data available
Properties Status
---
Solubility
---
Colour
White
Solubility In Fat
---
Relative Evaporation Rate
---
Solubility In Water
830 g/L Literature
Partition Coefficient
log Pow: -0,015 Measured
Odor
Slightly ammoniacal
Crystallisation Point
---
Physical State Data
solid
Melting Point
45 °C Literature
Flammability
Not expected to form explosive dust-air mixtures. Not expected to be a static-accumulating flammable liquid.
Auto Ignition Temperature
285 °C Literature
Decomposition Temperature
No test data available
Vapor Density
---
Softening Point
---
Solidification Point
---
Explosive Limits
---
Form
---
Appearance
Crystalline solid
Physical State
Crystalline solid
Cloud Point
---
Voc Content
---
Freezing Point
Not applicable to solids
Flash Point
closed cup 174 °C Literature
Lower Explosive Limit
Not determined
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. See Storage, Section 7.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems.

Incompatible

Avoid contact with: Nitrites. Strong acids. Strong oxidizers. Product may potentially react with various halogenated organic solvents, resulting in temperature and/or pressure increases. Avoid contact with metals such as: Zinc. Galvanized metals. Heating above 60°C in the presence of aluminum can result in corrosion and generation of flammable hydrogen gas. Avoid unintended contact with: Halogenated hydrocarbons.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials..

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
Shipping Name
Not regulated for transport
Transport Class
Not applicable
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Triisopropanolamine 99?

The signal word is warning.

What is the physical form of Triisopropanolamine 99?

Triisopropanolamine 99 is a crystalline solid appearing as crystalline solid with white color. It has slightly ammoniacal odor.

What is Triisopropanolamine 99 used for?

Manufacture of substance, industrial. Formulation & (re)packing of substances and mixtures, industrial. Use as an intermediate, industrial. Road and construction applications, professional. Use of concrete and cement, consumer. Use as binders and release agents, industrial. Use as binders and release agents, professional. Metal working fluids / rolling oils, industrial. Metal working fluids / rolling oils, professional. Uses in Coatings, professional. Use in Cleaning Agents, professional. Rubber production and processing, industrial. Use in laboratories, professional. Use as a Fuel Additive, Industrial. Use as a fuel, industrial. Use as a fuel, professional. Use as a fuel, consumer. Use in Cleaning Agents, consumer. Use in wood protection formulations, industrial. Use in wood protection formulations, consumer. Used in personal care products. Other Consumer Uses. For details on use descriptors and exposure scenarios, please refer to the extended part of the Safety Data Sheet.

What are the hazard statements for Triisopropanolamine 99?

This substance has 1 hazard statement:

  • H319: Causes serious eye irritation.

What is the melting point of Triisopropanolamine 99?

The melting point is 45 °C Literature and the boiling point is 301 °C at 1 013 hPa Literature.

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